Papers by Keyword: Amorphous Metals

Abstract: Nanoindentation and thermomechanical experiments on three types of metallic glasses with different glass forming ability were carried out. The nanoindentation behaviour at room temperature was associated with the creep at elevated temperatures. Different discontinuity populations and their shape observed on the nanoindentation loading curves were compared with morphology of plastic deformed indent regions. The influence of the differences in thermal stability of studied alloys on the nanoindentation in these alloys were studied as well.

Abstract: Firstly, this paper reminds the reader of some basic facts about the glassy state, then of the various ways to produce amorphous metals with particular emphasis on the route of vitrification from the melt. Vitrification of an undercooled melt is the most important route from the viewpoint of the application of metallic glasses. We compare diffusion in some metallic glasses with related crystalline metals. Glassy metals, also called metallic glasses, comprise conventional [1] and bulk metallic glasses [2,3]. We remind the reader of the major experimental techniques for diffusion studies in metallic glasses. The paper then reviews our current understanding of diffusion in glassy metals (see also [4,5,6]), including conventional as well as bulk metallic glasses and undercooled melts. We cover the temperature dependence of diffusion in metallic glasses and discuss the spectrum of activation parameters of glassy metals and its difference to the corresponding one of crystalline metals. We mention the pressure dependence and the isotope effect and we discuss tracer diffusion and viscosity diffusion for a bulk metallic glass and its undercooled melt. Finally we mention computer simulations of atomic jump processes. The diffusion mechanism in metallic glasses differs from that in crystalline metals and involves thermally activated, highly collective (chain-like or caterpillar-like) diffusion jumps. Finally, we mention diffusion along shearbands in a plastically deformed glassy metal.

Abstract: The paper focuses on the characteristic local network structure of icosahedra observed in the relaxed amorphous metals and its contribution to their elastic properties. Using molecular dynamics method, CuxZr100-x binary amorphous models are constructed by rapidly quenching process from liquid. Voronoi polyhedron analyses expose the existence of the medium-range local network structure composed of inter-penetrating icosahedra. It is found that the globally averaged shear modulus obtained from the atomistically defined elastic moduli decreases with increasing free volume content in the condensed matter. The contribution of the densely packed icosahedral cluster with higher elastic rigidity to the global elastic modulus is discussed.

Abstract: In the present study, the fatigue crack propagation tests of Zr-based metallic glass were conducted in laboratory air, and the fracture surface was observed to clarify the effects of loading frequency and the stress ratio. In spite of being brittle material, the metallic glass showed stable fatigue crack propagation behaviour, and the relationship between the crack propagation rate, da/dN, and the stress intensity range,
K, can be divided into three regions as well as conventional crystalline metals. The crack propagation rate can be expressed as a function of the stress intensity range by Paris law in the middle region. The power in Paris law was 1.4, and it is considerably smaller than the value for conventional crystalline metals. The threshold stress intensity range,
Kth, was 1.8 MPam1/2. The effects of the stress ratio and the loading frequency were not observed on the relationships, da/dN-
K and da/dN-
Keff. Then, the fatigue crack propagation of the metallic glass is cycle dependent in laboratory air.

Abstract: Tribological properties are found to change with microstructure. In Ni-P amorphous alloy, annealing conditions were varied with laser irradiation parameters such as scanning speed and laser power. The increase in hardness affected by scanning speed. A peak of hardness was observed as the function of scanning speed. This is because, the formation of nanoscopic composite structure by distribution of crystalline Ni3P compounds in amorphous matrix is the hardest structure.

Abstract: The upper bound for the production of uniform amorphous ribbons during free-jet melt spinning is predicted by coupling a mass balance condition for the melt-pool with a simple boundary layer model for momentum transfer. The relationships between melt-pool length, ribbon thickness and wheel speed are investigated, and a criterion is developed for the onset of unsteady melt-pool behavior, which has previously been associated with increased surface roughness, porosity, and the formation of crystalline phases at high wheel speeds.