Papers by Keyword: Glycidyl Methacrylate

Abstract: The main objective of this work was to produce grafted cellulose from coconut dregs. In this work, cellulose isolated from coconut dregs was grafted with various concentrations of glycidyl methacrylate (GMA). Cellulose-GMA prepared using 20% of ​​GMA produced the highest grafting percentage, where the grafting percentage reached 299.2%. The obtained grafted cellulose was characterized by FT-IR, XRD, and TGA. FT-IR spectra confirmed the formation of cellulose-GMA and XRD data showed a slight decrease in the crystallinity of cellulose after GMA addition from 6.98% to 6.02%, 5.57%, and 5.83% for cellulose-GMA prepared using 15%, 20%, and 25% of GMA, respectively. Cellulose-GMA showed higher thermal stability than cellulose, that potentially used in some applications at higher temperatures.

Abstract: The copolymerization of 1,1,1,3,3,3-hexafluoroisopropyl acrylate (HFIPA) and glycidyl methacrylate via reversible addition-fragmentation chain transfer (RAFT) process was investigated. 2-cyano-2-propyl dodecyl trithiocarbonate (CPDT) was used as chain transfer agent. It is turned out that CPDT and polymeric chain transfer agent obtained based on HFIPA and CPDT provide a good control over molar mass characteristic of copolymers (Đ = 1.05). Reactivity ratios were found to be r₁(GMA) = 1.57 and r₂(HFIPA) = 0.05 by Fineman–Ross model.

Abstract: The modified poly (butylene succinate) (PBS), namely, PBS-g-MA and PBS-g-GMA were prepared in order to be used as a compatibilizer for PBS composites. The grafting of maleic anhydride (MA) or glycidyl methacrylate (GMA) onto PBS was carried out using a twin-screw extruder. The grafting reactions were confirmed by spectroscopic analysis. Comparing with MA, it was found that GMA can be effectively grafted on PBS. The PBS-g-GMA was successfully used for PBS composites to enhance thermal properties. Furthermore, it was found that the incorporation of compatibilizer increased the melt viscosity of PBS composites.

Abstract: Poly (butylenesadipate-co-terephalate) (PBAT) was modified by melt grafting glycidyl methacrylate (GMA) in the presence of benzoyl peroxide (BPO) in a Haake mixer; and the various properties of blends of PBAT/thermoplastic starch (TPS) using GMA-grafted PBAT (PBAT-g-GMA) as compatibilizer were investigated. The blends comprising TPS content ranged from 20wt% to 50wt%. Thermal properties and thermal stability were characterized with DSC and TGA, respectively. The morphologic results indicated that the interfacial adhesion of PBAT/TPS blends was improved by PBAT-g-GMA. In comparison with the uncompatibilized blends, the tensile properties of compatibilized blends were significantly enhanced, particularly at a high content of TPS (i.e., 40wt% and 50wt%).

Abstract: P(BA-St), a good modifier for epoxy resin, was prepared by BA and St in situ polymerization. The modified resin system was based on diglycidyl ether of bisphenol and methyl tetrahydrophthalic anhydride, tris (dimethylaminomethyl) phenol. The influence of the copolymer on mechanical properties and thermal performance of the systems was studied. When 15 wt% of the BA/St with a weight ratio composition of 7.5/7.5 was added to epoxy, high performance modified epoxy resin was obtained.

