Authors: Yue Wang, Peng Zhang, Yun Long Li, Lin Li, Jian Quan Liang, Yuan Gao, Hong Da Zhang, Wei Sun
Abstract: Storage battery is an indispensable energy storage device at present. It is widely applied to industries like electric automobiles due to its advantages such as safety, reliability, low cost, etc. However, like most storage batteries, lead-acid battery has a series of problems in the low temperature environment such as the plunge of capacity, difficulty of charge, and so on, which deeply influence its application effect. To improve the low temperature performance of lead-acid battery, carbon materials could be added to the cathode of lead-acid battery. By measuring the properties like HRPSoC cycle and dynamic charging under different carbon (graphite) content, this article concludes that the addition of carbon material could improve the low-temperature performance of lead-acid battery. When the carbon content is between 0.3% and 0.9%, the improvement effect is relatively better. The research result of this article has a reference function to the design and development of low-temperature lead-acid batteries.
236
Authors: Chuan Min Chen, Jing Zhang, Li Na Zhu, Song Tao Liu
Abstract: Lead-acid batteries were widely used in many industries as important power supply devices for military and civil industries, transport and shipment devices owing to its advantages of low cost,high performance and safety. According to statistics, most lead-acid batteries can reach 1-2 years life under operating conditions, generating millions of used lead-acid batteries each year in China, which caused economic and environmental losses if not properly treated. The changes of physico-chemical properties in the process of operation of lead-acid battery were summarized in this paper. The corrosion and deformation of grids, water loss in electrolyte, aging of separators, corrosion of plates and irreversible sulfation were the main physico-chemical properties changes resulting in battery failure. In the homogeneous acidic medium, the grid of the lead-acid battery corroded away, one side was dotted distribution, and the other side was interlaced net shape. The corrosion of grids and incomplete reaction may lead to the water loss in electrolyte. What’s more, there existed a series of chemical reactions that reducing the battery capacity and leading to the failure of batteries, such as the aging and elastic collision of separators and irreversible sulfation. By analyzing the physico-chemical properties changes in the process of operation, the study supplied the direction for the specification of operating conditions and the extending of service life of lead-acid battery. The basic theories were provided for the repair, regeneration and recovery of lead-acid batteries.
197
Authors: Shoichiro Ikeda, Akinari Nobumoto, Hideo Ono, Shinji Ono, Shinji Kawasaki, Mohamad Rusop
Abstract: The hydrophilic carbon nanoparticles have been produced from synthetic graphite blocks by the electrochemical oxidation method in pure water. The resulting electrolyzed solution contains colloidal carbon nanoparticles (mean diameter is ca. 400 nm) and shows the pH value of around 2.5. The colloidal state of the solution is maintained more than a several years. After evaporation of water from the solution, carbon powders are obtained, which show a high solubility to water, namely the powder is hydrophilic. The electrolyzed solution containing carbon nanoparticles directly used as the electrical conductivity enhancer for the restoring the deteriorated lead-acid batteries by electrochemical method. The hydrophilic carbon nanoparticles were used as the environmental friendly solid-lubricant for the mechanical cutting coolants. In the case of aqueous coolants, the oily substances are used in the emulsion state in usual. By using the hydrophilic carbon nanoparticle suspension, no surfactants and no oily substances are required to maintain the suspension state. However, the cutting coolants are used in the pH values of alkaline state near 10, so the hydrophilic carbon nanoparticle solution has been neutralized by alkaline substances such as alkanolamines. In the case of oily cutting fluids for heavy duties, carbon mamo-particle powders are used after neutralized by basic barium dinonylnaphthalenesulfonate. The aqueous solutions of hydrophilic carbon nanoparticles exhibit the ability of sanitization effects to the cutting fluids and prolong the life times of them.
232
Authors: Van Tsai Liu, Jhih Rong Chen
Abstract: For high-power applications such as electric motorcycles, batteries in series to provide the required voltage is fairly common. The 48V is 12V connected four cells in series for lead-acid batteries of electric motorcycles. After charging and discharging of lead-acid batteries several times, the voltages are often imbalance. Without proper protection, may cause an excessive discharge of lead-acid batteries for early damage. Therefore, lead-acid battery module requires a simple balance circuit to improve battery life in order to avoid over-voltage or under-voltage condition occurs. Energy balance circuit to improve lead-acid battery module matching problems, make the safety and cycle life of lead-acid batteries to improve. This research intends to complete balanced circuit design of lead-acid batteries.
491
Authors: Kuang Cheng Li, Yan Liu, Xiao Ran Guo, Zheng Liu
Abstract: As a complex system, lead-acid batteries are affected by a number of factors, most of the lead-acid battery equivalent circuit models contain a large number of parameters, and the validity and accuracy of the models have a great relationship with the values of these parameters. Therefore, the parameter identification is a very important job of the modeling work. In this paper, we use the 7-HK-182 lead-acid battery for the study, doing charging and discharging experiments of this lead-acid battery, establish an equivalent circuit model, and identifying the parameters of this model, at last, through the simulation, we determine the accuracy of the parameters identification of the equivalent circuit model.
211
Authors: Kuang Cheng Li, Zheng Liu, Ya Long Liu, Yan Liu
Abstract: Lead-acid battery has perfect characteristics, such as good performance, rich raw materials and low prices, it plays an important role as starting power and auxiliary power in vehicles, Because of inadequate understanding internal active material in physical or chemistry reaction in charging process or technical conditions of limit ,the charging methods mainly contents the constant voltage ,constant voltage the current limit, constant current .These methods fail to damages such as overcharging ,short-charging, gas chromatography and high electrolyte temperature. So, this paper analyzes concentration polarization and electrochemical polarization in fast charging based on the MAS theorems. However, pulse discharge technology can change the concentration of ions near the electrode, which speeds up the electrochemical reaction rate and increase the energy into the chemical energy efficiency.
525
Authors: Chun Xiao Yu, Yan Ying Li, Chang Wang
Abstract: Based on the characteristics of semiconductor thermoelectric generation, this paper takes STC12C5410AD MCU as the core, and designs an intelligent lead-acid battery charging and discharging controller. It implements the intelligent switch, overload overcharge protection of charging way, and can automatically switch between power generating system and battery according to battery load circuit. It realizes the effective transformation of heat into electricity, intelligent storage and utilization.
706
Authors: Yu Lin Gong, Hong Zuo Li, Ming Qiu Li, Wei Da Zhan
Abstract: This paper expounds the principle of lead-acid battery intelligent charging system, design the main circuit of the intelligent charging system, the positive and negative pulse charging circuit, control circuit and software design of intelligent charging system. Experimental results show that the system USES intelligent charging method can effectively improve the charging efficiency of battery and prolong the service life of the battery, can be widely used in lead-acid battery charging system, which has a broad prospect of industrialization and social benefits.
1068
Authors: Lun Qiong Chen, Xia Han, Bei Li
Abstract: Current attenuation rate plays an important role for battery rapid charging.This paper studied the relation between state of charge (SOC) and rebound voltage. Then the fuzzy logic control system with single-input and single-tap has been designed based on SOC and initial charging current.The results showed the maximum current attenuation rate can be achieved when the relationship of initial current and SOC arrived at an optimal value.
506
Authors: Yue Hong Shu, Zuo Cheng, Xue Liu
Abstract: An overview of environmental protection technologies of modern lead-acid battery production is presented. Types of pollutants of lead acid battery in the production process are discussed and analyzed. Focusing on the different types of pollutants produced in different processes, and several environmental machines used in lead-acid battery are specifically introduced
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