Papers by Keyword: Iron

Abstract: The importance of iron and steel to any nation’s economy cannot be overstressed. This paper X-rays the importance of iron and steel to the development of any nation’s economy with reference to China, South Africa and Nigeria. It discusses that iron and steel companies are needed to provide high-quality and efficient services. Benefits that can be derived from iron and steel which includes; revenue generation for the sustenance of nation’s economy, employment generation, industrialization are discussed. Government policy, lack of commitment on the part of policy makers of this country among others have been outlined as barriers that militate against the development of iron and steel in the country. Commitment, implementation of every policy formulated for the industry and partnership with experienced private sector was identified as among the solution to move the sector forward. Keywords: Industry, Iron and Steel, Economic, Production, Consumption, Policy

Abstract: Infant malnutrition remains a major health problem in West Africa, particularly among children aged 6 months, the crucial period for dietary diversification. Faced with the predominance of imported industrial flours, which are often expensive, local populations are turning to traditional flours. To improve the nutritional quality of these flours, food fortification, recommended by bodies such as the FAO and the WFP, is commonly used. In this study, the mixture design method was used to formulate an affordable complementary flour, enriched in iron, zinc and vitamin C, from under-exploited local plant resources such as Anacardium occidentale kernel fragments and Parkia biglobosa pulp. An augmented centred mixing design with constraints was used to formulate, model and optimise the iron, zinc and vitamin C content of the infant supplement flour. Modelling of the iron content revealed a synergistically interacting cubic model with a desirability of 0.97, and an average iron content of 14.13 mg/100 g. Zinc content was estimated at 5.78 mg/100 g and modelled by a significant quadratic model. The vitamin C content was better represented by a linear model with a synergistic interaction, with a desirability of 0.97 and an average content of 117.6 mg/100 g, well above the standard of 30 mg/100 g. In conclusion, the optimisation has maximised the iron, zinc and vitamin C content of the formulation, offering an improved nutritional solution for combating infant malnutrition.

Abstract: For the purpose of synthesizing 2D-Material–Magnetic nanocomposites, several new modifications of existing 2D-materials synthesis methods by exfoliation and chemical synthesis from liquid charge are developed. Using them, graphene (G), graphene oxide (GO), reduced graphene oxide (rGO) and hexagonal boron nitride (h-BN) matrix magnetic nanocomposites for the first time are obtained by coating or intercalation their nanoparticles with ferromagnetic iron (Fe) or ferrimagnetic iron oxide – magnetite (Fe₃O₄). These materials are prospective for variety of high tech applications. In particular, h-BN–Fe₃O₄ composite nanoparticles can serve for neutron-capturing boron isotope ¹⁰B effective delivery agents in BNCT (Boron Neutron Capture Therapy) of cancer as they allow the controlling by an external magnetic field targeting to tumor tissue.

Abstract: An experimental method to calculate average charge of metal ions by electrolysis at different temperatures is proposed. Aluminium undergoes dissolution to the Al³⁺ ions at all temperatures. Iron undergoes dissolution to the Fe²⁺ or the Fe³⁺ ions and copper undergoes dissolution to the Cu⁺ or the Cu²⁺. It depends on temperature and electric current density. Direct electric current value and anode mass decreasing were measured during electrolysis into concentrated NaCl solution in water (5 mol/kg or 23.1%, freezing point equals -22°C, pH 6.5–7.5) at room temperature and 100°C. The average charges of copper, iron, and aluminium ions were calculated using Faraday’s law of electrolysis at electric current density 3,000 A/m² (or 30 A/dm²): +3 for aluminium; +2 for iron; and +1 for copper at room temperature, and +3 for aluminium; +2 for iron; and +1.5 for copper at temperature 100°C. The main condition was z_Al=3. We concluded that calculations of the average metal ions charges, z_Fe and z_Cu, were correct since z_Al=3. The result is as follows: the Al³⁺, the Fe²⁺, and the Cu⁺ ions dissolve into concentrated NaCl solution in water at room temperature; the Al³⁺, the Fe²⁺, the Cu⁺ and the Cu²⁺ ions (50%/50%) dissolve into the solution at temperature 100°C. We have obtained experimentally and by mathematical modelling that aluminium anodes (cylindrical or spherical) dissolve into the solution more rapidly with temperature increasing during electrolysis accordingly to the Arrhenius law, while copper anodes (cylindrical or spherical) dissolve more slowly with temperature increasing from room temperature to temperature 180°C like “inverse Arrhenius law”. Iron electrochemical corrosion rate practically does not depend on temperature below 100°C (and, obviously, up to 180°C) like “zeroth Arrhenius law”. The spherical anode effect is greater than the cylindrical anode effect in 1.5 times.

Abstract: Titanium and its alloys are the 5th most common metallic materials used world wide but the markets volume of titanium materials, is difficult to expand due to associated production costs, and the decrease of those costs are critical in order to expand their markets. A possible option is the alloy design, i.e. using low price alloying element, such as iron, chromium, manganese and oxygen, and the selection of other raw materials, i.e. grade of sponge titanium. In beta titanium alloy, Ti-Mo system alloy using ferro-molybdeum was developed by USA company or Ti-Cr-Fe-Al beta alloy were also developed by Japan company. In this paper, those developed alloys were explained. Furthermore, substitution of Ti-10V-2Fe-3Al near beta alloy, presenters are studying about Ti-Mn-Fe-Al alloy.

