Papers by Keyword: Corrosion Potential

Abstract: Mild steels were the most frequently used materials in industries and factories since it possesses unique properties but due to weak environmental changes, these cause deterioration and corrosion to the materials’ surface. To prevent such, protective coatings were applied to protect against corrosion in which by incorporating titanium nanoparticles in polyurethane coatings. Titanium nanoparticles were synthesized using titanium butoxide as a precursor. The obtained nanoparticles were used as an inhibitor mixed with coconut oil-based polyurethane polyol blend against the corrosion on mild steel of 3.5% of sodium chloride solution which has been investigated using the Tafel polarization technique. The polarization curves of the corrosion potential for bare mild steel, along with different amounts of titanium nanoparticles coating, exhibit a positive shift. This shift indicates that the coating film effectively reduces the transport path for the corrosive solution, providing a protective barrier against corrosion. This observation is further supported by the results of the adhesive strength test, which demonstrates that the attachment of the coating films to the metal increases with higher amounts of titanium nanoparticles. This indicates improved adhesion and a stronger bond between the coating and the substrate, enhancing the overall corrosion resistance. The increase of contact angle test confirms the improvement of the coating’s hydrophobicity with the addition of titanium nanoparticles. This suggests that the coating repels water more effectively, further contributing to its protective properties against corrosion. Results also show that the addition of 4wt% of titanium nanoparticles has better anti-corrosion properties than the PU CCP alone, and 0.5, 1.0, and 2.0wt% of titanium added.

Abstract: In this study, electrochemical measurements and observations investigated galvanic corrosion behavior between various metals with or without projection-shaped Ni–Cu alloy plating film and carbon-fiber-reinforced thermoplastic (CFRTP) of corroded areas. Stainless steel, aluminum alloy, and CFRTP plates were prepared. Ni and Ni–Cu alloy electroplating were performed on the stainless steel plate. Electroless zinc plating, Ni, and Ni–Cu alloy electroplating were performed on the aluminum alloy plate. The galvanic current between the metal and CFRTP plates was measured using an electrochemical measurement system. The test solution was 0.06 mol/L NaCl aqueous solution. For Stainless steel/CFRTP, the galvanic current flow was negligible with and without the Ni–Cu alloy plating film. For aluminum alloy/CFRTP without the Ni–Cu alloy plating film, the galvanic current ranged from-80 to-120 μA/cm² at a test temperature of 60°C. For aluminum alloy with the Ni–Cu alloy plating film, the galvanic current ranged from-60 to-80 μA/cm². The galvanic current for the aluminum alloy plate with Ni–Cu alloy plating was lower than that of the aluminum alloy plate without Ni–Cu alloy plating film. The result suggests that the formation of the Ni–Cu alloy plating on the aluminum alloy improves corrosion resistance.

Abstract: The purpose of this study was to investigate (simulation of environment for salt treatment of roads in winter and the simulation of the environment of condensed exhaust gas) the galvanic corrosion phenomena which can exist in the construction coupling of cars. The electrochemical behaviour of the hot dip galvanized steel and aluminium alloy, stainless steel and aluminium alloy and stainless steel and silumin which were investigated by electrochemical methods in 3 % NaCl solution and in SEG solution. The open corrosion potential measurement was used to obtain the values of the potential for each couple. The measurement showed a greater bimetallic risk for hot dip galvanized steel with aluminium alloy, where there was ΔE_SCE > 500 mV and this couple is not suitable either for use in aggressive environment. Calculation of the rate of corrosion attack results from the determination of corrosion currents as measured by Taffel and Evans. The extent of corrosion damage was analysed by means of a light microscope. Keywords: bimetallic; aluminium alloy; stainless steel; silumin; exhaust gas; corrosion potential; electrochemical method;

Abstract: Aim of this paper is to evaluate the influence of hydroxyl carbon nanotubes (CNTs-OH) content (by 0.1-0.5% of cement weight) on the resistance of chlorides-induced corrosion of steel bar embedded in concrete. The corrosion process of concrete was monitored by using half-cell potential method (Ecorr, mv CSE). Test results show that the addition of CNTs-OH considerably increased the resistance of rebar chlorides induced corrosion of concrete, and the optimum content of CNTs was about 0.3% by mass of cement. Simultaneously, results also indicate that the measuring position impacted the corrosion potential value, in which the point on the water/air interface had the highest corrosion probability. In addition, the water absorption and SEM of concrete containing CNTs-OH were also investigated, and the pore-filling effect of CNTs-OH was observed to improve the properties of concrete.

