Authors: Qi Mei Liu, Wan Xi Peng
Abstract: The analytical result by 80°С-based TD-GC/MS showed that 65 peaks were obtained from the helium volatiles from the fresh branches of Cinnamomum camphora and 60 chemical compounds were identified. The results showed that the main components were as: 1,3-Benzodioxole, 5-(2-propenyl)- (12.629%), Tricyclo[2.2.1.0(2,6)]heptane, 1,7-dimethyl-7-(4-methyl-3-pentenyl)-, (-)- (10.302%), 3-Cyclohexene-1-methanol, .alpha.,.alpha.4-trimethyl- (9.084%), Bicyclo[2.2.1] heptan-2-one, 1,7,7-trimethyl-, (1R)- (7.406%), Nerolidol (6.695%), Bicyclo[2.2.1]heptane, 2-methyl-3-methylene-2-(4-methyl-3-pentenyl)-, (1S-exo)- (6.017%), Bicyclo[2.2.1]heptan-2-one, 1,7,7-trimethyl-, (.+/-.)- (4.885%), Bicyclo[3.1.1]hept-2-ene, 2,6-dimethyl-6-(4-methyl-3-pentenyl)- (4.680%), Naphthalene, 1,2,3,5,6,8a-hexahydro-4,7-dimethyl-1-(1-methylethyl)-, (1S-cis)- (4.139%), 3-Cyclohexen-1-ol, 4-methyl-1-(1-methylethyl)-, (R)- (3.538%), Copaene (2.749%), Bicyclo[2.2.1] heptan-2-ol, 1,7,7-trimethyl-, (1S-endo)- (2.643%), Acetic acid, 1,7,7-trimethyl-bicyclo [2.2.1]hept-2-yl ester (2.536%), Cyclohexane, bromo- (2.530%), 1,6,10-Dodecatriene, 7,11- dimethyl-3-methylene-, (E)- (1.725%), Naphthalene, 1,2,3,4,4a,5,6,8a-octahydro-7-methyl-4- methylene-1-(1-methylethyl)-, (1.alpha.,4a.beta.,8a.alpha.)- (1.265%), Bicyclo[4.4.0]dec-1-ene, 2-isopropyl-5-methyl-9-methylene- (1.174%), (-)-Isosativene (1.149%), 11-Tetradecen-1-ol acetate (1.118%), .alpha.-Cadinol (1.061%), etc. The analytical result suggested that the helium volatiles from the fresh branches of C. camphora could be used as industrial materials of biomedicines, spicery and food industry.
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Authors: Qi Mei Liu, Dang Quan Zhang, Kuan Peng, Wan Xi Peng
Abstract: Cinnamomum camphora has been used to heal some specific diseases in the Chinese Folk for a long time. In order to explore the wide utilization in biomedicine and spicery, the chemical components of helium volatiles from the fresh branches of C. camphora were studied by TD-GC/MS. The analytical result by TD-GC/MS showed that 50 peaks were obtained from the helium volatiles from the fresh branches of C. camphora and 46 chemical compounds representing 99.993% of the total areas were identified. The results showed that the main components were as: Bicyclo[2.2.1]heptan-2-one, 1,7,7-trimethyl-, (1R)- (9.620%), 3-Cyclohexene-1- methanol, .alpha.,.alpha.4-trimethyl- (9.425%), 1,3-Benzodioxole, 5-(2-propenyl)- (8.223%), Bicyclo[2.2.1]heptane, 2-methyl-3-methylene-2-(4-methyl-3-pentenyl)-, (1S-exo)- (7.541%), Tricyclo[2.2.1.0(2,6)]heptane, 1,7-dimethyl-7-(4-methyl-3-pentenyl)-, (-)- (6.884%), Bicyclo[3.1.1] hept-2-ene, 2,6-dimethyl-6-(4-methyl-3-pentenyl)- (6.050%), Bicyclo[2.2.1]heptan-2-one, 1,7,7- trimethyl-, (1S)- (4.678%), 1,3-Benzodioxole, 5-(2-propenyl)- (4.500%), Naphthalene, 1,2,3,5,6,8a- hexahydro-4,7-dimethyl-1-(1-methylethyl)-, (1S-cis)- (4.491%), 3-Cyclohexen-1-ol, 4-methyl-1- (1-methylethyl)-, (R)- (4.254%), Copaene (4.120%), Tricyclo[2.2.1.0(2,6)]heptane, 1,7-dimethyl-7- (4-methyl-3-pentenyl)-, (-)- (4.097%), Acetic acid, 1,7,7-trimethyl-bicyclo[2.2.1]hept-2-yl ester (3.574%), Borneol 3.334%), 3-(4-N,N-Dimethylaminophenyl)propenoic acid, 2- (diethoxyphosphinyl)-, ethyl ester (2.809%), Eucalyptol (2.096%), 1,6,10-Dodecatriene, 7,11- dimethyl-3-methylene-, (Z)- (1.885%), (-)-Isosativene (1.664%), 1,6,10-Dodecatrien-3-ol, 3,7,11-trimethyl- (1.407%), Cyclohexene, 1-methyl-4-(5-methyl-1-methylene-4-hexenyl)-, (S)- (1.218%), 1,4-Methanoazulene, decahydro-4,8,8-trimethyl-9-methylene-, [1S-(1.alpha.,3a.beta., 4.alpha.,8a.beta.)]