Papers by Keyword: Binder-Free

Abstract: In this study, SnO₂ was successfully synthesized using spray pyrolysis method. Knowing that lanthanides has the capability to enhance the performance of metal oxides in supercapacitor application, Samarium was loaded to Tin Dioxide (SnO2) at different percent weight concentrations (0.5%, 1%, 3% 5%). XRD diffractograms shows the formation of tetragonal rutile structure with prominent peaks at 26.6°, 34.08°, 51.94° that corresponds to (110), (101), and (211) respectively and no additional peaks was detected with the incorporation Sm³⁺ ions which. The data obtained from Energy Dispersive X-ray Spectroscopy confirm the presence of Sm on the spray pyrolyzed SnO2. Scanning electron micrograph revealed that the increase in loading of Sm changes the morphology of the samples from 1D to 2D structures. Faradaic reactions indicated by the oxidation and reduction peaks were monitored using cyclic voltammetry in 1M KOH electrolyte. The specific capacitances were determined by analyzing the galvanostatic charge discharge profile of each sample. SnO₂ with 0.5% Sm yield the the highest specific capacitance, energy density and power density of 54.55 F/g, 1.60 WHr/kg, and 230 W/kg respectively. The results from this research offers a valuable information in synthesizing binder-free electrode and modifying its properties by incorporating samarium. These electrodes can be used for advanced applications such as electrochemical energy storage device, electrochemical sensors, and electrocatalytic applications.

Abstract: Fe₂O₃-C-Ni heterojunction structured composite on foam Ni was successfully prepared by simple and effective hydrothermal reaction. The obtained material had good structural stability and excellent electrical conductivity. This binder-free Fe₂O₃-C-Ni electrode exhibits typical pseudocapacitance. Specific capacitance of Fe₂O₃-C-Ni in 1.0 mol L^-1 KOH reaches 844.6 F g^-1, which is higher than that of Fe₂O₃-Ni and C-Ni electrodes. For practice application, assembled Fe₂O₃-C-Ni//AC capacitor exhibits a long-term cycling performance with remains 79.5% capacitance retention within 20000 cycles at 1 A g^-1.

Abstract: In this presentation, we show some experimental results of binder-free WC with Nano WC sintered by Pulsed Electric Current Sintering (PECS) process also known as Field Assisted Sintering Technology (FAST). The particle size of WC powder is almost 80 nm. These binder-free WC have extremely hardness and stiffness. However, these mechanical properties are dependent on the sintering condition, e.g., maximum temperature, applied presssure, etc. We show some relationship between mechanical properties and sintering condition to improve to sinter the binder-free WC

Abstract: In this paper, we show some experimental results of binder-free WC sintered by Pulsed Electric Current Sintering (PECS) also known as Field Assisted Sintering Technology (FAST). These binder-free WC have extremely high hardness and stiffness. However, these mechanical properties are dependent on the sintering condition, e.g., maximum temperature, applied pressure, etc. We show some relationship between mechanical properties and sintering condition to improve to sinter the binder-free WC.