Papers by Keyword: Cations

Abstract: The processing of palm oil from the fruits of the African oil palm generates an increasing amounts of solid waste. The production of beneficial products for various applications from the oil palm wastes would reduce the amount of unwanted materials produced and contribute to a healthier environment. In this research, fractions were derived from the filtrate of the oil palm deseeded fruit head ash by fractional crystallization. Their physicochemical properties, cation, and anion compositions were determined by standard methods. Three hygroscopic oil palm ash fractions, namely crystals, anhydrous, and sediment, were obtained from the filtrate of the soaked ash. The crystals fraction showed significantly higher mean values than the anhydrous and sediment in conductivity and total organic matter (p<0.0001 each), salinity (p<0.01 and p<0.0001), and total organic carbon (p<0.01), while anhydrous had higher total dissolved solids than the crystals (p<0.01) and sediments (p<0.05). pH and melting points for the crystals and anhydrous compounds were similar (11.07 and <330) and higher than that of the sediment (10.29 and 284.2). Compared to the crystals, anhydrous fractions reveal significantly lower values in iron, phosphate (p<0.01 individually), zinc, chloride, nitrate, and sulphate (p<0.05 each), while sediments had significantly higher zinc (p<0.05) and nitrate (p<0.0001) and lower iron, chloride (p<0.05 each), sulphate and phosphate (p<0.0001 respectively) mean values. From this study, the isolation of three fractions from the oil palm empty fruit bunch ash with different physicochemical properties and ionic compositions was achieved. These fractions may serve as useful resources for utilization in various fields of research and production processes.

Abstract: Computer simulation techniques have gained many attentions. The objective of this research was to study influence of the exchangeable cations of Group 1A (Li⁺, Na⁺, K⁺, Rb⁺, Cs⁺) on the CO₂ adsorption in the system using Grand Canonical Monte Carlo (GCMC) simulation. In this simulation, zeolite is a simulation box. The interaction potential simulation with Lennnard-Jones potential showed that Li⁺ and CO₂ had the greatest molecular attraction with Li⁺ having the highest number of CO₂ molecules in the simulation box. The number of CO_{2 /}molecules in the simulation box are as followed with Li⁺ > Na⁺ > K⁺ > Rb⁺ > Cs⁺.

Abstract: Streptomycin (STR) was the bactericidal antibiotic used extensively in human and veterinary medicine with a high aqueous solubility. In this study, the adsorption of STR on soil was studied as a function of pH, cationic types and ionic strength by using adsorption modeling and bath experiments. Adsorption modeling of the adsorption of STR was better fitted with the Freundlich as compared to the Langmuir. The absorbed STR on soil kept relatively constant at pH 3.5-8 and decreased at pH>8. And the order of cationic influence was CaCl₂> NaCl≈KCl> the blank sample for STR sorption capacity, suggesting that the sorption of STR increased as the presence of low concentrations of the cationic. The amount of STR adsorbed was inversely proportional to the logarithmic concentration of the background cations.