- (1.174%), .alpha.-Caryophyllene (1.156%), etc. The analytical result suggested that the helium volatiles from the fresh branches of C. camphora can be applicable to biomedicine and spicery industrial materials.
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Authors: Dang Quan Zhang, Lin Lin Guo, Huai Yun Zhang, Fan Wang, Li Hui Wang, Kun Yue
Abstract: Cinnamomum camphora is a famous non-wood tree, which can be used to extract camphor, C. camphora oil and its ramification. It is an excellent timber tree and evanescence species with the road. Researches about the chemical composition of C. camphora root wood is very less, this restricts the development and utilization of the root of C. camphora. Therefore, we used Py-GC/MS technology to analyze the high-grade resource recovering approaches of C. camphora root wood. After treated with freeze-drying and smashing, samples were extracted by the acetone extraction. After concentration and refrigeration dry, the comminuted power of C. camphora root wood was pyrolyzed in He atmosphere at 750°C, then the pyrolysis product was analyzed by online linked GC/MS. Relative content of each component was determined by area normalization. The analytical result showed that C. camphora root wood can be used as top value-added materials of biomedicine, and also as the materials of bioenergy, perfume, cosmetic, food, dye and industrial solvent.
225
Authors: Qing Li, Dang Quan Zhang, Qi Mei Liu, Kuan Peng
Abstract: The chemical components of helium volatiles from the fresh branches of Cinnamomum camphora were studied by TD-GC/MS. The analytical result by 60°С-based TD-GC/MS showed that 55 peaks were obtained from the helium volatiles from the fresh branches of Cinnamomum camphora and 53 chemical compounds were identified. The results showed that the main components were as: Bicyclo[2.2.1]heptan-2-one, 1,7,7-trimethyl-, (1R)- (15.4328%), 1,3-Benzodioxole, 5-(2-propenyl)- (14.881%), Tricyclo[2.2.1.0(2,6)]heptane, 1,7-dimethyl-7-(4-methyl-3-pentenyl)-, (-)- (12.694%), p-menth-1-en-8-ol (9.832%), Bicyclo[2.2.1]heptane, 2-methyl-3-methylene-2-(4-methyl-3- pentenyl)-, (1S-exo)- (6.143%), 1,6,10-Dodecatrien-3-ol, 3,7,11-trimethyl- (5.365%), Bicyclo[3.1.1] hept-2-ene, 2,6-dimethyl-6-(4-methyl-3-pentenyl)- (4.527%), Naphthalene, 1,2,3,5,6,8a- hexahydro-4,7-dimethyl-1-(1-methylethyl)-, (1S-cis)- (4.129%), 3-Cyclohexen-1-ol, 4-methyl-1- (1-methylethyl)- (2.965%), Borneol (2.627%), Bicyclo[2.2.1]heptan-2-ol, 1,7,7-trimethyl-, acetate, (1S-endo)- (2.586%), Copaene (2.534%), 1,6,10-Dodecatriene, 7,11-dimethyl-3-methylene-, (Z)- (1.612%), (-)-Isosativene (1.121%), etc. The analytical result suggested that the helium volatiles from the fresh branches of Cinnamomum camphora could be used as industrial materials of biomedicines and spicery.
