Papers by Keyword: Lithium

Abstract: The construction, operating principles, and Li-ion battery thermal runaway mechanisms were analyzed. The external mechanical damage to a Li-ion battery with the uncontrolled thermal runaway development was investigated. The battery self-heating temperature regime was determined. A possible reactions set leading to intense materials self-heating and decomposition was considered. The battery self-heating stopping by immersing it in a container with a water excess relative to the stoichiometric amount for the lithium metal maximum mass that can accumulate was investigated. The change in resulting aqueous solution pH was measured, and the hydrogen release was also recorded. Reaction completion time dependences was established. The water required amount to absorb the heat that could be released during the reaction was calculated, which correlated with the experimental data. Possible measures to Li-ion batteries prevent and stop the burning were considered.

Abstract: Thin film semiconductors are broadly applied in optical and energy conversion devices. Some thin films comprise titanium dioxide, tin oxide, and zinc oxide. The characteristics of the thin films can be changed according to their application. Zinc oxide semiconductors thin films were combined with different concentrations of LiClO₄, varying between 5 and 15% weight percentage. This study aimed to qualify and quantify the morphological, structure, and optical changes in ZnO affected by the presence of lithium salt in the microstructure. The x-ray measurements demonstrated larger polycrystalline sizes, a maximum of 57.53 nm. The band gap energy values lowered to 3.16 eV, lower than the usual 3.37 eV, and reflectance values reached 80%.

Abstract: Lithium demand has increased rapidly in the last few years because lithium is a metal that is important in technology, like electronic equipment and electric vehicles. One of the primary lithium resources is lithium ore, which contains minerals such as spodumene and lepidolite. Mica schist is one of the lithium ore sources that is indicated to contain lithium. The mica schist used in this research was from Kebumen, Central Java, Indonesia. This raw material indicates a lithium mineral called lepidolite. The aims of this research were to find out the potential of local Indonesian minerals as raw materials for lithium extraction processes in lithium-ion battery (LiB) applications, with the effect of leaching time and solid/liquid ratio. The leaching agent used in this research was 2 M chloride acid (HCl). Variables of this research were-100 mesh for particle size of raw material, 1:5, 1:10, 1:15, and 1:20 (g/ml) for solid/liquid ratio, 30, 60, 90, and 120 minutes for leaching time, and 70 °C for leaching temperature. Inductively Coupled Plasma (ICP-OES) analysis was done on this research to determine the mica-schist composition. The optimum lithium percentage that was obtained in this research was 40.65% on a solid/liquid ratio of 1:5 (g/ml) and a leaching time of 120 minutes.

Abstract: Lithium-ion battery (LIB) applications in consumer electronics nowdays are rapidly growing resulting the increase of batteries solid waste containing toxic and corrosive substances for the environment. On the other hand, the main active cathode components in LIB are Lithium and Cobalt, which are hazardous and limited in nature but are valuable metals. This study aims to use bio-hydrometallurgical techniques to recover heavy metals from LIB using microorganisms to avoid toxic waste from used solvents which are usually generated in conventional chemical leaching. Filamentous fungi have an important role in secreting citric acid and several organic acids to facilitate the dissolution of metal ions from the metal solids. Self-grown fungi, Aspergillus niger isolated from waste spices (Candlenut) was used as a leaching agent. Route based on fungal activity was evaluated to optimized the detoxification and metal recovery from spent LIB in various conditions (one-step, two-step and spent medium bioleaching) in 21 days of incubation. The quantitative result of XRF and EDX analysis of battery powder before and after bioleaching confirm that fungal activities are quite effective. The maximum recovery of both metals (Cobalt and Lithium) in leached liquor reached up to 72% analyzed using ICP-OES with the one-step leaching method. With respect due to the high metal recovery, fungal leaching has proven to be an easy and cost-effective green metallurgical method for recycling heavy metals in used LIBs.

Abstract: All-solid-state battery is a promising next-generation energy storage and conversion device and the development of solid electrolyte is very important as the core of all solid-state batteries. Herein lithium-indium chloride solid electrolyte is successfully prepared and the ionic conductivity is increased from 1.07 to 1.41 mS/cm by optimizing the vacuum parameter in the process of preparation. The samples have typical C2/m space group of cubic crystal system, and the vacuum optimized sample has more regular ion arrangement, better crystallinity and fewer lattice defects. The prepared sample is used as the electrolyte layer and the electrolyte part of the composite cathode, and the layered oxide LiNi_0.6Co_0.2Mn_0.2O₂ without surface modification was used as the active material. After assembling the cell, the initial discharge specific capacity of the cell was tested to be 157.5mAh/g. In addition, the phase transition of the composite cathode is analyzed under different charge and discharge state. It is found that the use of the lithium-indium chloride solid electrolyte in composite electrode does not affect the REDOX reaction of LiNi_0.6Co_0.2Mn_0.2O₂ layered oxide, indicating that the electrolyte material is stable and compatible with layered cathode material, showing its excellent application prospect.

