Papers by Keyword: Hydrogen Doping

Abstract: Vanadium oxide films have been fabricated by the acetylacetonate and triethoxy vanadyl sol-gel methods on silicon substrates, as well as by magnetron sputtering on glass-ceramic substrates. Additional annealing in reducing atmosphere results in formation of vanadium dioxide or mixed phases with a VO₂ predominance. The obtained films demonstrate the metal-insulator transition and electrical switching. In the films produced from triethoxy vanadyl, the peculiarities of electrical properties are related to the size effect, heterophase character of vanadium oxide films, and different types of charge carriers in the bulk of nanocrystallites and on their surfaces. Also, the effect of doping with hydrogen by means of plasma-immersion ion implantation on the properties of vanadium dioxide is explored. It is shown that the transition parameters in VO₂ thin films depend on the hydrogen implantation dose. At doses exceeding a certain threshold value, the films are metallized, and the phase transition no longer occurs.

Abstract: Water vapour interacts with growing chromia scales in several different ways. Formation and volatilisation of Cr2O2(OH)2 is shown to account quantitatively for chromium loss from thin alloy foils reacted with air-steam mixtures over periods of 103 h. In the shorter term, water vapour is shown to refine the grain structure of Cr2O3 scales grown on Ni-25Cr. Scaling kinetics are at the same time accelerated by an additional, larger contribution to diffusion by a grain boundary species, either OH- or H2O. A slight increase in scaling rate observed at low water vapour partial pressures in H2/H2O gases is thought to be due to hydrogen doping.

Abstract: In a hydrogen-doped metallic glass, there appear low-temperature and high-temperature internal friction peaks respectively associated with a point-defect relaxation and the crystallization. The high-temperature-side slope of low-temperature peak and also the low-temperature-side slope of high-temperature peak enhance the background internal friction near the room temperature. A hydrogen-doped Mg-base metallic glass was proposed as a high-damping material to be used near and somewhat above the room temperature. Stability of the high damping was also checked.