852
Authors: Dang Quan Zhang, Huai Yun Zhang, Lin Lin Guo, Kuan Peng
Abstract: Py-GC/MS technology was used to analyze the high-grade resource recovering approaches of C. camphora root wood at 350°C. The result showed that the chemical components of acetone extractives from C. camphora root wood are as: Benzene, 1,2-dimethoxy-4-(2-propenyl)- (10.255%), Bicyclo[2.2.1]heptan-2-one, 1,7,7-trimethyl-, (1R)- (7.751%), p-menth-1-en-8-ol (5.765%), Phenol, 2,6-dimethoxy-4-(2-propenyl)- (3.833%), 1,6-Cyclodecadiene, 1-methyl-5-methylene-8- (1-methylethyl)-, [s-(E,E)]- (3.669%), D-Allose (3.265%), Acetic acid (2.784%), 1(2H)-Naphthalenone, octahydro-8a-hydroxy- (2.719%), 1,3-Benzodioxole, 4-methoxy-6- (2-propenyl)- (2.674%), .beta.(3,4-Methylenedioxyphenyl)propionic acid (2.216%), Phenol, 4-methyl- (2.200%), Phenol, 2,6-dimethoxy- (2.138%), 3,4-Methylenedioxyphenyl acetone (2.125%), 5-Hepten-2-one, 6-methyl- (2.075%), 2-Oxabicyclo[2.2.2]octan-6-ol, 1,3,3-trimethyl- (1.808%), Phenol, 2-methoxy-3-(2-propenyl)- (1.688%), etc. The analytical result by 350°C-based Py-GC/MS showed that the 350°C pyrolyzate of acetone extractives from C. camphora root wood can be used as top value-added materials of biomedicine, but also used as the bioactive materials of bioenergy, cosmetic, food, and other industrial solvents.
837
Authors: Dang Quan Zhang, Qing Zhi Ma, Qi Mei Liu, Wan Xi Peng, Huai Yun Zhang, Kuan Peng, Zheng Jun Gu, Mo Hua Yang
Abstract: Pinus massoniana Lamb has been used to heal some specific diseases in the Chinese Folk for a long time. In order to explore the wide utilization in biomedicine and spicery, the chemical components of helium extractives from the fresh wood of Pinus massoniana Lamb was studied by TD-GC/MS. The results showed that the main components were 1,4-Methanoazulene, decahydro-4,8, 8-trimethyl-9-methylene- (29.98%), 1,4-Methanoazulen-9-ol, decahydro-1,5,5,8a-tetramethyl- (10.32%), 1R-.alpha.-Pinene (8.33%), 1,2,4-Methenoazulene, decahydro-1, 5,5,8a-tetramethyl- (4.72%), Borneol (2.99%), Thujopsene (2.80%), 1-Phenanthrenecarboxaldehyde, 7-ethenyl-1,2,3,4,4a,4b, 5,6,7,9,10,10a- dodecahydro-1,4a,7-trimethyl- (2.53%), Bicyclo[2.2.1]heptan-2-one, 1,7,7- trimethyl-, (1R)- (2.52%), Caryophyllene oxide (2.40%), Tricyclo[5.4.0.0(2,8)]undec-9-ene, 2,6,6,9-tetramethyl- (2.32%), 1,3-Benzodioxole, 5-(2-propenyl)- (2.274%), Acetic acid (2.07%), Eucalyptol (1.70%), Eucalyptol (1.70%), Benzaldehyde, 4-hydroxy- (1.61%), etc. The analytical result suggested that the helium extractives from the fresh wood of Pinus massoniana Lamb could be used as industrial materials of biomedicines and spicery.
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