Papers by Keyword: High Refractive Index Glass

Abstract: In this paper, BaO-ZnO-TiO₂-SiO₂ is used as the research system of high refractive index glass, and IR, XRD and DTA are used to study the structure, thermal behavior, crystallization and chemical stability of different glasses when B₂O₃ gradually replaces SiO₂. The results show that when B₂O₃ replaces SiO₂, glass still has an amorphous structure, and the density of glass shows a decreasing trend with the increase of B₂O₃ content. With the increase of B₂O₃ content, the boron-oxygen tetrahedron gradually transforms into the boron-oxygen triangle, which makes the overall crystallization of the glass structure weaken. The results show that the density, refractive index and water resistance of glass beads without B₂O₃ are the best. With the increase of B₂O₃ content, the activation energy of crystallization decreases, the potential barrier to be overcome for crystallization decreases, as the same time the phenomenon of glass crystallization is obvious. Keywords:High refractive index glass; BaO-ZnO-TiO₂-SiO₂; Crystallization; Chemical stability

Abstract: The effect of varying the TiO2–content on the lead-free high refractive index glass based on 25 wt% barium carbonate added in replacing lead oxide was prepared and its physical, optical, and electrical properties were investigated. Seven glass samples were synthesized and characterized by using an analytical balance, a refractometer, a LCR meter and an X-ray diffractometer. Specific gravity, refractive index, and dielectric constant increased linearly as the increasing of the TiO2-content. The amorphous state of modification of glass structure due to TiO2 addition was confirmed.

Abstract: Red colored gold ruby glass used for decorations in ancient times was actually gold nanotechnology at work by the addition of gold particles into molten lead glass. Most of high refractive index glasses are based on lead-bearing silicate glass. High refractive index lead glasses (HRLG) made from local sands and lead oxide were successfully fabricated both in laboratory and larger scales. In this study, gold metal was doped into the lead glass mixtures. Morphology of the prepared lead glass was observed using SEM and compared with that of the red colored Ancient Thai Glass (ATG). It was found that the fabricated red colored HRLG yielded similar color and clarity to the red colored ATG. From electron micrographs, the presence of gold in lead glass was in the form of nanoparticles. The optical properties of the glasses were also examined.

Abstract: Many difference useful and decorative articles have been made from glasses over the centuries, especially lead-containing glasses. Due to harmful effects of lead from glass fabrication process on human beings and considering the health as well as the environmental issues, many researchers tried to produce leadless glasses using some heavy chemical elements such as barium, bismuth and zirconium. Nowadays, barium compounds seemed to be satisfactory and to be able to increase the refractive index. For production of high quality crystal glasses with high refractive index in Thailand, most raw materials including high quality sand have been imported. Because, Thailand, in fact, is rich in many kinds of raw materials for glass manufacturing, therefore, this work is set up to study the fabrication of the lead-free high refractive index glasses using local sand and barite as the main raw materials. After complete melting, the physical and optical properties of the prepared glass samples were determined to compare these properties with those of glasses prepared from foreign sand. It was found that the prepared glasses produced from local raw materials were suitably for restoration, decoration, radiation shielding, as well as glass jewelry. These glasses can be considered as one of the environmental friendly materials.