Papers by Keyword: Diffusion

Abstract: The studies results of the titanium with aluminum diffusion interaction at a temperature of 650 oC are presented. The phase and chemical composition of the diffusion interaction zone, the nature of the change in its thickness from the exposure time are determined. It is shown that accelerated cooling of explosion-welded composites from the heat treatment temperature leads to spontaneous separation of the aluminum layer with the formation of a coating based on the TiAl₃ intermetallic compound on the titanium surface.

Abstract: The research of Janus colloidal particles has attracted much attention in recent years because of its huge prospects and applications in materials, chemicals, medicine, catalysis, etc. In order to reduce the cost of conducting experiments, the method of molecular dynamics simulation is used to conduct research on Janus particles. However, the current related simulation study lacks the visualization, dynamization and three-dimensionalization of the Janus particle simulation process. Therefore, the author simulates the free diffusion process of two kinds of Janus particles by using 3D visualization dynamic molecular dynamics related software in this paper. By analyzing the influence of the related parameters of particles and droplet on the diffusion process, new directions of the researches about the simulation of Janus particles can be proposed. The simulation results show that the size of the droplet, the position where the droplet is added to the solution, and the mass of the particles will affect the diffusion process rate of the particles in the droplet in the surrounding solution.

Abstract: Sorption resistances of environmentally friendly polymeric materials in different liquid mediums are studying in this work. As part of environmentally friendly polymeric materials based on polylactide, OK compost HOME plastic and coffee grounds sorption studying in different liquid mediums, the most stable compositions were identified in terms of size stability and diffusion coefficient. microscopic analysis of new environmentally friendly polymeric materials before and after exposure in operating liquid mediums was made and compositions with the least surface changes were determined.

Abstract: Modified stepwise model of gas sorption process with finely dispersed water flow. The sorption model allows forecasting the intensity of hazardous gases deposition with adequate for the emergency recovery conditions accuracy using minimum input parameters. This allows using the sorption model under the conditions of emergency and increasing the forecasting promptness. Use of chemical neutralizer is proposed to increase the effectiveness of chlorine hazardous gas deposition. Use of sodium hydroxide is proposed as the chlorine chemical neutralizer, which is easily dissolved in water, non-toxic and easy to store. An experimental laboratory facility was developed and created with the purpose of experimental verification of the sorption processes, which allows researching the sorption processes by liquid aerosols within a wide range of dispersity. Adequacy of the existing models as well as the modified one was verified experimentally. The verification results showed a 5% indicator of the theoretical and experimental results compliance.

Abstract: Friction stir welding (FSW) is employed primarily for metals characterized by poor weldability at fusion welding: aluminium, magnesium, titanium and copper alloys as well as stainless steels. The focus of the study was on the feasibility of application of WC-based hardmetal 85WC-Co and TiC-based cermet 80TiC-NiMo as potential tool materials for FSW of copper. The single-pass welding trials of Cu sheets were performed using a vertical milling machine. For better understanding of interactions between the tool and workpiece at welding temperature EDS line scans across the interfaces tool-workpiece after welding as well as after diffusion tests were performed. It was concluded that both tested ceramic-metal composites did not failure during multiple plunges and during the total transverse welding distance of 10 m. Also, significant tool wear was not observed after such a welding distance. The possibility of producing visually defect-free welds using tools from WC- and TiC- based ceramic-metal composites was proved and also mutual diffusion of elements across the interface tool-workpiece was discussed.

Abstract: MCrAlY can be used as bond coats for thermal barrier coatings (TBCs) with good ductility and excellent resistance against high temperature oxidation and hot corrosion. The behavior of the microstructure development in the MCrAlY coatings plays a key role on the oxidation resistance. In this paper, the microstructure in the coatings oxidized at 750~1100 °C was analyzed. The formation of the phases and their fraction were studied by comparing thermodynamic simulation results with the experimental observations. At higher temperatures (>1000 °C) β-to-γ’-to-γ phase transformation took place while at lower temperatures (<1000 °C) β phase would transfer to γ directly. The results show that the simulation can semi-quantitatively predict the microstructure formed in the coating.

Abstract: The oxidation behavior of FGH720Li(P/M Udimet720Li) superalloy was investigated under static atmosphere in temperature ranging from 600°C to 730°C. The oxidation kinetics, composition and morphology of the oxidation layers were characterized by means of isothermal oxidation tests, X-ray diffraction(XRD), scanning electron microscopy（SEM）and energy dispersive X-ray spectroscopy(EDS). The results showed that the oxidation kinetics curves of FGH720Li superalloy followed the parabolic law. The results of cross-sectional morphology and elemental distribution indicated that the oxidation layer could be divided into three parts：porous Cr₂O₃ outer layer, dense Cr₂O₃ medium layer and oxidation affected zone with nail-like Al₂O₃ inner layer. The oxidation process was primarily controlled by the diffusion of chromium and oxygen through the oxide scale.

Abstract: In this work, molecular dynamics (MD) simulation was utilized in relation to access the thermal conductivity of UO2, PuO2 and (U, Pu)O2 in temperature range of 500–3000 K. Diffusion study on mixed oxide (MOX) was also performed to assess the effect of radiation damage by heavy ions at burnup temperatures. Analysis of the lattice thermal conductivity of irradiated MOX to its microstructure was carried out to enhance the irradiation defects with how high burnup hinders fuel properties and its pellet-cladding interaction. Fission gas diffusion as determined was mainly modelled by main diffusion coefficient. Degradation of diffusivity is predicted in MOX as composition deviate from the pure end members. The concentration of residual anion defects is considerably higher than that of cations in all oxides. Depending on the diffusion behavior of the fuel lattice, there was decrease in the ratio of anion to cation defects with increasing temperature. Besides, the modern mixed oxide fuel releases fission gas compared to that of UO2 fuel at moderate burnups.

Abstract: Carburizing is a heat treatment process, which used widely for surface hardening. In this process, the parts are placed in a concentrated atmosphere of Carbon atoms. The carbon atoms diffuse in the samples from the surface. In the present article, the effects of carburizing temperature on fatigue life will be studied. The St37 steel material is selected for study due to its wide range of usage in industry and little attention on the carburizing of this material. The samples are prepared by implementing the carburizing process at different temperatures (300, 400, 500, and 600 °C). The holding time is 1 hour for all samples. The two-point bending fatigue tests had been carried out on constant loading stresses. The results of the fatigue life test show that the fatigue life enhances the carburizing process. The fatigue life improved from about 45000 cycles to about 65000 cycles (about 44% increase) by increasing the temperature from 300°C to 600°C. Holding at higher temperatures leads to an increase in fatigue life smoothly due to the increase in the diffusivity coefficient. Also, the fracture surface demonstrates that the crack initiation starts from outer surfaces very slowly and failure happens as a brittle fracture in the samples.

Abstract: In this paper, a brief history of the contributions of many of the major researchers in the field of solid state diffusion is presented starting from 1829 up to the present day. People who are still making significant contributions to the field are mentioned. The authors are well aware that such an attempt is necessarily incomplete and inevitably based on personal knowledge and flavour.