Papers by Keyword: Crystal Growth

Abstract: The crystallization of metastable metal alloys is characterized by a high rate of the crystallization front, which leads to the effect of "impurity capture" and deviation from the local equilibrium near the surface of the growing crystal. To calculate the growth rate of the crystalline nuclei, a method was developed for prediction of deviation of the components’ concentration near the crystal surface from the equilibrium values. A crystal nucleus was considered to be growing from the initial multicomponent phase, due to interphase transition of the components through its surface. It became possible to distinguish the equilibrium and non-equilibrium effect of the nucleus growth rate by decomposing the molar rate of the product formation near equilibrium, as a function of the molar concentration of the components in the Taylor series and limiting with the linear members. The practical calculations were carried out for the crystallization of the amorphous alloy Fe_73,5Cu₁Nb₃Si_13,5B₉ of the FINEMET type. The local deviations were investigated for the silicon concentration from the equilibrium values at the surface of the growing crystal.

Abstract: The research of the influence of technological modes has been carried out and the negative influence of contaminating impurities on the lead iodide crystallization process has been grounded. The new technological approach to PbI₂ single crystals growth has been proposed, which, unlike traditional methods, is based on increasing of the purity of the source components at the initial stage of technological process. The comparative analysis of the proposed growth technique with other known methods has been made, the efficiency of the purification operation of the Pb and I₂ source components for the obtention and properties of PbI₂ single crystals has been determined. The main types of defects during PbI₂ crystallization from the melt have been analyzed and technological approaches for elimination of the structural violations have been proposed.

Abstract: The development of semiconductor materials and devices will lead to a new industrial technology revolution, in which the Silicon Carbide (SiC) substrate material has very excellent performance and it is especially suitable for manufacturing wave length lasers, white light emitting tubes, high-frequency, high-temperature and high-power devices, etc. This paper focuses on solving the key problems for producing large size and low defects of SiC crystals by the PVT method, such as the preparation and purification of the high purity raw material, the simulation of the temperature field, the control of the crystal defects and the growth of the large size SiC crystals.It is critical for the development of SiC industry.

Abstract: Nano sized ZrO₂ nanopowder was synthesized by precipitation method. Phase transformation was investigated as a function of calcination temperature by XRD, SEM , and FT-IR. It is indicated that the thermal anneling from 400 to 800 °C resulted in increasing the average crystallite size from 12 to 20 nm. As the calcination temperature increased, the crystallite size and the agglomeration were increased. The increase in the monoclinic content and grain growth are caused by the calcination temperatures even calcination at 800 °C.

Abstract: The crucible design having a stepped wall was introduced for increasing the growth rate of SiC crystal without metal addition in top-seeded solution growth (TSSG) method. The numerical simulation confirmed that new crucible design to increase the solvent-crucible interface could definitely change the temperature distribution and increase the carbon concentration. The simulation result, SiC single crystals were grown with Si solvent at 1900°C using a normal crucible and a stepped crucible to investigate the effect of crucible design having a stepped wall. Grown SiC layers were analyzed using Optical microscopy and Raman spectra. The growth rate in the stepped crucible was finally 66um/h observed.

Abstract: Sn-0.7Cu-0.05Ni is a widely used Pb-free solder that solidifies into a near-eutectic microstructure and a small fraction of primary Cu₆Sn₅. This paper overviews in-situ time-resolved imaging experiments on the solidification of Sn-0.7Cu-0.05Ni solder under three conditions: (i) directional solidification, (ii) continuous cooling in a near-uniform thermal field, and (iii) solder joint solidification on a Cu substrate. Primary Cu₆Sn₅ grow as rods along [0001] in each case but can also grow as X-shaped crystals in (iii). There are significant differences in eutectic growth due to nucleation difficulties for tin in conditions (ii) and (iii).

Abstract: In this paper, we review our results from phase field simulations of tilted dendritic growth dynamics and dendrite to seaweed transition in directional solidification of a dilute alloy. We focus on growth direction selection, stability range and primary spacing selection, and degenerate seaweed-to-tilted dendrite transition in directional solidification of non-axially orientated crystals. For growth direction selection, the DGP law (Phys. Rev. E, 78 (2008) 011605) was modified through take the anisotropic strength and pulling velocity into account. We confirm that the DGP law is only validated in lower pulling velocity. For the stability range and primary spacing selection, we found that the lower limit of primary spacing is irrelative to the misorientation angle but the upper limit is nonlinear with respect to the misorientation angle. Moreover, predicted results confirm that the power law relationship with the orientation correction by Gandin et al. (Metall. Mater. Trans. A. 27A (1996) 2727-2739) should be a universal scaling law for primary spacing selection. For the seaweed-to-dendrite transition, we found that the tip-splitting instability in degenerate seaweed growth dynamics is related to the M-S instability dynamics, and this transition originates from the compromise in competition between two dominant mechanisms, i.e., the macroscopic thermal field and the microscopic interfacial energy anisotropy.

Abstract: A reaction-diffusion framework (RDF) is used to synthesize and control the size and morphology of single crystals of metal-organic framework-199 (MOF-199). The framework consists of diffusing copper ions (Cu²⁺, outer electrolyte) into a hydrogel medium containing the organic linker, 1,3,5-benzenetricarboxylic acid (BTC, inner electrolyte). The resulting supersaturation gradient, and its nonlinear coupling with nucleation and growth kinetics, provides means to control the crystal size, distrubution and morphology along the diffusion flux. This method is rapid, efficient, scalable, and environmentally friendly. By using this method we demonstrate how assorted experimental parameters, such as temperature, concentrations, and nature of the gel matrix can be easily tuned to produce different particle size distributions and various morphologies.

Abstract: Powders consisting of nanoparticles of zinc peroxide were prepared via a simple hydrothermal process using zinc acetate dihydrate and hydrogen peroxide precursors. The size of the crystallites was determined using x-ray powder diffraction. Over a period of 5 hours the crystallite radius increased from 4 nm – 9 nm at a temperature of 68 °C ± 5 °C, with growth rate constant of 0.23 nm³ min⁻¹ calculated using the Lifshitz, Slyozov, and Wagner model. The powders were further characterised with High Resolution Transmission Electron Microscopy, Energy Dispersive X-ray analysis, and Small Angle X-ray Scattering, showing well-crystallised ZnO₂ nanoparticles.

Abstract: Barium hexaferrite BaFe₁₂O₁₉ single crystals hexagonal shaped and sizes of up to 5 mm were grown from barium borate flux. The electro physical parameters of grinded crystals were investigated following the open-ended methodology, using Speag DAK system. Thebtained Debye characteristic for permittivity confirmed the theoretical expectations. The presented results show the specific behavior of the target value in terms of causal models for metal powder materials.