Papers by Keyword: Castor Oil

Abstract: The process of synthesizing polyurethane (PU) membranes typically involves linking together networks of polymers using organic materials like polyols and isocyanates. Subsequent investigations used additional inorganic substances within PU polymers to enhance the mechanical and thermal characteristics of membranes. In order to be used as a sensor matrix, the PU membrane needs to have certain good qualities and be able to firmly attach to ions. Hence, further refinement of the membrane is necessary in order to enhance these attributes. The PU membrane made from castor oil (Ricinus communis L.) was changed in this study by adding ĸ-carrageenan and D2EHPA. The composition of the membrane plays a crucial role in governing the creation of hard and soft segments within the membrane structure. The right membrane composition can be found by using Expert Version 13 software for process design. This software is based on the Response Surface Methodology and uses Box-Behnken Design. The primary aim of this study was to fabricate PU membranes utilizing natural resources while ensuring the attainment of desirable qualities. The R² and PRESS values, which are very important for figuring out how important the physical performance response is, led to the choice of the quadratic model design as the best one. One of the experimental conditions was the use of 0.231 mg of D2EHPA, 1.241 mg of κ-carrageenan, and 3.840 g of acetone. The final mixture was predicted to have a visual scale value of 6.5 so that a membrane with the best physical properties in terms of strength and flexibility could be made. The composite-derived PU membrane has favorable physical performance. The findings of this study can serve as a foundational element for the advancement of PU membranes in a wide range of prospective applications.

Abstract: Lubricants are commonly used in machining and energy system to reduce friction and wear within moving parts and aid in the transfer of heat. The use of lubricants enhances the overall performance and operation life of systems. Synthetic lubricants commonly used are non-biodegradable and are harmful to aquatic and land habitats. To overcome these challenges, biolubricants from vegetable and animal sources were considered as an alternative to synthetic and mineral lubricants. In this study, the esterification and transesterification processes were used to produce biolubricant from castor oil. Methanol and sulphuric acid (H₂SO₄) were used as alcohol and catalyst respectively for the acid catalysed esterification while ethylene glycol and sodium hydroxide (NaOH) were used for the transesterification process. The average biodiesel yield was 99.87%. The two-step method was deployed in the preparation of the castor nanobiolubricant. The nanobiolubricants were prepared using aluminium oxide (Al₂O₃) nanoparticles of 20 – 30 nm nominal diameter. The volume concentrations of 0.1%, 0.2%, and 0.4% were used in the preparation of the nanobiolubricants. The results showed that the addition of Al₂O₃ nanoparticles into the castor oil biodiesel altered the thermophysical properties (density, dynamic viscosity, pH, acidity, free fatty acid (FFA), flash point, and cold properties) of the biolubricants. The addition of Al₂O₃ nanoparticles reduced the acidity, flash point, and pH value of biolubricant while the cold flow property was improved. The dynamic viscosity decreased with an increase in temperature and increased as the nanoparticle concentration increased. The results were compared with the thermophysical properties of mineral oil, and from these analyses, Al₂O₃ nanobiolubricant can be successfully deployed as an alternative to synthetic and mineral lubricants in machining and energy systems. Fourier transform infrared (FTIR) and UV-Vis analyses were conducted on the castor oil, its biolubricant, and nanobiolubricants.

Abstract: This study aimed to investigate the impact of VCO and castor oil compositions on the physicochemical properties of liquid soap from patikan kebo (Euphorbia hirta) extract and compare it with the marketed liquid hand-soap. The liquid hand-soap was manufactured by adding patikan kebo extract with VCO and castor oil as fatty acid sources. The concentration of VCO and castor oil were varied in 5 formula with ratio 1 : 0, 3 : 1, 1 : 1, 1 : 3, and 0 : 1 of 200 mL of soap perspectively. Several tests such as organoleptic inspection, homogeneity, density, viscosity, foam volume and stability, pH, insoluble materials, free fatty acids, total active ingredients, and total plate number, were performed to determine the physicochemical properties of prepared handsoap. The results of the five formulas were known to the greater VCO the higher the viscosity and percent height of foam, the greater the castor oil the higher the value of specific gravity The five liquid soap formulas produced meet the requirements of SNI 2588-2017. The second liquid soap formula with a ratio of VCO and castor oil 3: 1 was declared to be the best product with free fatty acid 0.78%, pH 8.31, total active ingredient 24.3%, ethanol insoluble material 0.29%, specific gravity 1.09 g/mL, foam high stability 82.85%, and no colonies in testing the Total Plate Figures. It can be concluded that variations in the concentration of VCO and castor oil may affect the physicochemical properties of liquid soap for hand washing extracted from Patikan kebo.