Abstract: In this study, seven types of mortar test specimens were manufactured with parameters, that is, the surface of the reinforced steel bar was treated with hot dip galvanizing (Zn) and the surface of the test specimen was coated with underwater paint, and four types of inhibitors (DAW, MCI, DCI, and Silcon) were added in mortars respectively. And, the seven types of mortar test specimens were immersed in seawater for 4 years. The corrosion properties of the reinforced steel bars embedded in mortar test specimens were investigated using electrochemical methods. The corrosion potentials of the test specimens with painting on the surface of the specimen and Zn coating on the surface of the steel bar exhibited the noblest and lowest values respectively after one year, however, after 4 years, the specimens of underwater painting and of addition of Silcon inhibitor indicated the noblest and lowest values of corrosion potentials respectively. Furthermore, the painting specimen exhibited the smallest values of corrosion probability as welll as of the corrosion current density, while, addition of MCI inhibitor showed the highest values of both corrosion probability and corrosion current density. Moreover, the painting specimen showed the smallest value of neutralization degree among all the specimens, and the largest value of neutralization degree was observed at the specimen of natural condition (no adding of inhibitor, no painting and no Zn coating). As a result, it is considered that the addition of inhibitors, coating with hot dip galvanizing (Zn), and painting on the surface have the effects not only to inhibit the neutralization degree but also to increase the corrosion resistance of the embedded steel bar.

Abstract: The present investigation was carried out to optimize the hydrogen fluoride (HF) aqueous solution treatment for an Mg-2.5Zn-0.5Zr alloy, in order to improve the corrosion resistance of the material for orthopaedic applications. An MgF₂ coating was formed on the surface of Mg-2.5Zn-0.5Zr alloy treated with HF solution. The effect of the HF concentration and processing time on the morphology and electrochemical performance of the MgF₂ coating was systematically studied. The results showed that the MgF₂ coating became thick gradually with the increase of the concentration of HF solution. However, the pinhole on the surface treated with 40% HF increased significantly. The coating thickness immersed in the same concentration of HF solution increased with immersion time, and cracks formed in the surface after four hours of immersion, resulting in a decrease in the corrosion potential. When the alloy was immersed in the HF solution with a concentration 20% at 37°C for 2h, a uniform and dense fluoride coating was formed, with a thickness of MgF₂ layer of about 0.5μm. The corrosion potential of the coated Mg alloy in simulated body fluid (SBF) was 0.28V higher than the uncoated one. In addition, the fluoride-coated showed a good biocompatibility.

Abstract: Recently, anti-fouling paints which does not include the poison components such as tin (Sn) free, copper (Cu) free have been increasingly developed in order to decrease the contamination of marine environment. Moreover, the wear ratios of these anti-fouling paints are very important problem to prolong their life time in economical and environmental point of view. In this study, four types of anti-fouling paints as self-polishing type were investigated on the relationship between their polarization characteristics and wear ratios. Relationship between wear ratio and variation ratio of polarization resistance measured in corrosion potential was not well matched with each other. However, there was a good agreement between the wear ratio and variation ratio of diffusion limiting current density, for example, the higher or the lower variation ratio of diffusion limiting current density, wear ratio also increased or decreased respectively. Consequently, it is suggested that we can qualitatively expect the life time and wear degree of anti-fouling paint by only measuring the polarization characteristics before the wear test is practically performed in the field.Keywords: Anti-fouling paint, Self-polishing type, Polarization characteristics, Wear ratio, Diffusion limiting current density, Corrosion Potential

Abstract: AISI 304 and 316L flat samples were exposed during 3 months in Carribean sea water.At the end of the experiment E_corr of AISI 316L reached one-half the negative potential value than that of AISI 304. The tendencies of E_corr were correlated with the pitting corrosion development. They could be considered as a consequence of the opposition between the nucleation of new pits and repassivation of active sites. The analysis of E_corr fluctuations was carried out with the potential spectral density (PSD) vs. frequency in logarithmic scale. The decrease of the PSD slopes, exponent b values, indicated a release of spontaneous energy with the advance of pits formation on the stainless steel surface. The data showed that in the range of low frequencies the process that occurs on both stainless steels surfaces could be considered as fractional Brownian motion, an anti-persistent non-stationary process, while in the range of higher frequencies as fractional Gaussian noise, an persistent stationary.

Abstract: This study investigates how sulfate-reducing bacteria (SRB) influence the process of microbiologically induced corrosion (MIC) of carbon steel by measuring corrosion potential using open-circuit potential (OCP) measurements. MIC is mainly influenced by Desulfovibrio vulgaris, formerly known as Desulfovibrio desulfuricans subsp. Desulfuricans, deposited as spirillum desulfuricans, which produces D(-)-lactate dehydrogenase. This strain was recommended by ATCC to be used in the tests described in ASTM. A pure colony of SRB was isolated from the Baram and Sungai Ular areas in Malaysia. An evaluation of SRB growth was performed during the test in the inoculated medium anaerobically at 37 ̊. The results showed that the corrosion potential E_oc increases in the presence of SRB in pure and mixed cultures as compared to the control sample. These results indicate that the SRB caused the metal loss on the carbon steel surface through direct corrosive action of the H₂S generated by the bacteria during their metabolic process of reducing sulfates to the sulfide form.

Abstract: In dry-wet cycle chloride environment, the corrosion potential of the SFRC specimens is stable between-300mV to-400mV. And the common concrete specimens were about-500mV, adding steel fibers is higher corrosion potential and lower the corrosion possibility. Steel fiber has effective action on the controlling rebar corrosion and concrete crack. There were no cracks on all the surface of the SFRC specimens. Adding Steel fiber in concrete composed to be a corrosion cell as sacrificial anodes to protected steel rebar as cathode, in some degree to postpone rebar corrosion beginning time and increasing the structure services life.