Papers by Keyword: Heating Rate

Abstract: The electrospinning combined with the sintering process were used to prepare carbon-coated lithium iron phosphates (LiFePO₄/C) cathode materials for lithium ion batteries (LIB). In sintering process, different procedures were used to synthesize the LiFePO₄/C composite materials. The effect of the sintering time and heating rate on the structure, surface morphology and carbon content of LiFePO₄/C composite materials were investigated by wide angel X-ray diffraction (WXRD), scanning electron microscope (SEM), and elemental analysis (EA) techniques. It has better structure when the sintering process is as follows: heating rate is 2 oC min^-1 and pre-oxidized time is 3h at 280 oC and carbonized time is 8h at 700 oC.

Abstract: In general, firing process in brick manufacturing could affect the properties, colours and appearance of the brick. The main purpose of this study was to evaluate the effect of different heating rates on physical and mechanical properties during the firing of standard bricks and bricks incorporated with cigarette butt (CB). In this investigation, two different heating rates were used: slow heating rate (2oC min^-1) and fast heating rate (5oC min^-1). Samples were fired in solid forms from room temperature to 1050oC. All bricks were tested for their physical and mechanical properties including compressive strength, initial rate of absorption and density. Higher heating rates decrease compressive strength value but slightly increase the initial rate of absorption and density properties respectively. In conclusion, higher heating rates are able to produce adequate physical and mechanical properties especially for CB Brick.

Abstract: The pyrolysis characteristics of pine powder and polyvinyl chloride (PVC), respectively representing the biomass and plastics components of municipal solid waste, were studied in a thermogravimetric analyzer, and the influence of heating rate on pyrolysis characteristics was also investigated. The pyrolysis temperature was heated from ambient up to 900 °C at different heating rates including 10, 20 and 40 °Cžmin^-1. The pyrolysis of pine powder was composed of two obvious weight loss phases, which were dehydration and the decomposition of cellulose and hemicellulose. The lignin in pine powder decomposed over a broad temperature range until 900°C. The pyrolysis of PVC was complicated, and included the release of hydrogen chloride (HCl), the formation of hydrocarbons. Besides, the additives in PVC decomposed at about 600 °C. The TG and DTG curves of pyrolysis for pine powder and PVC were similar at different heating rates, however, each weight loss phase of pyrolysis was shifted to high temperature with increasing the heating rate.

Abstract: In this paper, the ultimate, proximate and component analyses of the Daxinganling larch bark and xylem were performed and intercompared respectively. The pyrolysis features of the bark and xylem were analyzed by using the differential thermal thermo-gravimetric analyzer (TG). The influences of heating rate on pyrolysis features were discussed. The results show: (i) the content of H is a little more in the xylem than the bark and the content of ash in the bark is two times of the xylem and the content of fixed carbon in the xylem is two times of the bark. The content of alcohol-benzene extract is significantly more in the bark than the xylem and the glarson lignin in the bark is two times of the xylem but the hemicellulose in the xylem is three times of the bark; (ii) the process of the bark pyrolysis has two pyrolysis areas, but the xylem has a only pyrolysis area, however, the main pyrolysis interval of temperature of the bark and xylem are between 420K to 720K, in which the weight-loss of bark is 87-91% of the full weight-loss and the xylem weight-loss is 91-95% of the full weight-loss. (iii) the DTG peak of the xylem is behind 25 K of bark, and the DTG peak of the bark is-0.47 but the xylem-0.93. (iv) the curves of the TG and DTG move to the side of the higher temperature a bit following the heating rate increased, while the main pyrolysis areas are wider.

Abstract: In order to study the performance of steel beam in the cooling process, a series of numerical analysis has been carried out in this paper. The solid model of the beam was established firstly using finite element method, the beam was heated and cooled gradually under the certain uniform load, then the internal forces and deformation of the beam were analyzed in the whole fire process. Based on this, the parameters of the highest temperature, heating rate and the cooling rate were changed, and their affect on the beam performance was studied by comparing.

Abstract: A modified model describing the austenite reaction was developed that took into account the effect of heating rate. The model considered the variation of activation energy during non-isothermal heating and one set of model parameter was adequate to predict the formation of austenite. To verify the theoretical model, the process of austenite formation during continuous heating in Cr5 roller steel with pearlite and ferrite mixed initial microstructure was analyzed by dilatation experiment. The results show that a strong logarithmic relationship between apparent activation energy and heating rate. Experimental kinetic transformations as well as critical temperatures of austenite reaction are in good agreement with the calculations. The model can be used to describe the transformation kinetics at an intermediate heating rate.

Abstract: The cold rolled band of the niobium stabilized type ASTM 430 ferritic stainless steel with 85 % thickness reduction was annealed with heating rates of 0.10, 6.8, 23.5 and 41.5 °C/s and a soaking time of 24 s. The changes in microstructure and texture were followed by interruptions in the annealing cycle at temperatures of 780, 830 and 880 °C. Annealing at the lower heating rate was more effective for the development of γ-fiber than the annealing performed with high heating rate. The increased rate of heating provided an increase in the onset recrystallization temperature, a reduction in average grain diameter and a more homogeneous distribution throughout the thickness. The specimens with higher volume fraction of the γ-fiber annealed with low heating rate showed a high average coefficient of anisotropy R =1.99.

Abstract: The growth behavior of 300M steel was investigated on a Gleeble-3500 simulator at the heating temperatures ranging from 1273 K to 1453 K and the heating rates ranging from 0.83 K/s to 40 K/s. The grain size of austenite was measured by using SISC IAS V8.0 image analysis software on Olympus PMG3 microscope. The experimental results showed that the coarse grains of austenite occurred at the heating temperature above 1413 K and the grain size of austenite increased with the increasing of heating temperature and decreased with the increasing of heating rate. The grain boundaries of austenite became flat and the angel of grain boundaries tended to 120˚ with the increasing of heating temperature. The grain boundaries of austenite increased and changed from flat to bend with the increasing of heating rate.

Abstract: The dynamical behavior of the reverse martensitic transformation has been numerically simulated with an atomistic model and compared with experiments in Cu-Zn-Al alloys. Starting from different configurations of the martensitic variants (varying mainly their mean size), the transformation to austenite was studied as a function of the heating speed. Both, experimental and numerical results show that at low velocities there is no dependence of the transition temperatures, whereas at higher speeds they gradually increase. Simulations allow us to have an insight of the underlying processes during the transition to austenite. They also show that a heating speed independent transition can only be obtained when a microstructure of very small variants is present.