Papers by Keyword: Ceramic Powders

Abstract: The issues of the process modeling of wear-resistant covers infusion of the NiCrBSi system, strengthened by the addition of solid powder materials are studied in the article. The results of a numerical study of the effect of heat current and thermophysical properties of materials on the process of heating and infusion of the cover are presented. The statements about the advantages of powders based on ZrO2 are demonstrated. Particular attention is paid to the issue of cracking in the cover after infusion. The assumption is substantiated about the positive effect of the addition of ZrO2 powders on the increase in the crack resistance of the cover.

Abstract: Synthesis of YSAG:Yb ceramic powders with different stoichiometry by chemical precipitation method was carried out. It has been established that scandium can replace both dodecahedral and octahedral positions of garnet. It is shown that scandium is embedded in those positions that become available to it when the YAG:Yb composition deviates from stoichiometric. Thus, scandium can compensate for the lack of one of the components of the oxide composition Y₂O₃, Yb₂O₃, and Al₂O₃ during the formation of the garnet phase.

Abstract: Laser surface treatment is at present one of up-to-date methods for surface layer engineering, in this technique into the matrix material are introduced some amount of alloying additives. So the surface layer is obtained in form of composite material consisting of ceramic particle powders with different properties influencing the surface layer appliance possibilities. Using the technology it is possible to obtain a layer revealing a structured structure consisting of the heat affected zone (HAZ), transition zone (TZ) and remelted zone (RZ), as well as the substrate material. The laser is without cracks and defects as well as has with a slightly higher hardness value compared to the raw substrate material. The used laser power range is set in the range between 1.0 to 2.5 Kw, with the laser scan rate of the beam head in a range between 0.25-0.75 m/min, depending of the applied laser power and material used for alloying.This study was conducted to determine the effect of carbide on oxide ceramic powders addition on the microstructure and mechanical properties their changes and enhancement possibilities during a rapid solidification process of the remelted surface layer. The investigation should help to use this laser treatment technology for alloying of ceramic powder particles into the surface of light alloys, especially magnesium and aluminium. The scientific reason of this work is the usage of High Power Diode Laser (HPDL) for improvement of aluminium`s mechanical properties, especially the surface hardness and war resistance.There was found during the investigations and analysis of the results that, the obtained surface layer is without cracks and defects as well as with a relatively higher hardness compared to the raw material, after standard heat treatment. The hardness value increases according to the laser power used so that the highest power applied gives the highest hardness value in the remelted layer, similar relation can be found in the wear resistance parameters, which increases also with increasing laser power.The findings of the investigations allows to state, that the distribution of the used ceramic particles is generally satisfied, especially the carbide powder was confirmed in the alloys matrix, the particles are mainly present in the upper part of the surface layer or in the bottom zone of the remelted area. The hardness value increases in general according to the laser power used and the highest power results with the highest hardness value in the surface layer. The main aim of this work is to investigate and determine the effect of HPDL remelting and alloying on the cast Al-Si-Cu and Mg-Al-Cu cast aluminium and cast magnesium alloys micro structure for possible application in real working conditions mainly for light metal constructions as well as in many branches of the industry like automotive and rail transportation.

Abstract: This paper presents the results of an investigation using transmission electron microscopy concerning the structure of AlSi7Cu2 cast aluminium alloy after alloying and remelting with a high power diode laser (HPDL). In particular, the changes in the particle/precipitation type, size and shape were determined, concerning especially the SiC and TiC particles added to the initial material. The aim of this work was also to present the laser treatment technology which will be used for further alloying and remelting with ceramic powders – especially carbides and oxides. The innovatory arrangement of this investigation is based on the mixing of two different powders, which were fed simultaneously to the laser-treated aluminium surface. The overview focuses on the laser power required to achieve good layer hardness to prevent hot work tool steel from losing its work stability and to make the tool surface more resistant to action in external conditions.

Abstract: This paper presents the results of laser remelting influence on structure and properties of the surface of the AlSi9Cu2 aluminium cast alloy as well as X40CrMoV5-1 and 32CrMoV12-28 hot work tool steels, carried out using the high power diode laser (HPDL). Structure changes were determined in the work, especially structure of the surface after wear resistance test. Also hardness investigation of the different remelting areas was performed. The reason of this work was also to determine the laser treatment parameters, particularly the laser power, to achieve a good layer hardness for protection of this constructional and tool materials from losing their work stability and to make the material surface more resistant for work extreme conditions. Tungsten carbide and boron nitride powder was used for alloying. The goal of this work was also to determine technical and technological conditions for remelting the surface layer with HPDL. The remelted layers which were formed on the surface of the investigated aluminium and steels were examined metallographic and analysed using a hardness and wear resistance testers. Key words: Wear resistance, HPDL treatment, aluminium alloys, tool steel, remelting, alloying, surface treatment, boron nitride, tungsten carbide.

Abstract: Using citric acid (CA) as a chelating agent, (1-x)Ca0.4Sm0.4TiO3 –xLi0.5Nd0.5TiO3 (CSLNT) (x = 0.3) ceramic powders were synthesized by the Pechini method. The CSLNT precursor and derived oxide powders were characterized by differential thermal analysis, thermogravimetric analysis, X-ray diffraction and scanning electron microscopy. Only perovskite CSLNT (x=0.3) phase appeared when the CSLNT precursor was calcined at 1050°C for 3 h. Compared with the conventional solid-state reaction method, microwave dielectric ceramics with better properties could be prepared by the Pechini method at lower sintering temperature.

Abstract: Nanostructured ceramic bulk materials were achieved from nano-Al2O3 ceramic powders via direct selective laser sintering (SLS). SLS as a non-traditional machining technology of Rapid Prototyping was introduced and compared with other ceramic forming technologies. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) were applied to analyze the microstructure of the ceramic bulk materials. These results demonstrated that the nano-Al2O3 ceramic powders can be sintered into bulk materials maintained nanostructure with some technological parameters. It was found that the nanostructured ceramic bulk exhibited unique microstructure and was free formed rapidly by this sintering technology.