Papers by Keyword: Alloying

Abstract: In this work, the technology of Al-Gd alloys production has been developed, in which gadolinium is added as an alloying element during induction melting or in the composition of Gd₂O₃ disperse particles in the complex use of powder metallurgy and foundry technologies. The design of Vibration-jet agitator (VJA) and technology of its use for introduction of disperse particles into aluminum melts were developed. Aluminum alloys and dispersion-strengthened composites containing gadolinium have been obtained, their structure and neutron absorption properties has been studied.

Abstract: In this article the time and heat dependence of the nitrogen distribution upon steel alloying of 04Cr20Ni6Mn11Mo2NVNb steel grade by the nitrided manganese of Mn85N10 grade at the holding in the air atmosphere from 2 to 30 minutes in the temperature range 1450-1550 °С was experimentally determined. It was determined that the highest degree of nitrogen transition into steel is 99% and is observed with a short holding time of 2 min (after the introduction of nitrided manganese into the steel melt) in the low-temperature region ~ 1450 °С. Further holding and / or temperature growth results in the release of nitrogen in the gaseous form, due to the thermal dissociation of the nitrogen-containing compounds contained in the melt and removal of nitrogen from the melt into the gas phase, which leads to a decrease in the degree of nitrogen transition to the steel. The key possibility for obtaining a steel of the indicated grades group with a nitrogen content of 0.45-0.6% is shown when alloying in an air atmosphere in a low-temperature region (1450-1500°C), while optimizing the holding time.

Abstract: In this article we justify the economic feasibility of using thermos-cyclic treatment of casing from economically alloyed steel 09G2S to produce the strength group Q125, in accordance with API 5CT. It was confirmed by the experiment that using a four-fold thermal cyclic quenching followed by a low-temperature tempering from the low-alloyed pre-eutectoid steel, it is possible to produce mechanical properties at the level: tensile strength 1068 MPa, conditional yield strength 1002 MPa, elongation 11.2 % and absorbed energy 64 Joules. In addition, an economic evaluation of the application in the production of high-strength casings from steel 09G2S, which allows reducing production costs by at least 11 %, due to thermal cycling.

Abstract: To fulfill the industrial demand of forged steels with high tensile properties and microstructural requirements coupled with reduced cost, the possibility to increase the properties of C-Mn steels by means of precipitation strengthening as achieved by micro-alloying (and without the addition of expensive elements such as Mo and Cr) has been evaluated. In order to do that, the effect of V addition has been exploited by means of metallurgical modelling followed by a laboratory ingot manufacturing. Heat treatment has been designed aimed to achieve the desired target tensile properties. Results show that ASTM A694 F70 grade requirements can bel fulfilled by 0.15% V addition and a proper heat treatment in a ferrite-pearlite microstructure, representative of a forged component. Results are discussed in comparison to those of a similar steel without V addition.

Abstract: Introduction to the Fe-C-X system: Si, Mn, Al and Nb, Ti, V, B allow the ultimate tensile strength and ductility of steel to be increased at the same time. Therefore, multiphase steels of the TRIP, DP, MART and CP are the steels of the future. The scientific aim of the researches were to obtain new basic information on alloying process of liquid steel in a tundish with the use of the pulse–step method. The facility under investigation was a single outlet tundish being a component of a slab continuous casting machine. Computer simulations of the liquid steel flow and alloy behaviour in turbulent motion conditions were done using the Ansys-Fluent computer program. For generating the computational grids, Gambit program was used. For pulse–step method optimisation two aspects were considered. At first numerical simulations were performed for the selection of the time interval between the pulse feed of the first alloy batch and the continuous feed of subsequent alloy batches in order to maintain the required homogenisation level. Next simulations were done for determination of the mass of the pulse charge that ensures not only the attainment of the 95% homogenisation level, but also the limitation of alloy concentration peaks occurring in the liquid steel and going beyond the 95% homogenisation zone. On the basis of numerical investigations the mixing curves and time mixing for different variants of pulse-step method optimization were obtained.

Abstract: Microstructure evolution and mechanical behavior of alpha/beta Ti-6Al-4V and Ti-6Al-4V-0.75Mo-0.5Fe titanium alloys during uniaxial compression to a height strain of 70% was studied. The plastic-flow response for both alloys is characterized by successive stages of strain hardening, flow softening, and steady-state flow. During compression the lamellae spheroidized to produce a globular microstructure with higher rate of globularization in Ti-6Al-4V-0.75Mo-0.5Fe. The globularization kinetics in Ti-6Al-4V-0.75Mo-0.5Fe was also found to be much faster than that in Ti-6Al-4V. This difference can be partially associated with different interphase energy due to doping of β-stabilizing elements.

