Papers by Keyword: Biphenyl

Abstract: Two thiophene derivatives 4,4'-di (thiophen-2-yl) biphenyl and 4,4'-di (thiophen-2-yl) -2-nitrobiphenyl ,which were used as monomers for preparing poly (4,4'-di (thiophen-2-yl) biphenyl) (DPBT) and poly (4,4'-di (thiophen-2-yl)-2-nitrobiphenyl) (DPNT) by ferric chloride oxidation polymerization, were synthesized via Suzuki reaction with 4,4'-dibromobiphenyl as the raw material. UV-vis absorption spectra, fluorescence spectra, photoluminescence spectra and electrochemical properties of the polymers were recorded and used for calculating the band-gap (E_g), HOMO orbital energy (E_HOMO) and LUMO orbital energy (E_LUMO) of the polymers. The calculation results indicated that attaching an electron-withdrawing group such as-NO₂ to the main chain can lower band-gap and increase the maximum absorption wavelength.

Abstract: Two novel copolymers consisting of 3-hexylthiophene and 4,4-di (thiophen-2-yl) biphenyl (DTBHT) or 4,4-di (thiophen-2-yl)-2-nitrobiphenyl (DTNHT) were synthesized. Both of the copolymers show lower HOMO energy level (-5.62, -5.51 eV) than that of the P3HT (-5.1 eV). Compared to DTBHT, adding nitro group in DTNHT improves effective conjugation of the main chain and successfully lowers the electrochemical bandgap of the copolymers from 2.39 to 2.28 eV and optical band-gap from 2.17 to 2.07 eV with significant increase in fluorescence quantum yield from 0.140 to 0.252. Keywords: biphenyl, 3-Hexylthiophene, conjugated polymer

Abstract: A monomer 4,4'-bis(β-hydroxyethyl)biphenyl (2BP) was synthesized by the Williamson reaction from 2-chloroethanol and 4,4'-biphenol. Then, the novel dendritic liquid crystal macromolecule (DLCM) containing biphenyl structure was synthesized with 2BP and 1,3,5-benzenetrimethylacylchloride as monomers by dispersion method. The structures of 2BP and the DLCM were characterized by FT-IR and 1H-NMR. The thermal stabilities of he DLCM were measured by TGA and DSC. The results showed that the DLCM had good thermal stability and the DLCM may have a higher phase inversion temperature.

Abstract: Liquid crystalline polyesters containing central biphenylene moiety in the mesogenic unit with ester linkages to the different lengths of flexible spacers were synthesized using melt polycondensation reaction. Glass fiber, as a reinforce, was meltpolymerized with 4-acetoxybenzoic(ABA),4,4＇-diacetoxybiphenyl and terephthalic acid(TA) to make TLCPs with a good mechanical properties. All the obtained compounds were characterized by conventional spectroscopic methods. The thermal behavior of the polymers has been characterized using polarized optical microscopy and differential scanning calorimetry. The effect of monomer structure and mechanical properties has been investigated on the prepared polyesters and is also compared with that of the analogous polyester by other processing mode. Optical microscopy showed a highly threaded liquid crystalline texture to a high birefringent Schlierene texture characteristic of the nematic phase for all polyesters. DSC experiments were also found in accord with mesophase formation. The melting points of polymers having a central 4,4’-biphenyldicarboxylate residue have two broad endotherms. The glass transition temperature values of polyesters are not effect by the glass fiber. According to the SEM result showed that the composite had strong fiber-matrix adhesion. From the mechanical test result, it showed that TLCP are reinforced by rigid fiber further improvement of properties depending on fiber content, fiber fabric construction, fiber type. The mechanical properties of GF/TLCP had been improved greatly as the content of glass fiber was increased,but GF/TLCP mechanical properties do not improve remarkably as glass fiber content more than 30wt%.The effect of copolymerization with added glass fiber in synthesis process is compared with that of the anlogous homopolyesters by other processing mode. Our finding shows that the copolymers exhibit reduced technical process and maintained mechanical properties.