Papers by Keyword: Biodiesel

Abstract: The world's energy needs to be enhanced after the COVID-19 pandemic has caused a shortage of petroleum-based fuels that has occurred in almost all countries in the world. It is essential to use non-edible vegetable oil as a renewable energy source. This study aimed to produce Schleichera Oleosa oil as biodiesel using a homogeneous catalyst (KOH). This study uses the ester/transesterification method in which Schleichera oleosa oil (SO) is heated in a 1L double jacket reactor at 60 °C. The results showed that the optimum conditions were obtained at 0.75 vol% KOH and an agitation speed of 1000 rpm with a reaction time of 90 minutes. This condition resulted in a biodiesel yield of 89%. Furthermore, it was found that the high oxidation stability was 9.03 h, and the pour point was 9 °C. Thus, the physicochemical biodiesel produced is acceptable according to the ASTM 6751 standard.

Abstract: Demands for energy are rising as the world's population expands. To meet these demands, fossil fuels have been overused, yet this over reliance on them has led to their depletion. The usage of fossil fuels has also significantly contributed to the release of greenhouse gases, which is a serious environmental concern. Sustainable energy is therefore environmentally friendly and financially sound. Petro-diesel can be replaced by biodiesel because it is biodegradable and less hazardous. Biofuel is any fuel produced from biomass, which can be either animal fats or waste, plant or algae material as a feedstock. Biomass benefits in producing fuels which helps to lessen the demand for petroleum fuel and products. Petroleum fuel and gas increase the greenhouse gas emissions profile of the transportation sector. The Republic of South Africa (RSA) is the 14^th world's largest emitter of greenhouse gases. This is due to the emissions resulting from burning and heavy reliance on coal. Since biofuel can be produced domestically from natural sources like soybeans, rapeseed, macadamia nuts, coconuts, and even leftover cooking, it has the potential to serve as a remarkable substitute for the commonly used petroleum-derived diesel fuel. This study addresses the historical development of macadamia nuts with a focus on the South African Macadamia Nuts (SAMN) industry, its origin, and as a feedstock for biodiesel production. The generation and classification of biodiesel, physicochemical properties, biodiesel standards, and both American Society for Testing and Materials (ASTM), European Committee for Standardization (EN 14214), and South African biodiesel framework standards are discussed. Furthermore, the biodiesel blending requirements, techniques, and benefits were outlined. Finally, the biodiesel regulatory framework of SA and biodiesel framework as per the Biodiesel Task team (BTT) was examined.

Abstract: The use of blended palm biodiesel has been implemented in Malaysia starting with B5 (5% palm biodiesel blended with 95% petroleum diesel) in 2011, B7 (7% palm biodiesel blended with 93% petroleum diesel) in 2014, and B10 in 2019. Palm biodiesel has been regarded as a reliable petroleum diesel substitute since 1995 following the research and development carried out by MPOB. Six trucks participated in the trial to evaluate the use of B20 and B10 through fleet testing and laboratory investigations. The trucks were divided into two groups according to fuel used. The field trial started in 2019 and ended in 2021. Engine oil and filter samples were taken at 5,000 kilometers intervals between service interval 30,000 kilometers. All the engine oil samples were within their operational service limits at each 5,000 kilometers sampling interval. The average viscosities of used engine oil in B20 group were 12.75 mm² s^-1 and for B10 group 12.98 mm² s^-1. The total basic number (TBN) values for the B20 group was 6.4 mg KOH g^-1 and 6.3 mg KOH g^-1 on average for B10 group. The wear and contaminants test showed the average iron particles concentrations for B20 and B10 groups were 22 ppm and 25 ppm respectively. In terms of engine oil evaporation, the average zinc and phosphorus concentrations reduced by only 20% for both vehicle groups. The average values for soot in oil showed that the B20 group had 10% less soot build-up compared to B10 group. The use of B20 had affected engine oil quality with minimal advantages for soot in oil and iron particle concentrations.

