Authors: Mark Anthony R. Agbayani, Marissa A. Paglicawan, Marianito T. Margarito, Blessie A. Basilia
Abstract: The study involves the use of high density polyethylene (HDPE) as a filament for 3D printing. Considering the warpage and adhesion problem of HDPE on the build plate during 3D printing, this was addressed through the incorporation of wood flour compatibilized with styrene-ethylene-butylene-styrene grafted maleic anhydride (SEBS-gMAH). The composite wood-HDPE (cHDPE) was studied to observe warpage changes. Using different SEBS, heat bed parameters and identification of the suitable print heat beds for HDPE was conducted. Results from the mechanical testing show that the compressive strength and elastic force of virgin HDPE (vHDPE) increases with infill percentage, while the same properties for cHDPE increases up to 50% infill density/percentage then decreases as it approaches 100% infill percentage. Digital microscopy imaging shows that poor layer adhesion initiated the poor compressive performance of cHDPE. Warp studies reveal that wood flour significantly decreases warping of HDPE by 42.88% at 50% infill density. While different SEBS brands show similar effectiveness as heat beds in reducing warping of HDPE during printing.
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Authors: Alyssa Sarah E. Arenas, Chelsea Mae L. Escutin, Persia Ada N. de Yro
Abstract: Polymers that are low-cost, lightweight, durable, and eco-friendly can be considered as one of the aims of recent research studies to solve environmental problems, especially those caused by the abundance of plastic wastes. The notable mechanical properties of such polymers could be achieved with reinforcements such as using natural fibers like hemp, sisal, wood-fiber, jute, and the focus of the study, rice husk. Using high-density polyethylene (HDPE) as the matrix, the addition of rice husk fillers was able to improve the mechanical properties of the polymer composites. However, the microstructure of the composite seems to be uneven, and voids could be observed. This must be due to disturbances or inhomogeneity in the interfacial dispersion of the filler (rice husk) and the matrix (polyethylene). This paper aims to introduce a poly (ethylene glycol) methacrylate (PEGMA) compatibilizer that can help provide stronger interfacial dispersion between the filler and matrix to improve the mechanical properties and morphology of the composite. It also offers a broader perspective regarding the possible component combinations and ratios in fabricating polyethylene which may, later on, lead to the manufacture of more efficient polyethylene-based products.
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Authors: Zheng Lu Ma, Jui Chin Chen, Chi Hui Tsou, Yan Mei Wang, Xin Yuan Tian, Chen Gao
Abstract: High-density polyethylene (HDPE) is used as the matrix and attapulgite (ATT) is used as the reinforcing phase. HDPE/ATT nanocomposites are prepared by melt blending. The effect of ATT content on the mechanical properties, water absorption and morphology of HDPE/ATT composites was studied. The results show that adding a small amount of ATT can improve the mechanical properties of HDPE, but excessive addition will reduce the mechanical properties of HDPE. The water absorption and contact angle test results show that as the ATT content increases, the composite material becomes more and more hydrophilic. After joining ATT, the performance of HDPE / ATT composite material has a significant improvement effect, and it is believed that it will have broad application prospects in the future.
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Authors: Xu Li, Ling Yuan, Ying Jun Zhang, You Li Yao, Chi Hui Tsou, Ya Li Sun
Abstract: In this paper, multiwall carbon nanotube-ZnO (MWCNT/ZnO) was melt-blended with polyethylene (PE) by a Haake-Buchler Rheomixer. The mechanical properties, thermal stability and dispersion degree of the composite materials was characterized. Differential scanning calorimetry, X-ray diffraction analysis, thermogravimetry, tensile test and SEM were carried out. The results showed that with the addition of MWCNT/ZnO, the crystallinity and thermal degradation temperature of PE changed. 0.2phr MWCNT/ZnO/PE exhibited crystallinity that was 10% higher than PE. With the addition of MWCNT/ZnO, the tensile strength of PE decreased gradually, but the elongation at break increased first and then decreased. When MWCNT/ZnO content is 0.2phr, the elongation at break of the composite is close to 532.21%, which is 116% higher than that of pure PE.
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Authors: Aleksandr Korotkov, Vitalii A. Korotkov, Vasilii Fedorov, Stefan Vöth
Abstract: The possibility and efficiency of the use of high-density polyethylene as a binding substance in grinding wheels for cutting-off, as well as for finish cylindrical grinding, is researched. It is determined that: - breaking mechanical strength of such circles ensures their safe operation at maximum operating speeds of 30–35 m/sec; - the use of high-density polyethylene as a binding substance in cutting wheels is not advisable, due to intensive wear and low cutting power of these tools; - wheels for finish cylindrical grinding on the basis of high-density polyethylene and hollow spherocorundum as abrasive grains in a number of key indicators (cutting power, roughness of machined surfaces) are highly competitive with grinding wheels on a bakelite bond or are comparable to them, and significantly exceed the latter in terms of wear resistance.
