Papers by Keyword: Lanthanum Hexaaluminate

Abstract: The effect of (i) heterogeneous nucleation by seeding or (ii) doping with neodymium on the formation of lanthanum hexaaluminate was studied during sol to gel conversion. The resultant dried gels were calcined at various temperatures starting from 1100°C to 1600°C for 2 h to study the phase evolution and microstructure.The combined effects of advanced sol gel processing and heterogeneous nucleation promoted the formation of lanthanum hexaaluminate phase at lower temperature (1200°C) than the conventional routes (1300°C). Lanthanum hexaaluminate phase was detected at 1200°C and 1300°C in seeded gel (SG) and unseeded gel (UG), respectively. Heterogeneous nucleation of SG decreases the temperature of formation of lanthanum hexaaluminate by 100°C. Single phase lanthanum hexaaluminate was formed at 1600°C in seeded gel whereas trace of lanthanum monoaluminate phase was still present in UG even at 1600°C.On the doped ones, randomly grown platelets of lanthanum magnesium hexaaluminate form a porous interlocking structure. Presence of various percentages of neodymium oxide significantly modifies the porous interlocking microstructure into self-reinforced, card-house like microstructure. Platelets of rare earth rich magnesium hexaaluminate were grown preferentially more than the stoichiometric rare earth magnesium hexaaluminate at elevated temperature greater than 1450°C. Rare earth rich magnesium hexaaluminate platelets formed the skeleton of a card house structure and the tiny platelets of stoichiometric rare earth magnesium hexaaluminate fill the rest. Lattice parameters of the hexagonal unit cell (c and a) decrease, relative density increases and pore size distribution remained almost unaltered with the increment of doping concentration.

Abstract: The low thermal conductivity of Lanthanum hexaaluminate, abbreviated as LHA, combined with high structural reliability of alumina matrix ceramics attracted our attention to develop a new functionally graded layered LHA-Al2O3-composite, with a LHA and a porosity gradient along the thickness of a bulk oxide ceramic. LHA is formed by in–situ reaction during sintering of the alumina/LHA composite. The high sintering temperature required for completion of LHA formation in LHA-rich layers causes grain growth and a degradation of mechanical strength in alumina-rich layers. Therefore, microwave hybrid heating was investigated as a method to enhance the reaction rate without excessive grain growth. Comparison of conventionally and microwave assisted sintered homogenous composite ceramics with 20–80 volume percent LHA showed that utilization of microwave heating could enhance the solid–state reaction and densification in samples containing more than 20 volume percent LHA. Enhanced microwave absorption in LHA rich layers assisted the sintering of a functionally graded composite at lower temperatures, enabling LHA formation without any abnormal grain growth in alumina rich layers.

Abstract: Lanthanum hexaaluminate (LHA) has superior thermo-chemical stability at temperatures higher than 1000 °C and is a promising competitor to Y-ZrO2-based thermal barrier coatings (TBCs). The yet unresolved problem is control of microstructure of high LHA content ceramics and adjustment of porosity upon, to arrive at a material exhibiting low thermal conductivity at high temperature combined with structural reliability. Therefore, a functionally graded alumina/lanthanum hexaaluminate (FGLHA) with a gradient in composition was developed. The thermal diffusivity and thermal conductivity of FGLHA were compared with the one of the monolithic composite ceramics. The alumina-rich composites showed excellent mechanical properties whereas the LHA-rich composites presented lower thermal conductivity.