Abstract: The extraction and processing of silver minerals produce significant amounts of waste, which poses environmental challenges due to their low metal content and the potential release of toxic elements. The study investigates the application of Acidithiobacillus ferrooxidans (AF) bacteria to the bioleaching of these waste materials, with the aim of maximizing the recovery of iron, copper and arsenic. The objectives of the study include characterizing waste materials, optimizing the bioleaching process parameters and evaluating metal extraction efficiency. The samples were leached with additives (CuSO₄ 5H₂O and AgNO₃) to accelerate the kinetics of metal dissolution in solution and reduce the bacterial leaching time. The results showed that samples 1-2 and 2-2 containing additives had higher values of dissolved iron and copper in the leachate compared to samples 1-1 and 2-1 without additive application.

Abstract: Groundwater has become one of the natural sources of water nowadays. Naturally, groundwater contains dissolving materials such as soils, rocks, and minerals, which later release constituents, including iron (Fe²⁺) and manganese (Mn). However, raw groundwater has been found to consist of a high concentration of such minerals, which exceed the Groundwater Quality Standard published by the Department of Environment Malaysia. Initially, the concentration of Fe²⁺ and Mn exceeding the limit mentioned in the standard; 1.0 and 0.2 mg/L, respectively, might affect the quality of the groundwater. Hence, such condition of water needs to be treated before it can be distributed to the user. This study presents the combination usage of alum and potassium permanganate (KMnO₄) in removing Fe²⁺ and Mn in the groundwater. The jar test was the main mechanism used in identifying the best optimum medium dosages (alum and KMnO₄) as well as the best contact time for both mediums to efficiently remove Fe²⁺ and Mn in groundwater. In this study, water samples were taken from Chicha Water Treatment Plant in Kelantan. It can be said that both alum and KMnO₄ managed to remove Fe²⁺ and Mn up to 35% and 45%, respectively when using alum dosage of 12 mg/L and KMnO₄ dosage of 1.5mg/L with a contact time of 40 minutes. In addition, both mediums also managed to remove other parameters such as colour, turbidity, cations, and pH.

Abstract: We study ultrafast magnetization dynamics induced by laser heating using various phenomenological temperature models. The temperature dynamics of the electrons, spins and lattice for thin foils is investigated. Numerical results for the temperature and magnetization dynamics for them are compared with those available in the literature.

Abstract: Iron is a major impurity in many water resources and leads to contamination in drinking water. One technology that can be used to reduce the iron content is adsorption using activated carbon. Activated carbon can be derived from biomass including forestry and agricultural waste. To produce an economic adsorbent, the researcher used bengkirai wood sawdust waste which contains 52.9% cellulose and 24% lignin. This material is treated by physical and chemical activation to produce activated carbon. However, there is no information on the effect of the type and concentration of activator on the performance of bengkirai wood activated carbon in reducing iron content. Thus, the purpose of this research is to understand the effect of activator type and concentration on the performance of activated carbon from bengkirai wood to adsorb iron content. There are five steps in this research which are preparation, carbonization, chemical activation, characterization and performance test. The raw material is prepared by screening to get an uniform size of bengkirai wood sawdust. Then, the uniformed bengkirai sawdust is physically activated in the carbonization step by heating it in the furnace at 600°C for 2 hours. After that, the carbon is activated using acid which are HCl, HNO₃, and H₂SO₄ with concentrations of 0.1 M, 0.3 M and 0.5 M. The characterization done in this study are iodine number test and functional group test using Fourier Transform Infrared Spectroscopy (FTIR). The final step is performance test of activated carbon to adsorb iron in the water by contacting the activated carbon into water containing iron for 1 hour. The concentration of iron in the water is measured using Uv vis spectofometry. The result shows that the carbon activation with H₂SO₄ 0.1 M produce activated carbon with the highest iodine number compared to the other type of activator and concentration. The iodine number for this activated carbon is 839.76 mg/g. However, the activated carbon treated using HNO₃ shows the best performance to adsorb iron in water.

Abstract: The present study investigates the tensile behavior of the two bimetallic composite wires Cu-Al and Fe-Al. The purpose is to understand the deviation their tensile strengths show from the Rule of Mixtures’ prediction. To that end, an experimental-numerical approach was adopted. Following tensile testing of the above cold-drawn composite wires, the manufacturing process (wire drawing) was simulated via finite element analysis. The prominent role of processing-induced residual stresses on the yield strength of cold-drawn products is known. Therefore, a discussion based on the axial tensile residual stress profile was developed. It was concluded that the higher-magnitude-near-surface tensile residual stresses in the Fe-Al wire causes its tensile curve to show a negative deviation from the Rule of Mixtures (RoM). The Cu-Al wire, on the contrary, exhibits a slight positive deviation.