Papers by Keyword: Isothermal Annealing

Abstract: Regularities of change of electrophysical properties of glasses S87-2, S78-4, S78-5, applied in electronic optics had been studied. The correlation between structural changes and electrical conductivity is established. A comparative analysis of the electric current influence on the new phase formation and the time to achieve phase equilibrium in the glasses is carried out.

Abstract: In this work, we have developed a series of amorphous alloy ribbons of Fe₇₅Co₄B₁₃Y₄Nb_4-xNi_x(x=0, 0.5, 1, 2, 3 and 4) which were prepared by industrial purity alloy. Besides, the effects of Ni substitution and isothermal annealing on the saturation magnetization (M_s) and intrinsic coercive force (jH_c) were systematically investigated. The SQUID-VSM data pointed out the M_s has been increased by Ni content addition with largest enhanced by 57 % from 114 emu/g to 180 emu/g. After quickly annealing at the optimal temperature, the M_s reached 199 emu/g and jH_c decreased from 50 Oe to 33 Oe. DSC measurements displayed that this system has a multi-step crystallization in the heating process. Under the premise of maintaining the excellent amorphous forming ability (AFA), the gap between the two crystallization peaks was broadened with Ni addition, which is good to the forming of α-Fe phase at the annealing treatment. And this was also consistent with the X-ray diffractometer (XRD) results. The Scherrer formula calculated results suggested that isothermal annealing has significant effect on size of α-Fe nanocrystals in annealing process, which obvious affect the M_s and jH_c. The annealing temperature and time can not only affect the precipitation of nano-crystalline, but also control the grain size. Hence, an appropriate annealing process is very important to improve the properties of these iron-based nanocrystalline magnetic materials. In conclusion, the results will help us to understand the influence of Ni elements and isothermal annealing on the microstructure and magnetic of Fe₇₅Co₄B₁₃Y₄Nb_4-xNi_x amorphous alloys.

Abstract: In order to eliminating the banded structure in SAE8620H gear steel,an isothermal annealing process and its mechanism has been studied in this paper. Results showed that isothermal annealing process can effectively eliminate banded structure in SAE8620H gear steel.With isothermal temperature 640°C-a certain low temperature indeed high undercooling,and for high nucleation at this temperature resulting in the decrease of nucleation rate difference in all areas,banded structure level decreased to 1 level.When isothermal temperature decreased to 610°C and 590°C,although the undercooling is so high that various regions began to nucleate at the same time,the transition temperature is so low that alloy elements in the regions previously occupied by pearlite bands diffuse faster than other regions,thus proeutectoid ferrite grains in these regions grow faster,regenerating the banded structure .

Abstract: The molecular dynamics simulation studies on the microstructure evolution properties of amorphous Ca₇Mg₃ alloy during the isothermal annealing have been performed. The simulated structure factor S(q) of Ca₇Mg₃ is well agreed with the experimental data. Results indicate that the metallic glass of Ca₇Mg₃ alloy is relaxed into amorphous structure of greater stability in which much more icosahedron structures is formed; interestingly, it is also found that the short short-range order has no change, while the short-range order of the system increases during the isothermal annealing process.

Abstract: The electrical resistivity and the corresponding mechanical properties (hardness) of some 5xxx Al-Mg alloy processed by plastic deformation were investigated. Plastic deformation was performed at room temperature. Isothermal annealing produced a significant change in both the electrical and mechanical properties of the samples. As the annealing time was increased, the resistivity and hardness up to full recovery. The activation enthalpy of migration of defects was determined, was found to be 0.234±0.06 eV, 0.218±0.049 eV, 0.316±0.016 eV 0.232±0.012 eV for 5005, 5251, 5052 and 5754 alloys, respectively.

