Papers by Keyword: Ferroelectrics

Abstract: Solid solutions of PZT ceramic at Zr/Ti ratio of 0.56/0.44 having various content of softener (La⁺³) and hardener (Sc⁺³) ions according to chemical formula (Pb_1-y La_y) (Sc_x Zr_0.56-x Ti_0.44) O₃, [y= (0.0 and 0.02); x= (0.02, 0.04 and 0.06)], were prepared via conventional solid state reaction methods. Structural and microstructural characteristics were investigated systematically. The measurements of XRD diffraction spectra showed occurring of phase transformation after doping with Sc⁺³ ions in both, PZT and PLZT ceramics, through emerging of tetragonal phase to coexist with the rhombohedral phase. Their fraction varied depending on content of Sc⁺³ ions. SEM mages display a different influence of softener and hardener ions, at 0.02 % mole, on the grain size. Doping with La⁺³ causes reduction in grain size, whereas Sc⁺³ increase the grain size. However, further increase in Sc⁺³ content in both (PZT and PZT) ceramics causes sharp decreasing in grain size. The latter feature is preferable in terms of increasing in the energy storage values.

Abstract: BiScO₃-xPbTiO₃ (BS-PT) of perovskite type structure (with x~0.64) were prepared by solid state ceramic process with addition of calcium fluoride (CaF₂) in different molar ratios (0.5, 1.0 and 4.0 mol%). The doped compositions were found to have different symmetry compared with parent material. The 0.5 mol% doped sample was found to possess enhanced rhombohedral phase as compared to other compositions while he Curie temperature (T_c) was not affected appreciably. Small dielectric peaks were observed, indicating phase transition, at temperature lower than T_c in all the samples except 4.0% doped composition. At room temperature doping reduced the loss factor. d₃₃ and P_r reduced rapidly with doping. The characteristics of BS-PT ferroelectric ceramics became harder with the addition of CaF₂.

Abstract: The capacitance of (1-x)Pb(Mg_1/3Nb_2/3)O₃-xPbTiO₃ (PMN-xPT) [001]-oriented single crystal was examined as a function of temperature and applied external dc electric field. The phase transition temperatures under the applied electric field were measured upon cooling the crystal (zero-field heating field-cooling condition) from paraelectric cubic phase. From these data, temperature versus electric field phase diagram of PMN-xPT crystal have been constructed and discussed.

Abstract: Effects of the electric inclusion in ferroelectrics on the stress and electric field concentration and polarization switching are investigated based on a phase field approach containing the time-dependent Ginzburg-Landau equation. To capture a clear physical picture with the simulation, the crack medium in the electric inclusion is taken into account explicitly as a crack fluid medium as water, oil or air in region. The simulations exhibit a macroscopic electric field concentration in the electric inclusion filled with air, and a significant influence on the domain evolution from the micro perspective, while the electric inclusion filled with water have little influence. The numerical calculations indicated that, when the dielectric constant inside the flaw are much smaller than the dielectric constant of the ferroelectric matrix, the electric field inside the crack medium are enhanced much higher than the applied electric loading. The result implies the domain evolution takes place with the minimization of total free energy, which involves the high electric field energy derived from the electric inclusion. Therefore, the crack fluid medium in ferroelectric plays in importation role in the effect on the non-uniform distribution of the stress and electric field.

Abstract: Ferroelectric ceramic solid solutions Li_xNa_1-xTa_yNb_1-yO₃ (х = 0.17; у = 0 – 0.5) with the perovskite structure have been obtained by the thermobaric synthesis method. Particularities of their microstructure, elastic properties, electrical conductivity and permittivity have been researched. It has been established that an increase in the thermobaric synthesis temperature leads to a decrease in the Young’s modulus value. Specific static conductivity values have been determined; charge carrier activation enthalpies Н_а have been calculated. The Curie temperature of the samples has been determined to decrease with an increase in tantalum content. A Ferroelectric ceramic solid solution Li_0.17Na_0.83Ta_0.1Nb_0.9O₃ was shown to undergo four structure phase transitions in the temperature range 300-820 К. A Li_0.17Na_0.83Ta_0.1Nb_0.9O₃ has been shown to be a high temperature superionic. Possible mechanisms of the detected phenomena are discussed.

