Papers by Keyword: DC Electrical Conductivity

Abstract: Pentavalent phosphorous oxide doped yttria-stabilized zirconia (P₂O₅)_X-(Y₂O₃)_0.03-(ZrO₂)_0.97 with x=0.06 mol.% was achieved via an economical technique using mechanical alloying (MA) technique. Three types of nanocomposite powders of electrolyte were produced by high-energy ball milling with different milling times. The phases of synthesized electrolyte powders and sintered electrolytes were illustrated by X-ray diffraction (XRD). The average particle sizes of powders indicated around (360, 245, and 48) nm at milling duration (1, 10, and 45) hrs, respectively. The XRD analysis results of 1 h MA electrolyte powder obtained tetragonal ZrO₂, while the 45 h MA electrolyte manifested a minority phase of monoclinic ZrO₂. Then, the XRD of the sintered electrolyte with the optimum electrical properties appeared two phases. The major phase of the tetragonal zirconium yttrium oxide and a minor phase was a monoclinic zirconium oxide. The average grain sizes of the three types of the sintered manufacturing electrolytes were (7.638, 2.642, and 1.245 µm) after the mechanical alloying duration of (1, 10, and 45) hrs, respectively and sintered at 1873 °K. The DC conductivity (σ) studied corresponded to the influence of milling times on the microstructure for each sintered electrolyte. From the results, the synthesized sintered electrolyte with a long MA duration gave a maximum DC (σ) 1.03E-1S.m. And, the DC conductivity (σ) was 1.11E-02 of electrolyte produced with 10 hr mechanical alloying. Otherwise, the lower DC conductivity got with the electrolyte prepared in the lowest milling duration was 8.9 E-2 S.m.

Abstract: BSCCO 2212 superconducting samples, doped Tellurium, with the chemical formula Bi2-xTexSr2CaCu2O8, were prepared by the conventional solid state reaction technique. The prepared samples were studied utilizing XRD, DC-electrical conductivity and SEM. XRD spectra indicated that 2212 with tetragonal structure is the major phase, whereas Bi-2201 and CaTeO4 are minor phases. At higher Te-additions x, traces from some other semi conducting phases were detected. The critical transition temperature Tcoffset was found to decrease non-linearly with x, which attributed to the hole filling caused by the liberated electrons of Te4+ ions. For x–values in the range 0.1 ≤ x ≤ 0.4, the steepness of (ρ vs T) relationship increases abruptly around 150 K; this was attributed to change in the oxygen vacancy feature (phase-like transition). SEM photographs revealed that as Te-content increases the compactness of the surface and the connectivity of the grains decreases, while pores and voids increase as a result of decreasing the amount of Bi and presence of multiple-phases in the sample.

Abstract: The films of polyaniline:polyethyleneterephthalate films were prepared by polymerizing aniline soaked in polyethyleneterephthalate films of different thicknesses. The films were characterized by FTIR as well as for their electrical properties. The electrical properties of the films were observed to be of good quality as almost all the films showed a great increase in their electrical conductivity from insulator to semiconductor region after doping with hydrochloric acid. All the films in their doped state follow the Arrhenius equation for the temperature dependence of electrical conductivity from 35 to 115oC. The thermooxidative stability was studied by thermogravimetry and differential thermal analysis. The stability in terms of dc electrical conductivity retention was also studied under ambient conditions by two slightly different techniques viz. isothermal and cyclic techniques. The dc electrical conductivity of the films was found to be stable below 90oC for all the films under ambient conditions.