Papers by Keyword: MEVVA

Abstract: Carbon ion implantation has often been considered as an additional method to further improve the wear, corrosion and oxidation resistance of hard coatings on tools or machine parts. The present research investigates the effect of carbon implantation on the structural and mechanical properties of the sputter-deposited solid solution Ti-Al-N coatings. The carbon implantation was carried out by using metal vapour vacuum arc ion source (MEVVA) with solid cathode at energies of 5 and 50 keV, and a dose of 6×1017 atoms cm-2. The mechanical and the microstructure properties of the implanted layer were identified by a variety of analytic techniques, such as nano-indentation, x-ray photoelectron spectroscopy (XPS) and x-ray diffraction (XRD) etc. Additionally, the wear performance of the samples was evaluated by a typical ball-on-disk tribometer in dry conditions. The results showed that the coatings with high energy carbon implantation exhibited an enhanced hardness. The improved hardness could be attributed to the formation of TiC phase, as indicated in XPS. In the sliding tests, the coatings with the post-treatment of carbon implantation showed an improved tribological property in terms of friction coefficient and wear rate. The friction coefficient could be reduced from 0.6 to 0.1. The coatings had ten-fold better wear resistance than the coating without ion implantation.

Abstract: HIP (hot isostatic pressed) high-purity alumina was modified by Ti-ion implantation in a MEVVA (Metal Vapor Vacuum Arc) implanter. The samples were implanted by Ti ions with nominal doses 5×1016 to 1×1018 ions/cm2 under ambient temperature. The effects of titanium implantation and the ion dose implanted on the microstructures and mechanical properties of the ceramics were studied. After implanted by Ti ions, the maximum nanohardness of the as-implanted ceramics were increased about 20%; the bending strength were increased about 22%; the life of the alumina cutting tools were about 2 times longer than before. The result showed that all the factors of the improvement of the ceramic surface states played an important role on the mechanical properties after implantation.

Abstract: ZTA (alumina toughened by 20 wt.% zirconia), hot-pressed silicon nitride (with totally 10 wt.% Y2O3 and Al2O3 as additives) and TZP (pressureless-sintered yttria stabilized zirconia) ceramics were implanted by various doses (5 × 1016 ions/cm2 ~ 1 × 1018 ions/cm2) of Ti, Zr, and Cr ions with a MEVVA (metal vapor vacuum arc) source implanter. The bending strength of these ceramics was investigated. It was discovered that, for different ceramics, different behaviors were presented with the same doses of implantation ions. For alumina and zirconia ceramics, the bending strength increased with increasing implantation doses of Ti and Zr ions, but decreased with high dose of Cr ions. For silicon nitride ceramics, however, the bending strength originally increased with smaller doses of metals implanted, and decreased with higher doses of metals of Ti, Zr, and Cr ions. The different behaviors are correlated to the different variations in compositions and microstructures of ceramics after ion implantation.

Abstract: There are too many methods to enhance the performance of ceramic cutting tools. All the methods can be sorted into two types: inner modification and surface modification. One of the main method to the inner modification of ceramic cutting tools is dispersion strengthening. Usually, in order to enhance the performance of ceramic cutting tools, some dispersed phases of TiN, TiC or TiCN, Al2O3, and/or ZrO2, and so on, and/or some whiskers, or fibers were added into the ceramic matrixes. And the new types of cutting tools, which possessed much more excellent performance than the original ones, were called composite ceramic cutting tools. For the composite Si3N4-based ceramic, Al2O3-based ceramic, and TiCN-based cermet, the cutting efficiency could be enhanced to 3~10 times, compared with cemented carbide tools. And they can be used for rough and finish machining of various cast iron workpieces and hardened steels, respectively, including milling and planning. Ion implantation is a surface modification for ceramic cutting tools. With certain doses of metals, for example, titanium, zirconium and chromium, and so on, implanted into the ceramics, the hardness, Young’s modulus, fractural toughness, and bending strength, etc., can be enhanced. For Al2O3 and Si3N4 ceramics, the hardness, Young’s modulus, and bending strength increased with a maximum factor of 50%, and the flank wear decreased with a factor of 2~12, compared with the unimplanted ceramic cutting tools. However, the main shortcoming of ion implantation to modify ceramics is the thickness of modified layers. They are, usually, too thin for cutting tools. The so-called PHEDP, pulsed high energy density plasma, is another surface modification method for ceramic cutting tools proposed recently. With such method, much thicker coatings of TiN, TiCN and (Ti,Al)N, etc, were deposited onto Si3N4 and WC ceramic cutting tools.The main merits involved in high hardness and Young’s modulus of the coatings, low residual stresses, and good adhesive strength between the coatings and substrates. And the flank wear of the as-depositedtools decreased with a factor of 5~10.