Abstract: The requirement for curde oil and natural gas is still increasing. It was observed a growing of interested in the exploration and exploatation of unconventional fuels, including shate gas. There is about 3 to 5 trilion cubic meters resources of that type of gas in Poland. The latest data predicts that in addition to gas in the shale is also petroleum. The development of this branch of mining in our country can cause a significant increase in demand for pipes. The results of basic research of experimental steels for pipe line are presented in this article. Analyse of published materials about steels for pipe line was done. The chemical composition of two types of new steels meeting the requirements for X80 and X100 grade plates according API 5L norm were developed. The heat tratment using dilatometer DIL 805A/D were carried out. The influnce of heat temperature before rolling proces on structure of austenite was defined. The heating schemes were proposed for obtaining a high yield, while not allowing the dissolution of the alloying elements inhibit austenite grain overdevelopment. For samples after tests the structure of primary austenite and the size of former austenite grains were determined. The influence of deformation cinditions on structure were determinated, too. The results obtained from the examinations will be used to develop a technology for rolling sheets of pipelines in the category of X80 and X100 according to the API.

Abstract: The industrial development require new materials characterized highest mechanical properties. The conditions of thermo-mechanical treatment proved to highest level of mechanical properties for steels. Another method of making strong materials is to reduce the scale of the microstructure using heat treatment [1]. The paper presents the results of investigation into the effect of time and temperature variations during isothermal annealing on the mechanical properties of high carbon (c.a. 0,8%C) bainitic steel. Chemical composition of that steel (addition Si, Mn, Mo and Cr) obtain high level of tensile strength and good plastic properties. The analyzing of published results of researches of high carbon bainitic steels shown, that transformation of bainite can take between 2 to 60 days within the temperature range 125÷325°C [2,3] Based on results of researches of investigated steel a isothermal annealing in temperature range 200÷300°C were done. The experiments were done for 24, 50 and 100 hours of annealing. After that the mechanical tests were done. A Zwick Z100 testing machine was used for tests. The force and elongation values were recorded. On their basis, the proof stress and tensile strength of the steel tested were determined as a function of annealing temperature. The microstructure were determinated too.

Abstract: In this paper, we report a Fe-based nanocrystalline-amorphous matrix composite synthesised via partially crystallising an amorphous alloy. The microstructure of the composite was characterize. An amorphous rod of 2mm in diameter was initially prepared via injecting the melted Fe₃₆Co₃₆B₂₀Si₄Nb₄ alloy into a copper mould in vacuum, which was confirmed to be completely amorphous by X-ray difraction（XRD）. Differential scanning calorimeteric（DSC）curve shown that the span △Tx of the supercooled liquid region and the reduced glass transition temperature（Tg/Tm）for the amorphous alloy are 40 K and 0.615, respectively. The composite composed of nanocrystalline particles homogeneously dispersed in an amorphous matrix was prepared by isothermal annealing. In this course, the amorphous Fe-based sample was held for different time at different temperature. The types of the nanocrystalline phases obtained in different annealing conditions were characterised by XRD and selected-area diffraction pattern（SAED）.The crystallization behavior of the amorphous Fe-based alloy was discussed.

Abstract: Positron annihilation lifetime (PAL) is one of the most important nuclear techniques used in material science. Electrical measurements are also used in material science. Samples of 25 % deformation have been used for these studies. Both positron annihilation lifetime and electrical measurements were used to determined the activation energy of migration the dislocation in 7075 alloy. The isothermal annealing measurements were performed at 643, 663, 683 and 703 K. The activation energy of migration the dislocation are obtained as 1.35 ± 0.16 eV and 1.25 ± 0.05 eV for positron annihilation lifetime and electrical techniques respectively.

Abstract: Positron annihilation lifetime (PAL) measurement is one of the most important nuclear techniques used in materials science. Electrical measurements are also used in materials science. Both PAL and electrical measurements were used here to determine the activation energy of migration of dislocations in one of the most important engineering aluminum alloys: 2024. Samples of 25% deformed (thickness reduction) material have been used for these studies. The isothermal annealing measurements were performed at 583, 603, 623 and 643K for both techniques. The activation energy of migration of the dislocation was found to be equal to 1.24 ± 0.08eV by using PAL measurements and to 1.35 ± 0.01eV by using the electrical technique.