Abstract: This research presents the production of biodiesel from nonedible, renewable ackee apple seed oil and its characterization. The study was carried out on trans-esterification of oil with methanol and sodium hydroxide as catalyst for the production of biodiesel. The harvested ackeed seed was sundried crushed manually and oven dried at a temperature of 105 for 24 hours 250g each of milled ackee seeds were respectively placed in the thimble of a Soxhlet extractor with the use of about 800ml of n-hexane., the flask was heated at 60 with the use of an electric mantle. As the solvent was heated in the boiler, the pure vapor rose through a by-pass and into the top part of the container where the sample to extract was contained. In the condenser, the vapors condensed and drip into the sample-containing thimble.The process parameters such as catalyst concentration, reaction time, and reaction temperature were optimized for the production of ackee seed oil biodiesel. The biodiesel yield of 18.30 % was noticed at optimal process parameters. The physicochemical characteristics of the oil such as pour point, cloud point, pH value, specific gravity, viscosity, acid value, saponification value, iodine value,were determined. Gas Chromatograph Mass Spectrometry (GCMS) was also used to determine the elemental composition of the oil extracted. The fuel properties of biodiesel produced were found to be close to that of diesel fuel and also meet the specifications of ASTM standards.Keywords: Transesterification; Ackee seed; Biodiesel; Characterization; Optimal process, Fuel properties.

Abstract: Green economy and blue economy are essential to applicate. One of the mandatory programs from the Indonesian government is B30, a specification of diesel fuel that has 30 percent of biodiesel content. Based on the biodiesel feedstock specification standard, the free fatty acid content is below 1%. The aim of this research was to produce biodiesel feedstock with high purity of triglyceride from used cooking oil by using batchwise solvent extraction. Batchwise solvent extraction involves the polarity of oil and solvent to separate polar and non-polar lipid fractions. The target of this research was the lowest percentage of free fatty acid and the highest percentage of triglyceride. This method also skipped the general method of refined oil products, such as degumming, neutralization, bleaching, and deodorization. The used cooking oil was mixed with a binary solvent (n-hexane and technical grade ethanol) and a single solvent (food grade ethanol 96% only). Each mixture was stirred at 300 rpm for 15 min and then poured into a separator funnel for 15 min. Polar and non-polar lipid fractions were separated. The non-polar lipid fraction was processed in the same procedure until eight stages. It was found that the batchwise binary solvent extraction produced a non-polar lipid fraction with triglyceride and free fatty acid purities of 88.81% and 2.06%, respectively. Moreover, the batchwise single solvent extraction produced a non-polar lipid fraction with triglyceride and free fatty acid purities of 95.89% and 0.93%, respectively, which is suitable with the standard of biodiesel feedstock below 1%.

Abstract: The consumption of fuel oil in all countries in the world is always increasing. Indonesia is one of the countries that are still dependent on fuel oil, especially for transportation and industry. Biodiesel is known as an alternative to diesel fuel that is believed to be able to overcome the problems of world energy needs. One of the raw materials that have the potential to be biodiesel is Waste Cooking Oil (WCO). This research aims to study the Na₂O/Fly ash catalyst preparation process used for the transesterification reaction of WCO into biodiesel, study of purifying WCO as a raw material in biodiesel, analyze the effect of the methanol molar ratio to oil, catalyst loading and reaction time on the transesterification process in terms of the yield of the reaction, density, viscosity and an acid number of biodiesel product. The research method was begun preparation of Na₂O/Fly ash catalyst and purification of WCO with despicing and neutralization methods. Afterwards, the transesterification process was running by varying %wt of the catalyst, the molar ratio of methanol to oil, and reaction time. The percentage weight of the catalyst used is 4% and 6% to the WCO weight, the molar ratio of methanol to oil is 6:1 and 8:1, and the transesterification reaction time used is 60, 80, 100 and 120 minutes. The results showed that the Free Fatty Acids (FFA) of WCO raw material was 3.102%, but after the despicing and neutralization processes were carried out, the FFA of WCO decreased to 2.538% and 0.282%, respectively. The optimal condition for the biodiesel production process was obtained when the catalyst weight is 6% with a molar ratio of methanol to oil by 8:1 which runs in 120 minutes. In these conditions, the obtained yield of reaction results are 99,09%, density 882 kg/m³, viscosity 11.15 cSt and an acid number of 0.2244 mg KOH/g. The results of XRD analysis on the catalyst Na₂O/Fly ash is dominant by alumina (Al₂O₃), silica (SiO₂), ferrous oxide (Fe₂O₃), calcium oxide (CaO), and natrium oxide (Na₂O) compositions. Moreover, GCMS analysis on biodiesel showed that the methyl ester content formed was 98.13%. Based on parameters above, density and acid number has met the quality standards of SNI 7182: 2015.

