Papers by Keyword: Interstitials

Abstract: Ti and its alloys are widely used as biomaterials. Their main properties are excellent corrosion resistance, relatively low elastic modulus, high specific strength, and good biocompatibility. The development of new Ti alloys with properties favorable for use in the human body is desired. To this end, Ti alloys with Mo, Nb, Zr, and Ta are being developed, because these elements do not cause cytotoxicity. The presence of interstitial elements (such as oxygen and nitrogen) induces strong changes in the elastic properties of the material, which leads to hardening or softening of the alloy. By means of anelastic spectroscopy, we are able to obtain information on the diffusion of these interstitial elements present in the crystalline lattice. In this paper, the effect of oxygen on the anelastic properties of some binary Ti-based alloys was analyzed with anelastic spectroscopy. The diffusion coefficients, pre-exponential factors, and activation energies were calculated for oxygen and nitrogen in these alloys.

Abstract: As a result of the work of Frank-Read dislocation source the shear zone is formed. It is filled with deformation defects forming as a consequence of the dynamic features of the motion of dislocation loops and due to the interaction of shear forming dislocations with dislocations of non-coplanar slip systems. The accumulation of jogs on screw segments leads to the fact that the edge segments are moving faster than the screw segments so the shear zone is swept out generally by screw segments. The expressions of the intensities of the deformation defects accumulation in shear zones are given in the article. The point defects plays special role in the formation and evolution of misorientation substructures into deformed monocrystals, polycrystals and nanocrystals.

Abstract: Because of their low elasticity modulus, titanium alloys have excellent biocompatibility, and are largely used in orthopedic prostheses. Among the properties that are beneficial for use in orthopedic implants is the elasticity modulus, which is closely connected to the crystal structure of the material. Interstitial elements, such as oxygen, change the mechanical properties of the material. Anelastic spectroscopy measurements are a powerful tool for the study of the interaction of these elements with the metallic matrix and substitutional solutes, providing information on the diffusion and concentration of interstitial elements. In this study, the effect of oxygen on the anelastic properties of alloys in the Ti-15Mo-Zr system was analyzed using anelastic spectroscopy measurements. The diffusion coefficients, pre-exponential factors, and activation energies of these alloys were calculated for oxygen.

Abstract: In multicrystalline silicon for photovoltaic applications, high concentrations of iron are usually found, which deteriorate material performance. Due to the limited solubility of iron in silicon, only a small fraction of the total iron concentration is present as interstitial solute atoms while the vast majority is present as iron silicide precipates. The concentration of iron interstitials can be effectively reduced during phosphorus diffusion gettering (PDG), but this strongly depends on the size and density of iron precipitates, which partly dissolve during high-temperature processing. The distribution of precipitated iron varies along the height of a mc-Si ingot and is not significantly reduced during standard PDG steps. However, the removal of both iron interstitials and precipitates can be enhanced by controlling their kinetics through carefully engineered time-temperature profiles, guided by simulations.

Abstract: Metal injection molding (MIM) is a well-established, cost-effective method of fabricating small-to-moderate size near net-shape metal components. In the MIM of titanium (Ti), one of the key points in the process is the interstitial contamination, especially oxygen. This study examines the sources of interstitial contamination during the metal injection moulding of commercially pure (CP-Ti) and Ti6Al4V (Ti-64) alloys. Also presented is a route to control and minimize the contamination in the sintered parts. The effect of the levels of oxygen contamination on the mechanical parts is also presented in the work.