Abstract: The dimension stone wrapping process is a method used before the sawing of the block which aims to enhance the integrity of the rock, thus ensuring that fractured or altered blocks remain intact while they are handling and splitting into slabs. This method increases safety and allows the processing of many materials once not commercialized. Nevertheless, the epoxy resin used in the process comes from a non-renewable resource and contains toxic substances on its composition. Therefore, in order to increase the eco-efficiency in the sector of dimension stones, a comparison of the epoxy resin with an ecological and non-toxic resin based on the castor oil, was carried out aiming to know the resulting tensile strength in the contact of the polymer with the stone surface. Two types of rocks were tested, a silicate and a carbonate one. The results indicated that the castor oil resin performed a higher tensile strength regarding carbonate rocks, suggesting that the castor oil resin could replace the epoxy resin when applied to this rock group, providing an environmental advantage and a global marketing differential.

Abstract: It has been carried out preparation of Chrom/Nanocomposite ZrO₂-Pillared Bentonite catalyst with varying the amount of impregnating precursor at 0 to 3% (w/w). Material characterization of catalyst was carried out using X-ray Diffraction (XRD), X-ray Fluorescence (XRF), Infrared Spectroscopy (IR), Transmission Electron Microscope (TEM), Brunauer, Emmett, Teller (BET) and acidity measurement of ammonia-adsorption method. The results of research showed that pillarization was able to increase the basal spacing, surface area, diameter of pore and total volume of pore in catalyst, however increasing of impregnated Cr metal on bentonite caused the decreasing of basal spacing and surface area of catalyst but it would also caused the increasing amount of acid site. The experimental results showed that the catalyst could convert the castor oil into a liquid phase of 78.80% (w/w) with a biogasoline content of 32,73% (w/w).

Abstract: In this paper, we report the initial research to obtain hybrids (PU@Hap-1%, PU@Hap-2% and PU@Hap-3% compound by hydroxyapatite (Hap) synthesized by coprecipitation (CP) method, with monoglycerides (MG) of castor oil (Ricinus communis) polymerized with hexamethylene diisocyanate (HDI). Hap, was characterized by X-ray diffraction (XRD), Rietveld refinement, Fourier transform infrared (FTIR), RAMAN spectroscopy and X-ray fluorescence (XRF). Hybrids, MG and castor oil, were characterized by Fourier transform infrared (FTIR). XRD patterns and Rietveld refinement analysis confirmed that hexagonal phase for nanostructure for Hap, with average size particles D  12 nm, obtained by Scherrer equation and ration Ca/P = 2.13 (m/m) confirmed that XRF spectroscopy. FTIR and RAMAN spectra exhibited all active modes for vibrational stretches (1, 2, 3 and 4) of the phosphate groups () and vibrational modes of O-H bonds, present in the hexagonal structure for Hap in a ranger from 400 to 4000 cm-1 and 400 to 1100 cm-1, respectively. The conversion of castor oil (triglyceride) to MG, was monitored by FTIR spectroscopy, confirmed that increase of intensity active modes in 3317 cm-1 and 1741 cm-1, corresponding to the vibrations modes of O-H and C=O, respectively. Finally, we observed that all active modes in FTIR spectroscopy, corresponding to the hybrids: PU@Hap-1%, PU@Hap-2% and PU@Hap-3%, and Polyurethanes – PU (standard), confirmed the increase of intensity mode of the phosphate group with the increase of Hap in the polymerization of the mixture MG with HDI.

