Papers by Keyword: Bulk Amorphous Alloys

Abstract: Metallic amorphous materials were developed during 80’s as new materials, with very interesting industrial properties (heat conductivity, magnetic properties, fusion temperature, corrosion resistance, etc.). Technology to obtain these materials, based on very rapid cooling of a melted alloy with glass forming ability, has limitations for the dimensions of the products that can be obtained with amorphous structure (thickness has to be very thin), which can be overpassed by development of bulk amorphous alloys with high glass forming ability and good control of the cooling speed. Numerical modeling of thermal field during ultra-high cooling, developed in researches presented in this paper, allows researchers to estimate the results of applying in reality certain cooling conditions. This model will help developers of bulk amorphous alloys in checking if are ensured conditions to obtain an amorphous alloy with fewer experimental tests, less time and low expenses.

Abstract: By using the Mg₆₅Zn₃₀Ca₅ amorphous powder prepared by ball-milling of the master alloy or its mixture powders, we produced Mg₆₅Zn₃₀Ca₅ bulk amorphous alloy and its composites by a spark plasma sintering process. The microstructure and corrosion properties of the prepared Mg₆₅Zn₃₀Ca₅ bulk amorphous alloy and its composites were investigated. The bulk amorphous alloy and its composites exhibited a high relative density and high corrosion resistance than commercial Mg alloys.

Abstract: The aim of the research was to develop an amorphous and microstructured layer on non-amorphous alloys by laser surface treatment. The as-prepared Cu based master alloy ingots were imbedded in a metallic sinking with Wood metal to assure the good thermal conductivity during the laser treatment. The laser remelting, alloying and coating techniques were applied from the laser surface treatment techniques. The surface layer production and a subsequent rapid cooling were performed using CO2 laser and pulse and continuous modes of Nd:YAG laser. The characterization of the microstructure of the resulting surface layer was investigated by scanning electron microscopy (SEM) and X-ray diffraction (XRD). Actual remelting on substrates showed that the process of laser remelting is a suitable technique for production of metallic glasses as surface layers. The amorphous layer up to 250 m in depth can be produced by laser surface remelting on Cu46Zr42Al7Y5 alloy.

Abstract: The effect of Co substitution for Be on the glass-forming ability and mechanical properties was investigated in Ti₃₅Zr₃₀Be_27.5-xCu_7.5Co_x (x=0, 3.5, 7.5, 11.5 at.%) alloys by using X-ray diffractometry (XRD), differential scanning calorimetry (DSC), high-resolution transmission electron microscopy (HRTEM) and compression test. With the substitution of Co for Be, glass-forming ability (GFA) is significantly enhanced and fully amorphous rods with a diameter of up to 12 mm were produced in the alloy with 3.5 and 7.5 at.% Co. The Ti₃₅Zr₃₀Be₂₄Cu_7.5Co_3.5 bulk glassy alloy exhibits good plasticity of 4% during compressive applied load at ambient temperature in conjunction with distinct yield strain of 2% and high fracture strength of 2196 MPa. The effect of the addition of Co on the structure and deformation behavior of the Ti₃₅Zr₃₀Be_27.5-xCu_7.5Co_x (x=0, 3.5, 7.5, 11.5 at.%) alloys is discussed.

Abstract: This paper presents some results for numerical simulation of the thermal field developed during rapid cooling of iron base alloy (Fe₇₃Cr₂Ga₄P₁₃Si₅C₃), to obtain bulk metallic glasses. Technology of rapid cooling gives the possibility to obtain bulk metallic alloys with an amorphous structure which can be used for industrial applications like magnetic shields. Validity of the numerical model of the cooling process was confirmed by the X-ray diffraction analysis. Once the model being validate, it can be used to optimize the rapid cooling process and casting mold geometry to be able to investigate the possibility to obtain larger amorphous bulk components.

Abstract: This paper presents a mathematical model that describes the influence of the chemical composition on the glass forming ability of ferromagnetic alloys. Glass forming ability is given by the difference between the glass transition temperature and the primary crystallization temperature of the alloy. The glass forming ability is better as long this difference has a higher value. These temperatures were determined using differential thermal analysis.

Abstract: Bulk metallic glasses (BMGs) are an emerging class of materials. The amorphous alloys have very attractive properties. There is potential for applications. The quaternary and pentanery (ZrCuAlNi)100-xTix (x = 0, 2 and 5 at. %) alloys were synthesized by melting 2-3N pure metals in an arc furnace. Amorphous ingots were produced using Cu mold casting technique. The alloys showed wide supercooled liquid region Tx, high thermal stability and good glass-forming ability (GFA). Many thermal parameters like Trg, , , β and  were measured employing high temperature differential scanning calorimetry (DSC). Structural characterization was carried out by X-ray diffraction (XRD) technique. Microstructural characterization was conducted using high resolution field emission scanning electron microscopy (FESEM) and elemental analysis was done using energy dispersive spectroscopy (EDS). Crystallization behavior and phase formation was studied. Activation energy for crystallization was calculated using Kissinger and Ozawa equations. The alloys show double stage crystallization. Mechanical properties were measured. Compression test was carried out and fracture strength and strain were determined. The fracture behavior was studied which showed veins like patterns, shear bands formation and liquid droplets.

Abstract: The glass-forming ability, thermal stability and magnetic properties of the Nd60-xDyxFe30Al10 (x=0, 2, 5) bulk amorphous alloys were investigated by x-ray diffraction (XRD), differential scanning calorimetry (DSC), scanning electron microscope (SEM) and the vibrating sample magnetometer (VSM). The results show that the glass forming ability of the Nd60-xDyxFe30Al10 (x=0, 2, 5) alloys decrease with increasing Dy content. The as-cast Nd60-xDyxFe30Al10 (x=0, 2, 5) alloys show hard magnetic behavior at room temperature. With increasing Dy content, the intrinsic coercivity of the alloys increase significantly while the saturation magnetization and remanence of the alloys decrease monotonously. With increasing annealed temperature, the intrinsic coercivity of the Nd55Fe30Al10Dy5 alloy decreased significantly, while the saturation magnetization and remanence decrease monotonously. The Nd55Fe30Al10Dy5 alloy shows soft magnetic behavior after annealed at 773K for 30 min.