Abstract: A new solid polymer electrolytes (SPE) comprising copolymer of poly(glycidyl methacrylate, GMA) and (ethyl methacrylate, EMA) as polymer host and LiClO₄ as dopant was prepared by solution-casting technique. The copolymer was prepared by photopolymerization method and was characterized using NMR. The SPEs were characterized using electrochemical impedance spectroscopy (EIS), fourier transforms infrared (FTIR) and X-ray diffraction (XRD). The highest conductivity achieved was 4.0x10^-4 at 373K with highest conductivity at room temperature (2.7x10ˉ5 S cm^-1 at 30 wt. % of LiClO₄). The active coordination site for the cation (Li⁺), three electrons donating functional carbonyl, ether and epoxy group of the GMA-co-EMA host have been evaluated base on their properties that were recorded in (FTIR). The structural analysis showed reduction in copolymer crystallinity phases at its highest conductivity

Abstract: (2-oxo-1,3-dioxolan-4-yl)methyl-2-methylprop-2-enoate (DOMA) was synthesized from glycidyl methacrylate (GMA) and carbon dioxide, which can be further polymerized into water-based non-isocyanate polyurethane(NIPU). The structure of DOMA was characterized by IR spectra, 1H-NMR and 13C-NMR analysis. The effects of the catalysts, reaction temperature, pressure and duration on the yield of DOMA were enquired in detail. It was shown that TBAB and ZnI2 used as catalysts, reaction temperature, pressure and duration set as 110°C, 1.2 MPa and 4 hr respectively, the yield could reach 76.5%.

Abstract: Compatibilization between polypropylene(PP) and wood-flour was achieved by means of direct reactive extrusion of glycidyl methacrylate(GMA), PP, wood-flour, and other additives. Impact cracking surfaces of the PP/wood-flour composites(WPCs) was observed via scanning electron microscope(SEM), and mechanical properties of the WPCs were tested. The effect of comonomer styrene(St) and antioxygen triphenyl phosphite(TPP) on the reactive compatibilization was also evaluated. Experimental results indicated that the anchoring strength of interface in the composites was obviously strengthened after direct reactive extrusion. The tensile and flexural strength of the WPCs were obviously improved, but the elongation at break and notched impact strength slightly declined after reactive compatibilization by GMA and dicumyl peroxide(DCP). The addition of St and TPP improved the mechanical properties of the WPCs. At 1.5% of GMA, 0.3% of DCP, 1.5% of St and 1% of TPP in the extrusion composition of WPC, the tensile strength, flexural strength, elongation at break and notched impact strength respectively increased by 39%, 31%, 28% and 29% comparing to those of the WPC without reactive extrusion.

Abstract: Five groups of polyacrylate dispersion are prepared with emulsion polymerization technique. Methyl acrylate (MA), ethyl acrylate (EA), butyl acrylate (BA) and styrene (St) are employed as basic polymerizing monomers; acrylic acid (AA) and glycidyl methacrylate (GMA) as reactive monomers; sodium dodecylsulfate (SDS), composite fatty alcohol ether polyethylene oxide (composite AEO) as emulsifier and ammonium persulfate (APS) as initiator. The polymerizing monomers and their charge ratio, pH of pre-emulsions and product emulsions as well as the dosage of ecological cross linker GMA are changed for their effects on the reaction conversion rate, gelatinization rate and staining resistance, yellowing resistance and water tolerance of samples. The studies show that the pH value of pre-emulsion and product emulsion as well as GMA content act on remarkable effects on the application properties of the ecological polyacrylate pigment binder.

Abstract: A novel composite, wood-polymer composite, was fabricated by polymerization of functional monomers within wood porous structure. The wood was a fast-growing plant wood, Micheliamacclurel wood, which was rarely reported in previous studies, and two functional monomers, glycidyl methacrylate and ethylene glycol dimethacrylate, were novelly employed. The monomers, added with a few Azo-bis-isobutryonitrile as initiator, and maleic anhydride as catalyst, were first impregnated into wood pores under vacuum/pressure conditions, and then in-situ polymerized into polymers through a catalyst-thermal treatment. After the processes, wood-polymer composite was resulted. SEM and FTIR analysis for the composite indicated that the monomers polymerized into solid polymer, which fully filled up wood pores, and the resulted polymer grafted onto wood matrix, resulting in good interface combination between polymer and wood matrix. Such composite with satisfactory interface can be potentially applied as structural material in construction field.