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Authors: Rohani Binti Mustapha, Mohamad Awang, Siti Noor Hidayah Binti Mustapha
Abstract: In this study, the effect of different treatments and the addition of maleic anhydride grafted polyethylene (MAPE) on the mechanical and thermal properties of Alpinia galanga (AG) fiber/high-density polyethylene (HDPE) composites were investigated. The AG fibers were pretreated with sodium hydroxide (NaOH) and then treated with 3-aminopropyltriethoxysilane (3-APE) as well as treated with p-toluenesulfonic acid (PTSA). The samples were first prepared by melt blending method before being injected to specimen dumbbell shape using an injection moulding machine. Three different fiber loadings were studied, such as 3, 6, 10 and 15 wt%. The tensile test results revealed that the NaOH and 3-APE treatments increased the tensile strength of AG/HDPE composites with the addition of MAPE at all fiber loadings, whereas tensile strength of PTSA treatment improved at 3 wt% fiber loading. The morphological studies confirmed a better adhesion between treated fiber and HDPE matrix with the inclusion of MAPE. Thermal analysis study showed that NaOH, 3-APE and PTSA treatments on AG fibers improved the thermal stability of the composites with an addition of MAPE by delaying the thermal degradation of the composites. The water absorption test proved NaOH and 3-APE treated fiber exhibited lower water absorption than other composites with the inclusion of MAPE. Overall, the results indicated that chemical treatment with NaOH and 3-APE with the presence of MAPE is a good approach towards the development of natural fiber composites.
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Authors: Emi Erawati, Hamid Hamid, Rosyad Adrian Febriansyar
Abstract: Plastic is materials that are not easily broken down, so it can cause a variety of complex problems such as loss of natural resources, environmental pollution, and depletion of landfill space. Plastic favored by the public is Polypropylene (PP) and High Density Polyethylene (HDPE) for example, food storage, transparent drinking glasses and drinking bottles for babies. This will be a problem in the future. Some alternatives used to reduce the volume of plastic waste are the thermal transformation process which is divided into three types of processing, namely combustion, gasification, and pyrolysis. Pyrolysis is a process of thermal degradation of long chains into smaller molecules. The process of pyrolysis in this study used a variety of catalysts (without catalyst, 5%, 10%, 15%, and 20%) and used variations in particle size, namely size I (30 cm3); size II (7.5 cm3); size III (1,875 cm3) weighing 350 grams of plastic cups and 350 grams of bottle caps. Pyrolysis run for 100 minutes and took the result of pyrolysis every 20 minutes interval. The test carried out by using proximate analysis, fuel specification analysis, and GC-MS. Based on the result of research conducted on the pyrolysis process of a mixture of HDPE and PP variations of catalysts, it obtained optimum liquid and gas yields of 98.57% and 1.43%. Besides, in the size variation, the optimum liquid and gas yield was 96.57% and 3.43%. The proximate result has fulfilled the conditions set by the value of ash content, fly substance, and carbon bound 0.15%; 99.57%; 0.28%. In the GC-MS (Gas Chromatography-Mass Spectrometry) test the highest % area was 39.18% with C9H18 or 2,4-dimethyl-1-heptane compounds. The best simulation result obtained the value of activation energy and reaction speed for liquid and gas in the variation of the catalyst of (87,930.07; 101,527.17) J/mol and (2.03 x 102; 3.74 x 103).
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Authors: Aleš Mizera, Tomáš Fiala, Miroslav Manas, Pavel Stoklásek, Martin Ovsik
Abstract: Commodity polymers are a common part of everyday life. They consist mainly of polyolefins such as polyethylene, polypropylene. They are primarily used for ease of processing, cost and especially chemical resistance. The disadvantages of these polymers are low mechanical properties as well as temperature resistance. Any improvement in the mechanical properties can extend the application possibilities of the commodity polymers to the areas reserved for the construction polymers. This paper deals with changing two injection moulding process parameters - melt and mould temperature to high-density polyethylene (HDPE) surface hardness. HDPE hardness was measured using the method of Depth-Sensing Indentation (DSI) on three different instruments (ultranano-, nanoand micro-hardness tester). It has been found that as the melt and mould temperature increases, the hardness slightly increases.
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Authors: Mohammad Sayem Mozumder, Anusha Mairpady, Abdel Hamid I. Mourad
Abstract: Polymeric nanocomposites have proven to be excellent candidate as biomaterials. However, materials and approaches used to improve the mechanical property of the polymer are still under scrutiny. In this study, improvement of mechanical property upon addition of nanotitanium oxide (n-TiO2), cellulose nanocrystal (CNC) and two different types of coupling agent was analyzed. Influence of the individual factors and its interaction with tensile strength was evaluated using analysis of variance. From the analyses of main effect and interaction effects, it could be concluded that n-TiO2 and CNC have major influence on the improving mechanical properties. Moreover, the coupling agent and compatibilizing agent did not have considerable effect on the mechanical properties. The central composite design was used to evaluate the best combination of n-TiO2 and CNC to be experimented. The responses were modeled and optimized using response surface methodology (RSM) and artificial neural network (ANN). The predicted data was in agreement with the experimental data. The modeling accuracy and efficiency is evaluated based on regression coefficient (R square value). Both the method had recommendable R square value. However, the R square value of the Artificial neural network (R2>95%) was higher than Response surface methodology (R2>70 %).
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Authors: Ales Mizera, Miroslav Manas, David Manas, Pavel Stoklasek, Lenka Hylova
Abstract: This study deals with high-density polyethylene (HDPE) which was put to the drop weight and tensile impact tests. HDPE is a semicrystalline thermoplastic polymer which is used in common applications such as packaging, consumer goods and car tanks. The injection moulded HDPE samples were subjected the drop weight impact test at different potential energies and the results were subsequently evaluated and discussed. The second test was performed on pendulum test machine where impact resistance in tensile was studied. It was found out that HDPE is a low-cost material with high-performance properties in the field of the impact resistance which was evaluated in penetration and tensile test where the plastic deformation creates.
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