Abstract: This study's goals are to fabricate and analyze the microstructure and optical properties of BT and Li-doped BT as the dependence of the Li concentrations (x) of 0.05, 0.1, and 0.15. The thin films of the BT and Li-doped BT have been successfully deposited on the quartz substrates by the sol-gel method. The microstructure and optical features were characterized via XRD and UV-Vis Spectrophotometer, respectively. The XRD patterns exhibit that the lattice parameter and cell volume of the Li-doped films are bigger than that of the BT due to the existence of Li doping in the BT host structure. Additionally, the tetragonality and crystallite size of all films decrease as the more Li number with the BLTO5 has the biggest lattice strain as compared to the others. Meanwhile, the optical characterization reveals that the transmittance spectra increase and the absorption edges shift to the shorter wavelengths as the addition of Li dopant indicating the bandgap values change. In contrast, the refractive index values of the films reduce by the more Li number.

Abstract: The article presents the results of studies on recovery of lithium from reservoir brines using both commercial and synthesized aluminum hydroxide and hydrated manganese oxide as sorbents. The research results showed that, when using commercial aluminum hydroxide and synthesized hydrated manganese oxide as sorbents, lithium recovery from brine was 21.8 and 20.1%, respectively. Studies were conducted on lithium chemisorption on freshly precipitated aluminum hydroxide, which was obtained by adding aluminum chloride solution and tri-calcium hydro-aluminate to the brine. Chemisorption of lithium was carried out under the following conditions: T = 50 °C; AlCl₃ solution concentration - 120 g/dm³; molar ratio Li/Al = 7; pH equal = 8.0-8.8; holding time with stirring 1 h. The degree of lithium extraction from brine was 71%; lithium capacity of freshly precipitated Al (OH)₃ was 5.9 mg/g. During calcareous leaching of lithium-aluminum precipitate, lithium was extracted into a solution by 74.7%.

Abstract: In this work, Li_1.6Mn_1.67O₄ is successfully prepared by solid state reaction method and firstly prepared as adsorbent for geothermal fluid of Lumpur Sidoarjo. XRD shows the all samples are indexed as Li_1.6Mn_1.67O₄ with spinel structure. The further increase of calcination temperature, diffraction peaks of Li_1.6Mn_1.67O₄ are growing strong and sharp, implying an improved crystallinity and an increased grain size. SEM images of LMO adsorbent show irregular shape with particles size in the range of 15-52 μm. Li_1.6Mn_1.67O₄ at 700 oC has the highest capacity of lithium adsorption with capacity of 29.8 mg/g. It is attributed to the high crystalline of Li_1.6Mn_1.67O₄ at 700 oC compared with other samples. In addition, the higher calcining temperature will result in the increasing grain size and crystallinity that enhance the adsorption performance of the Li_1.6Mn_1.67O₄ adsorbent.

Abstract: Since several years, the lithium market is characterized by high growth rates especially due to the increasing demand for lithium-ion batteries. Therefore, the primary production is currently expanded and there is a growing interest in recycling. However, because of the chemical properties of lithium, many production processes lack efficient processes for the separation, concentration and purification of lithium. This article reviews the current use of liquid-liquid extraction (LLE) and chromatography in lithium production as well as research. Currently, the industrial application of LLE and chromatography in lithium purification is limited to the extraction of impurities and co-products. Extraction of lithium is only used as concentration step in few processes before lithium precipitation. In research and development, a wide variety of extractants and resins is investigated. In LLE, chelating extractants like crown ethers and calixarene and synergistic systems show the greatest potential. In the chromatographic separation the main focus of research lies upon cation exchange media, especially media with sulfonated ligands. However, most research is still in early development. Therefore, extensive research is needed to enable the industrial use of optimized LLE and chromatography processes in lithium production. Content TOC \o "1-3" \h \z \u HYPERLINK \l "_Toc515547308" Abstract PAGEREF _Toc515547308 \h 2 HYPERLINK \l "_Toc515547309" Content PAGEREF _Toc515547309 \h 3

Abstract: In view of the increasing demand for lithium and the unequal distribution of lithium deposits worldwide, local deposits such as the zinnwaldite deposit at Zinnwald/Cínovec are increasingly coming into focus. It could be shown that especially the direct carbonation process with supercritical CO₂ represents a promising approach for a technical implementation due to the low chemical consumption as well as the high selectivity for lithium. Moreover, besides primary ore (zinnwaldite), the method is also suitable for recovering lithium carbonate from black mass, the lithium-containing fraction from lithium ion battery recycling.