Abstract: In this paper, the castor oil, as additives, has been investigated on the phase separation temperature of M15, M30, M50 and M65 methanol gasoline at-25.0°C to 40.0°C, respectively. The effect of the additives on the phase stability and saturation vapour pressure was discussed. It was found that castor oil derivatives have good phase stability to various ratio methanol gasoline blends. Introducing water in the methanol gasoline blends need much amount of methyl castor oil to realize phase mixable. Besides, the castor oil can depress the saturation vapour pressure of methanol gasoline effective as well. With these data, it can be concluded that the castor oil have the great potential to be used gasoline-methanol additives.

Abstract: Synthesis and characterization of Cr/Al₂O₃-bentonite nanocomposite as a hydrocracking catalyst of castor oil have been conducted. The catalyst was prepared according to the following method. At the first step, bentonite was activated using H₂SO₄ to obtain H-bentonite, after that the activated clay was pillarized by Al₂O₃, Next, a salt solution of Cr (NO₃)₃·9H₂O was impregnated in the pillared bentonite sample, followed by calcination and reduction to obtain the final catalyst, i.e. Cr/Al₂O₃-bentonite. The catalysts including unpillared bentonite were characterized using infrared spectrometer (FT-IR), X-Ray diffractometer (XRD), X-ray Fluorescence spectrometer (XRF), Transmission Electron Microscope (TEM) and gas sorption analyzer. GC-MS analysis was conducted to characterize the hydrocracking product. The research results showed that pillarization of bentonite caused an increasing of the basal spacing of bentonite in an amount of 1.01 nm. Although Chrom was unevenly dispersed on the bentonite and it probably blocked the bentonite framework resulted in the decrease of catalyst specific surface area, Cr/Al₂O₃-bentonite catalyst gave the best conversion of 64.03%. The GC-MS analysis data showed that the hydrocracking products contained various kinds of organic compounds such as acetone, acetic acid, methyl benzene, octane, heptanal, 2-octene, 1-undecanoic acid, 9-octadecenal and 10-undecenoic acid.

Abstract: Today the use of fatty acids as heat storage substance is growing. The use of several types of fatty acids such as oleic acid, palmitic acid, and stearic acid as heat storage materials has been studied. But, ricinoleic acid from castor oil has not been studied yet. This study was conducted to ascertain the characteristics of ricinoleic acid as a heat storage material.Methyl ricinoleic was obtained through transesterification of castor oil by methanol with sodium methoxide catalyst. Methyl ricinoleic was then hydrolyzed using sodium hydroxide in ethanol to produce ricinoleic acid. Ricinoleic acid was identified by FTIR (Fourier Transform Infrared Spectrophotometer) test standard ASTM E 1252-07 and its chemical composition was determined by Gas Chromatography-Mass Spectrometry (GC-MS). The identification of the type, amount, and environment of hydrogen in the compound was determined by Nuclear Magnetic Resonance (NMR). The analysis on characteristics, that is, transition and melting temperatures of material was performed by DSC (Differential Scanning Calorimetry) test standard ASTM D 3419-08.Based on the results of FTIR, GC-MS, ¹H-NMR, dan ¹³C-NMR tests, the spectra that were obtained indicated that the test substances were methyl and ricinoleic acid 70.349%. And, the results of DSC tests indicated that the characteristics of ricinoleic acid absorbed and released latent heat at the temperature from 8.58°C and absorbed sensible heat at the temperature from-7.17°C to 8.58°C.

Abstract: This study aims to investigate the effects of castor oil and biodiesel on the tribological performance of engine oil. Five mixed types of engine oils (B0, B5, B100, 5B-5% and 10B-5%) were used as the testing oils. Tribological performance of the test oil was evaluated under different temperature and duration by Cameron Plint TE77 reciprocating rig. SEM, EDS and AES/XPS were separately to characterize the morphology of worn surface and indentify the composition of the surface films. The results show that the anti-wear ability of the engine oil mixed with castor oil is better than that of the engine oil mixed with biodiesel oil. At room temperature, the anti-wear ability of engine oil is dominated by the physical adsorption capacity and hydrodynamic effects; while at high temperature, the anti-wear ability of engine oil is depend on the moment of decomposition of ZDDP additive and its chemical reaction rate.