Papers by Keyword: Dissolution Kinetics

Abstract: The Philippines is expected to have an increase in consumption of waste plastic laminates known as sachets, composed of polyethylene (PE) and polyethylene terephthalate (PET) and used in various food and non-food consumer goods. The increase in demand of these sachets has led the country to become one of the top ocean polluters worldwide. Chemical recycling- specifically selective dissolution and reprecipitation- is seen as one viable option for the recovery of these polymers. In this study, the absorption and dissolution kinetics of D-limonene, a potential candidate solvent, in the two-layer (2LL) and three-layer (3LL) laminates were modelled and analyzed for the design of separation equipment to recovery PE. The absorption of limonene for both laminates was observed to initially follow Fickian diffusion, but plateaus when the dissolution rate becomes comparable with the solvent diffusion rate. The dissolution of the 3LL almost closely follows Fickian behavior, while 2LL initially follows Fickian behavior. Deviations from Fickian dissolution may be attributed to the difference in swelling behavior between the non-uniform solvent-polymer diffusion layer and the glassy polymer layer.

Abstract: At room temperature and pressures, the reaction between sodium cyanide and platinum group metals (PGMs) does not occur because of poor kinetics. However, at elevated temperatures, PGMs can be leached by sodium cyanide like the reaction of gold. However, few rate expression which describe the leaching of Palladium in cyanide solution has been developed. In this paper, the rate of Palladium dissolution was measured in pressure clear cyanide solution using a Palladium rotating disk. The data at different rotation speed, cyanide concentrations, temperature and oxygen pressure are obtained. The dissolution rates were independent of rotation speed for oxygen-saturated solutions between 100-400rpm. With increasing temperature the dissolution rate is increased. With increasing cyanide concentration and oxygen pressure, the dissolution rate first increased to a maximum value and then decreased.

Abstract: Potassium-feldspar rocks were ground for 10, 40, 120 and 180 minutes respectively using a porcelain ball mill. The kinetics of potassium release from activated rocks and their effect on yield and nutrient uptake by grain amaranth were evaluated. Results showed that high intensive grinding could improve physicochemical properties and bioavailability of potassium-feldspar rocks. With increasing grinding time, the particle diameters were decreased, the specific surface areas were increased, and the diffraction peaks were decreased remarkably. Maximum release of acid-soluble K was obtained in all rocks during the initial stages of leaching (0-10days), but their differences narrowed down at latter stages (10-60days). The cumulative release of K from the rock treated for 180 minutes was the highest amount (5331.51 K mg/kg rocks) and was 3.75, 1.29 and 19.8% higher than the rocks treated for 10, 40 and 120 minutes, respectively. Data from pot experiment revealed that activated rocks with higher bioavailability promoted the growth and K accumulation of gain amaranth. This study indicated that mechanical activation could be an alternate technology for the efficient of using potassium-feldspar rocks for crop production.

Abstract: This work presents the results obtained from a research on the kinetics of liquid metal front deep- advancement into granular Mg7-FeSi alloy. The phase-to-phase surface interaction, size of particles, control and speed of heat and mass exchange processes are presented in this paper. On the basis of these results it is shown that the phase-to-phase interaction can be superficial, layer, volumetric or combined.

Abstract: This paper uses a combination of thermodynamic calculation and kinetic simulation to model the homogenisation process of cast microstructure for multi-component alloys. The approach assumes that the solute segregation profile across the half dendrite arm spacing can be scaled to the solute concentration profile during solidification as generated by a Scheil type calculation. When secondary phases dissolve during homogenisation, they are treated as an additional fraction of pseudo-eutectic to the initial solute concentration profile of the primary solution phase. The methodology is compared with the assumptions made by other authors, highlighting the significant advantages in the present treatment. Examples are drawn from a cast nickel-based superalloy.

Abstract: Bioactive ceramics such as bioactive glasses, calcium carbonate and sintered hydroxyapatite are widely used in biomaterials field because of their high biocompatibility. In this study, natural hydroxyapatite (N-HA) and synthetic Hydroxyapatite (S-HA) were heat treated at 800°C and studied using “in vitro” experiments. Several physicochemical methods like: SRD, FTIR, SEM and ICP-OES were employed to evaluate the effects of the thermal treatment and to compare their behaviour after soaking in the Simulated Body Fluid SBF at different times. The formation of TCP has favours the formation of new phase. Obtained results show that the dissolution occurred more in N-HA than in S-HA and consequently the precipitation of new phosphate phase is more important in N-HA. This is due to the presence of Mg, Sr and Zn in N-HA with concentration higher to that in S-HA.

Abstract: The kinetics of dissolution of ordered phase with Pt2Mo structure has been studied in two nickel chromium alloys – one without molybdenum and another with molybdenum - using differential scanning calorimetry. The activation energy for dissolution, determined using three nonisothermal approaches was found to be ~ 418 kJ /mole for both the alloys. This value agreed very well with the activation energy for coarsening of g″ precipitates in Ni-Cr-Mo matrix and is close to activation energy for mobility of chromium and molybdenum in complex nickel alloy matrix.