Abstract: The reason of performing the investigations carried out in this work was to investigate the microstructure of the laser treated Al-Si-Cu cast aluminium alloy with the ceramic powder particles using High Power Diode Laser (HPDL) for remelting, and/or alloying. First of all the feeding and distribution of the powder in the surface layer of the alloyed and remelted AlSi7Cu material. Very important issue is the determination of the laser treatment parameters, especially the powder feeding rate, laser power, and scan rate to achieve an enhancement of the layer hardness for ensuring this cast aluminium alloy from losing their working properties and to achieve the tool surface is more resistant to wear. The purpose of this work was also to determine technological and technical conditions comparison for the Al2O3 and SiC ceramic powder alloyed into the surface layer with High Power Diode Laser. There are presented also the investigation results about the determination of proper technical condition during the laser treatment, especially the laser head distance and shielding gas influence. The presented results concerns first of all the structure investigation of the obtained surface layer allowing it to achieve an enhanced hardness and wear resistance more resistant for work, special attention was devoted to monitoring of the layer morphology of the investigated material and on the particle occurred. Light (LM) and scanning electron microscopy (SEM) were used to characterize the microstructure of the obtained surface zones - the remelted zone (RZ) and heat affected zone (HAZ), the ceramic powder distribution and intermetallic phases occurred. A wide range of laser power values was applied and implicated with different laser scan rates. The powders in form of ceramic powders used for alloying were chosen with the particle size of ca. 60μm. This study was conducted to investigate the influence carbide and oxide powder addition on structure and mechanical properties as well the and structure changes occurred during the rapid solidification process. The investigation ensures to use laser treatment for alloying/feeding of ceramic powder particles into the surface of light alloys. The scientific reason of this work is the applying of High Power Diode Laser (HPDL) for improvement of aluminium`s mechanical properties, especially the surface hardness. As the main findings was determined that the obtained surface layer is homogeny without cracks and has a comparably higher hardness value compared to non-treated material. The surface hardness increases together with the applied laser power, the highest power applied gives the highest hardness value for the surface. Also the distribution of the ceramic particles is proper, but there a need for further modelling, because the hardness increases in general according to the laser power used so that the highest power applied gives to highest hardness value in the remelted layer, but for other powder amount or alloy the values should be determined separately, and more data would be necessary to create a model for the technique appliance. The practical purpose of this work is to analysis the impact and application possibility of HPDL laser surface treatment on the cast Al-Si-Cu alloys to deliver application possibilities for diverse branches of industry.

Abstract: This work investigates the problem of how to reduce the prime cost of Grade Q125 Group 4 casing and tubing according to API 5CT and proposes process solutions to resolve it, consisting in the enhancement of series of mechanical properties without chemical alloying of steel with expensive elements such as chromium, molybdenum, vanadium, niobium and boron. During the investigation the process parameters of 9MnSi5 low-alloy steel heat treatment were developed, which confirmed the efficiency of this technology providing high values of strength and yield strengths which are minimum 931 MPa and 862 MPa respectively; at the same time maintaining the required cold resistance and resistance to hydrogen cracking of pipe. The suggested process parameters were based on heat cycle quenching with heating in induction furnace up to 1050–1100°С, 880–900°С and 740–780°С accordingly at each cycle and cooling rate in each case equal to 50°С/sec, during which the uniform martensite grain size ranging from 5 to 10 micron was obtained.

Abstract: Metallography analysis of invar alloys crystallized with different cooling rates has been carried out. The study has demonstrated that velocity of crystallization has an impact on the dispersity of graphite. The higher velocity of cooling, the more dispersive graphite is. The volume percentage of graphite in alloy, crystallized with high cooling rate, is lower than compared with low cooling rate. Crystallization with low cooling rate leads to the reduction of the amount of carbon into γ-phase. The coefficient of thermal expansion is basically depends on the amount of carbon into γ-phase.

Abstract: As compared with the untreated one, the low-carbon steel with gradient alloying produced by impact peening showed an increase in corrosion resistance. Specifically, when the corrosion potential increased from-1061 mV to-603.5 mV, the corrosion current density decreased from 1.579×10^-3 A/cm² to 6.703×10^-4 A/cm², the capacitive arc radius increased, and there was no corrosion products viewed on the surface. The improvement in corrosion resistance could be attributed to the diffusion of Cr allowed by the large number of defects induced by the impact peening deformation. This also resulted in the formation of Fe-Cr solid solution, which helped to promote the formation of a passivation film.