Abstract: The paper is devoted to mathematical modeling pyroelectric current of ferroelectric single crystal under the conditions of intensive light heating in view of fractal behavior of these materials. The proposed approach is based on numerical simulation of thermal distribution in a ferroelectric sample using time fractional operator as well as computation of pyroelectric response. The simulation results for typical TGS ferroelectric crystal were described in one-dimensional case of the model in comparison with experimental data. Pyroelectric signals depending on temperature pyroelectric coefficient and thermal physical characteristics were also analyzed.

Abstract: The paper is devoted to developing the theoretical basis of the mathematical modelling and computer simulation intended to analyze and control the electron beam-stimulated effects in ferroelectric materials. In order to simulate the electron beam-induced charging dynamics of ferroelectrics the modification of drift-reaction-diffusion model was proposed. The calculation was based on the numerical solution of the continuity equation and Poisson equation. The parameters of the electron irradiation doze and source function were estimated by 3D Monte-Carlo simulation of electron trajectories in the solid specimen. The computation was associated with typical ferroelectrics (LiNbO₃, LiTaO₃) irradiated by intermediate-energy electron bunches specified for SEM. The contribution roles of drift component as well as diffusion component during dynamic charging process were discussed. The simulation results enable us to predict charge distribution, dynamic of the potential distribution, electric field and electron beam-induced component of polarization at the given experimental parameters. These findings can be used to control polarization switching in ferroelectrics electron beam-irradiated by the SEM techniques.

Abstract: The aging characteristics and influence of electric field poling on the phase transitions in (1-x)Pb (Mg_1/3Nb_2/3)O₃-xPbTiO₃ (PMN-xPT) [110]-oriented single crystal were examined through temperature dependent complex capacitance study. In addition to two phase transition anomalies exhibited by the crystal in the virgin state, other phase transition instabilities were observed in the complex capacitance of the crystal under the external applied electric field. The aging behavior deviated from the linear logarithmic law and followed the stretched exponential expression typical for relaxor ferroelectrics. Moreover, aging decreased with frequency while it became faster with increase in temperature towards the paraelectric – ferroelectric structural phase transition temperature.

Abstract: In photonic crystals composed of ferroelectrics, the hybrid bands with corresponding to new additional band gaps are expected to appear around the Brillouin zone’s center and boundaries. In this hybrid bands, the group-velocity anomaly modes related to the phonon-polariton branches are expected to be discovered. Propagation characteristics of the group-velocity anomaly modes in the hybrid bands of one-dimensional photonic crystals fabricated by ferroelectric Li₂Ge₇O₁₅ single crystals are discussed on the basis of finite element method and finite-difference time-domain numerical analyses and experimental results obtained by terahertz time-domain spectroscopy. It is founded that the electric-field intensity of the standing-wave mode at the end point of the dielectric band branch is found to be localized around all of the ferroelectrics plates in the photonic crystal. In contrast, group-velocity anomaly mode in the vicinity of the standing-wave mode is strongly localized around the first ferroelectrics plate on the incident side and decays as it propagates through the following ferroelectrics plates.

Abstract: In the presented work composite ferroelectric/ferrimagnetic ceramics have been obtained and described. The investigated material is based on PMN-PT powders and Ni-Zn ferrite powder. The Powders of ferroelectric component (i.e. (1–x)PMN-(x)PT with x from 0.25 to 0.40 with step 0.03 were synthesized using the sol-gel method. The magnetic component i.e. nickel-zinc ferrite was obtained from oxides using the classic method of obtaining ceramics. The compositions of PMN–PT used by us have rhombohedral or tetragonal symmetries, or belong to morphotropic region. The final ceramic composite samples were obtained using the classic method of ceramic technology with calcination route and final pressureless densification using free sintering. In this paper, XRD, EDS dielectric and magnetic properties have been investigated and described for the obtained composite ceramic samples.