Papers by Keyword: Creep Rupture Strength

Abstract: Tempered martensite lath structure (TMLS) plays a vital role in creep resistance of high chromium martensitic steels. Under creep conditions the TMLS could be stabilized by three agents: (i) a dispersion of boundary M₂₃C₆ carbides and Laves phase; (ii) a dispersion of M(C,N) carbonitrides, which are homogeneously distributed within ferritic matrix; (iii) substitutional alloying element within ferritic matrix. The boundary particles exert a large Zener drag force which effectively hinders migration of low-and high-angle boundaries. A dispersion of M(C,N) carbonitrides both within ferritic matrix and lath boundaries provides the pinning of mobile dislocations. This process is responsible for reliving long-range elastic stress field originated from lath boundaries. In addition, M(C,N) carbonitrides provide high threshold stress. Substitutional elements as W and Mo effectively slowing down diffusion in ferritic matrix retard climb of lattice dislocation that also prevents the aforementioned knitting reaction. The suppression of knitting reaction between lattice dislocation and low-angle boundaries prevents their transformation to subboundaries by concurrent operation of all three agent types. Depletion of W and Mo from solid solution leads to the occurrence of static recovery and precipitation of Laves phase at boundaries under long-term aging. This process is responsible for creep strength breakdown. The strain-induced formation of Z-phase at the expense of V-rich M(C,N) carbonitrides highly facilitates this process. However, slow strain-induced coarsening of M₂₃C₆ carbides and M(C,N) carbonitrides provides the suppression of the knitting reaction between mobile lattice dislocations and intrinsic dislocations of lath boundaries and replacement of TMLS by subgrain structure. Ostwald ripening of boundary M₂₃C₆ carbides and Laves phase leads to rapid creep rate increase with strain in tertiary creep and premature rupture owing to the formation of subgrain structure replaced TMLS and further subgrain growth.

Abstract: The relationship between creep rupture strength and Laves phase precipitation and growth kinetics was investigated at 650 °C for two Fe-9Cr-3Co (wt.%) alloys differing mainly in the amounts of W and Mo added. In the alloy with 3.14 wt.% W added, Laves phase precipitated heterogeneously on grain boundaries and hence had little dispersion strengthening effect. Its stress exponent for rup-ture time became lower in the lower creep stress range tested. In the alloy with 1.31 wt.% W and 3.22 Mo added, Laves phase precipitated both heterogeneously on grain boundaries and homogenously within grains and there was no reduction in stress exponent for rupture time in the whole stress range tested. The Lave phase precipitation kinetics increased with increasing the total amount of W and Mo in the alloys. The differences in stress-rupture time relationship observed between the two alloys were discussed in relation to their differences in the Lave phase precipitation behaviour.

Abstract: The influence of minor Mo addition on the lattice misfit and creep rupture strength of a new single crystal superalloy have been investigated. It was shown that Mo can reduce the lattice misfit; increase the tendency of forming TCP phase; extend the time to material failure.

Abstract: The strength of high temperature components is designed according to creep rupture strength. A statistical processing of creep rupture data of HK40 steel was performed by Z-parameter method based on Larson-Miller method. The data has been studied to evaluate the distribution under different temperature and stress. And the distribution of Z-parameter was investigated. With the application of Z-parameter, reliability design for allowable stress of creep rupture strength was carried out according to design life. The results show that the distribution of Z-parameter is supported by normal distribution. In comparison with allowable stress designed by conventional safety factor method, reliability design based on Z-parameter is more agree with experimental data.

Abstract: Creep rupture data plays vital role in life prediction and safety assessment of high temperature components. In order to describe the scattering of the data, a statistical analysis of creep rupture data for 4Cr25Ni35 steel was performed by Z-parameter method. With the application of Z-parameter, reliability design for allowable stress of creep rupture strength was carried out according to design life. It is found that Manson-Haferd method appears better correlation results with experimental data. Statistical analysis shows that the scattering of Z-parameter for 4Cr25Ni35 steel is supported by normal distribution. Compared with safety factor method, the method based on Z-parameter can perform reliability design for allowable stress of creep rupture strength by considering the dispersibility of the rupture data. Reliability design based on Z-parameter is more agree with experimental data.

Abstract: A statistical analysis of creep rupture data for 2.25Cr-1Mo steel was performed. The scattering of creep rupture data was represented by Z-parameter method based on Manson-Haferd method. With the application of Z-parameter, reliability design for allowable stress of creep rupture strength was carried out according to design life. The higher the value of confidence level, the lower the allowable stress. In comparison with safety factor method and minimum rupture strength method, it can be seen that reliability design based on Z-parameter is more agree with experimental data than other methods. Reliability design provides more precise results by considering the real distribution of creep rupture property and provides more flexible choice for design due to the need of safety and economy.

Abstract: The precipitation of nano Cr2N particles in high Cr FM steels has been studied. The nitrogen content of the FM steels was changed to form stable Cr2N particles. Tempering temperature was also changed from 500 oC to 800 oC to study the precipitation behavior of the Cr2N particles with the tempering temperature. The Cr2N particles remained as a stable phase at a higher tempering temperature by increasing the nitrogen content. The shape of these particle was a fine needle type which was very similar to V(C,N) particles. The size of some Cr2N particles was increased as the nitrogen content increased. But these precipitates were not dissolved or largely coarsened during a creep deformation at 600°C. So it seems that they may act as an effective obstacle against a dislocation glide during a creep deformation, thus contribute to an increase of the creep rupture strength in high Cr FM steels.

Abstract: This paper describes the evaluation of the creep behavior with two types of matching filler metals for 2.25Cr-1.6W(T23)/Mod. 9Cr-1Mo(T91) dissimilar weld joint. Through the welding procedure qualification tests prior to the creep tests, optimum PWHT holding times at 745±5oC were determined as 30minutes for T23 matching filler metal and 60minutes for T91 matching filler metal. It was also confirmed that carbon migration across the weld interfaces and the softened area at HAZ occurred during PWHT. Creep rupture tests were carried out at 575-650oC and 70-220MPa for two dissimilar metal welds manufactured by an optimum PWHT condition. From the comparison of creep rupture strength, it was shown that the creep strength of the welded joint including T23 matching filler metal was similar to that of T23 base material and somewhat higher than that of the welded joint including T91 matching filler metal. From metallurgical study on the crept specimen, the creep damage of T23/T91 dissimilar weld joints could occur at T23 side IC HAZ and near the T23/T91 weld interface simultaneously. However, the final failure locations seemed to depend on the filler metal and the cause of this phenomenon might be regarded as the additional effect of carbon migration across the weld interfaces. It is thought that the dissimilar weld including T91 filler metal which failures at T23 side CG HAZ subject to both metallurgical notch and carbon migration become more susceptible to creep damage than that including T23 filler metal in which the carbon depletion occurs at the T23 filler metal with higher creep strength than T23 HAZ. T23 filler metal can therefore be proposed for matching filler metal of T23/T91 dissimilar weld joints