Papers by Keyword: Chloride Diffusion

Abstract: This study investigates the durability of partially-damaged concrete with the addition of Silica Fume and Ground Granulated Blast Furnace Slag. Portland cement was replaced by 10% SF and 60% of GGBFS as a replacement of Portland cement. Thirty-six concrete cylinders (100 x 200 mm) were subjected to three compressive loading levels (50%, 75%, and 90% of its ultimate strength capacity). After 28 days of curing, the concrete specimens were experimentally tested for electrical resistivity, rapid chloride penetration (RCPT) and chloride migration coefficient (D_nssm) according to NT-BUILD 494. The experimental results showed that the GGBFS improves significantly the durability of concrete with the highest electrical resistivity and lowest chloride permeability compared to control and SF concrete and both SF and GGBFS had significant effect the concrete durability properties even when the concrete was subjected to compressive damage up to 90% of the compressive strength. A correlation between D_nssm and RCPT in partially damaged concrete was observed and an empirical linear relationship was developed to estimate D_nssm.

Abstract: Chloride penetration could lead to the rebar corrosion and cause the durability problem in concrete structure under marine environment. It is a coupling process between chloride penetrating and corrosion damage evolving in concrete. This paper proposed an analysis method to deal with this coupling problem. The corrosion damage degree was considered as an internal variable in coefficients of chloride diffusion. Additionally, the interfacial boundary displacement values varied with chloride concentration and service time of concrete structure. This iterative computing algorithm was tackled as user subroutine packaged into software ABAQUS. The numerical examples were given to confirm the reliability of the developed model. The results show that corrosion expanded damage accelerates chloride ions diffusion and vice versa.

Abstract: Based on the existing studies about chloride ion erosion in prestressed concrete structures, this paper intends to discuss the effects of the stress level and environment factors (including temperature and humidity, etc.) on chloride ion diffusion under marine atmosphere zone. The investigation from pre-stressed concrete crossbeams which service for 39 years in Lianyungang Port shows the chloride ion concentration distribution and chloride ion diffusion. According to the chloride ion concentration distribution, it finds that chloride ion concentration values in pre-concrete structures is C_max,1> C_max,2. In addition, the free chloride concentration distribution values go down smoothly after the second peak. Therefore, the result shows that the improved model can be used in marine atmosphere zone.

Abstract: The growing focus on issues related to the control of CO₂ emissions, energy conservation and waste recycling pushes the construction industry to tackle the challenge of sustainable development. The production of ordinary Portland cement (OPC), main product of the sector, is one of the most polluting in terms of CO₂ emissions, thus finding alternative binder is becoming an urgent matter. Geopolymers are largely investigated for this purpose, but studies concerning the durability of reinforced conglomerates prepared with alkali activated binders are only few. The present work aims at investigating the durability performances of steel reinforced geopolymer mortar samples based on carbon fly ash in comparison with OPC mortar. The effect of different Na₂O/SiO₂ molar ratios in the geopolymer mixes is evaluated in terms of mechanical and microstructural properties as well as corrosion resistance in a chloride rich environment. The obtained results show that under the same severe environmental conditions more limited chloride amounts penetrate in reinforced fly-ash geopolymers where a better corrosion behaviour is also detected up to a week of exposure for samples with a nominal Na₂O/SiO₂ molar ratio equal to 0.12 and 0.14. Instead, the corrosion resistance is quite similar to that of reinforced OPC mortar when a period of three months is considered.

Abstract: The chloride diffusion in limestone cement concrete exposed to combined chloride and sulfate solutions at low temperature was studied. For this purpose, a normal Portland cement and two Portland limestone cements (15% and 35% w/w limestone content) were used for concrete preparation. The specimens were immersed in two combined chloride-sulfate solutions of different sulfate content, and stored at 5°C. The total and free chloride contents, as well as the chloride diffusion coefficients were determined for each concrete composition. The results show that the total chloride content and free to total chloride ratio are increased with time. The sulfate content of the corrosive solutions has not a clear effect on total chloride content and chloride diffusion coefficient. It seems that the lower sulfate content results, in general, in higher free to total chloride ratio values. The use of limestone in cement results in higher chloride concentrations in concrete and free to total chloride ratio values. In general, these phenomena are intensified for higher limestone content.

Abstract: This paper aims to analyze accelerated chloride diffusion in high performance concrete (HPC) blended with mineral admixture by using boundary element method (BEM). Rapid chloride permeability test (RCPT) was employed and executed. The experiment proves that the highest resistance to chloride permeability can be acquired in the quaternary-blended concretes (ordinary portland cement + fly ash + blast furnace slag + silica fume). A chloride diffusion BEM model was established according to the diffusion coefficient calculated from the charge passed. The numerical solutions agree with experiments well. It can be inferred that the acceleration degree of RCPT is not the same in different mix proportion. Besides, the results also suggest that the low chloride permeability of the concretes with mineral admixtures may be attributed to the lower diffusion coefficient and the lower surface chloride concentration.

Abstract: Nowadays, influences of concrete cracking on durability of concrete structure are widely reported. However, the influence of macro cracks on chloride diffusion of concrete is unknown under the condition of marine submergence. Therefore, the present paper adopted a notch method to study natural chloride diffusion in cracked concrete with a width of above 0.3 mm. The results show Apparent diffusion coefficient of acid soluble chloride rises from 2.66 ×10^-12 m²/s to 5.92×10^-12 m²/s with increasing crack width from 0 mm to 0.45 mm. Besides, one exponential function was used to describe the piecewise relationship between diffusion coefficient (water or acid soluble chloride) and crack width.

Abstract: The chloride diffusion coefficient of concrete is time dependent. The high performance concrete (HPC) was prepared and the specimens were tested by ASTM C1202 and the durability of HPC in long period is analyzed with the time dependency of diffusion in this paper. The results show that the chloride diffusion coefficients of the HPC with only fly ash are large than those of the HPC with multi-admixtures, but the attenuation of the chloride diffusion coefficients of the formers are faster than the latters. The analysis results show that the chloride concentrations in concrete is over estimated when time-dependence of chloride diffusion is not considered, and the durability of concrete in long period is determined by both chloride diffusion coefficient and age factor.

Abstract: The stochastic model of chloride diffusion is the foundation of evaluating concrete structures’ reliability in marine environment. In this paper, the random field of chloride diffusion coefficient was described as a group of random variables by local average theory. The chloride distribution matrix, diffusion matrix and nodal concentration vector were expanded by using the Taylor series. The stochastic finite element method was developed, and the mean and standard deviation of the chloride distribution concentration were yielded by the presented method. A numerical example demonstrated the high precision of the stochastic finite element method presented, and the service life of concrete structures could be predicted by the method.

Abstract: The concentration of chloride ion in concrete has been an important part of the study of reinforcement corrosion, while the microstructure of concrete on the concentration of chloride ions play an important role, in order to evaluate the sea sand for ordinary concrete and fly ash concrete microstructure andmineral composition, we use the 28 days of age in sea sand Mohr method for the determination of the different types of water-soluble chloride ion concentration to the chloride ion binding characteristics in the study of sea sand in concrete