Abstract: This study aims to: (1) activate rice husk ash (ASP), coconut shell ash (ATK), and wood charcoal (AK) to become adsorbents and characterize them; (2) purify waste cooking oil (WCO) using ASP, ATK, and AK adsorbents; (3) making biodiesel from the purified WCO and characterizing their quality. This work uses experimental techniques, starting with preparing adsorbents by activating with KOH and characterizing activated ASP, ATK, and AK adsorbents using SEM and FTIR. The adsorbents were then used to purify WCO. Biodiesel was made from purified WCO by transesterification using an H₂SO₄ catalyst in ethanol. The process was carried out at 60°C for 12 hours. Then biodiesel layer was heated to 70°C to evaporate the ethanol. The biodiesel products were tested according to Indonesian National Standard (SNI). The results showed that peaks of the activated ASP, ATK, and AK adsorbents have alcohol groups (-OH), and other functional groups. Activated adsorbents have many pores when compared to adsorbents before activation. Biodiesel synthesized using activated ASP adsorbent has a higher flash point than using activated ATK and AK adsorbents and fulfils SNI specifications.

Abstract: Biodiesel is produced by an esterification process with hygroscopic chemicals, otherwise the biodiesel is very easy to produce water, and the hydrocarbon compounds were easily oxidized, causing corrosion in the stockpiling process such as in storage tanks and distribution pipes. Antioxidants have been shown to reduce the formation of water in the biodiesel stockpiling process. While the demulsifier plays a role in helping to separate water and oil. In this study, the addition of an acrylate-based demulsifier in the accumulation of biodiesel-containing antioxidants was carried out. The antioxidant used in the form of tertiary butylhydroquinone with a concentration of 0.5 M has been able to play an active role in inhibiting the formation of water in the biodiesel stockpiling process. However, the stability of the water and oil emulsion has not been achieved properly, therefore the addition of an acrylate-based demulsifier with a volume of 2 mL, 5 mL, and 10 mL into 100 mL biodiesel can separate oil and water well. The biodiesel that has been added with a demulsifier is evaluated at storage times of 24 hours, 48 hours, and 72 hours. The result is that the storage for 72 hours is more effective in separating water and oil than storage for 24 hours and 48 hours. To evaluate the water content in the biodiesel stockpiling process out using 831 KF Coulometric and Fourier-Transform Infrared Spectroscopy analysis.

Abstract: Due to the greenhouse effect of increased fossil fuel use, resulting in an increase in the period during which fossil fuels will remain available. Because of its advantages for the environment and its production from renewable resources, biodiesel has grown more appealing. As there is a supply of used cooking oil, interest in producing biodiesel is rising. This research examines how CaO and sawdust function as heterogeneous catalysts in transesterification regarding ethanol to produce bio-diesel from the used cooking oil. The impacts of the subsequent variables on the yield of the created biodiesel were investigated. Those parameters include the catalyst concentration (0.5-3 wt%), reaction period (1-4 hr), the molar ratio of ethanol to oil (8:1– 20:1), and temperature (45 to 80 °C). This led to the discovery that CaO catalyst is more efficient compared to the sawdust catalyst, with the maximum percentage yield being 75% for the sawdust catalyst and 95% for the CaO catalyst under catalyst conditions (0.50%), ethanol oil molar ratio of 20:1, and 65 Celsius temperature for 3 hours. It was evident from the results that the biodiesel fuel produced by the catalyst developed in this study fell within the acceptable range of biodiesel fuel.

Abstract: This research focuses on purifying the biodiesel provided by the Davao City Biodiesel Plant using a modified fractional distillation. The researchers considered six variables to determine raw and purified biodiesel properties and characteristics: density, kinematic viscosity, flashpoint, fire point, soap content (NaOH and KOH), and water content. The experimentation results were verified using ASTM D6751 – Standards Specification for Biodiesel Fuel (B100). For the purified biodiesel, an increase in flashpoint and fire point temperatures has been observed using the modified process, thus exceeding the standard limit. Although it affects biodiesel quality, an increase in flashpoints and fire points may be better for fuel handling, transportation, and storage safety reasons. These barely influence the overall performance of biodiesel. In conclusion, the modified process improved the quality of the raw biodiesel from 50% to 83% of the variables' set standard with the optimum conditions of 3.5 inHg at 2 hours and 2.5 inHg at 1 hour.