Authors: Ryosuke Kainuma, W. Ito, R.Y. Umetsu, V.V. Khovaylo, T. Kanomata
Abstract: In some Ni-Mn-In- and Ni-Mn-Sn-based Heusler-type alloys, martensitic transformation from the ferromagnetic parent phase to the paramagnetic martensite phase appears and magnetic field-induced reverse transformation, namely, metamagnetic phase transition, is detected. In this paper, the metamagnetic shape memory effect due to the metamagnetic phase transition and the magnetostress effect in the Ni-Co-Mn-In alloys are introduced and the phase diagrams of Ni50Mn50-yXy (X: In, Sn, Sb) alloys are shown as basic information. Furthermore, the magnetic properties of both the parent and martensite phases in the Ni-Mn-In- and Ni-Mn-Sn-based metamagnetic shape memory alloys are also reviewed.
139
Authors: Martin Pötschke, Stefan Roth, Uwe Gaitzsch, Claudia Hürrich, Andrea Böhm, Ludwig Schultz
Abstract: Textured polycrystalline Ni-Mn-Ga alloys were prepared by directional solidification. Alloys were chosen to have the 5M modulated martensitic structure after proper heat treatment. A two-side mechanical training decreased the twin boundary pinning stress. The stress-strain behaviour for the training process and the magnetically induced stress depends on the training direction. Magnetic field induced strain was demonstrated in samples with a plate-like geometry. The influence of the microstructure on the magneto-mechanical behaviour is discussed.
129
Authors: Victor A. L'vov, Volodymyr A. Chernenko
Abstract: The analytic survey of experimental and theoretical studies of the magnetic anisotropy of ferromagnetic shape memory alloys (FSMAs) is presented. The interdependence between the magnetic anisotropy of FSMAs, their lattice parameters, microstructure, and magnetostrain properties is considered. The temperature dependencies of the magnetocrystalline anisotropy energy density (MAED) and magnetically induced mechanical stress are described in the framework of magnetoelastic model based on Landau theory of phase transitions. The magnetic anisotropy of thin martensitic platelets/films and wires is considered. The effect of compensation of magnetocrystalline anisotropy by the magnetostatic one is studied. The reduction of MAED as a result of internal twinning of single crystal is discussed. The possibility of observation of reversible magnetic-fieldinduced strain in the twinned FSMAs with reduced MAED is demonstrated.
31
Authors: Xiao Gang Sun, Chao Ying Xie
Abstract: Polymer composites inserted with high volume fraction of NiMnGa powders were fabricated and their magnetic-field-induced strain (MFIS) was investigated. It is found that MFIS of NiMnGa/polymer composites increases with the increase of volume fraction of NiMnGa powders in composites. Large MFIS of 950 ppm has been obtained along the orientation magnetic field while only 220 ppm was on the perpendicular orientation magnetic field.
387
Authors: Stefan Roth, Uwe Gaitzsch, Martin Pötschke, Ludwig Schultz
Abstract: Textured polycrystalline NiMnGa alloys were prepared by directional solidification.
Alloys were chosen to have either the 7M or the 5M modulated martensitic structure after proper
heat treatment. Mechanical training allowed to reduce the twin boundary pinning stress to below the
magnetically induced stress. Thus, magnetic field induced changes in the mechanical behaviour
could be demonstrated. The conditions of preparation and mechanical training will be discussed
together with their influence on structure, microstructure, and the magneto-mechanical behaviour.
29
Authors: Ratchat Techapiesancharoenkij, Samuel M. Allen, Robert C. O'Handley
Abstract: Ni–Mn–Ga based ferromagnetic shape memory alloys (FSMAs) have emerged as a
promising class of active materials capable of producing a large (up to 10%) magnetic-field-induced
strain (MFIS). This large strain is not the familiar anisotropic magnetostriction; it results from
field-induced twin-boundary motion and has appropriately been referred to as magnetoplasticity.
FSMAs still have several characteristic shortcomings that may limit their potential applications. A
threshold field of 150 to 300 kA/m must be overcome to initiate twin-boundary motion and a larger
field is required to achieve full strain. The operating window of the stress output from FSMA
actuators is limited to the range between 1 and 1.5 MPa. Outside this operating range, the strain
output diminishes significantly. This paper addresses these performance limitations and describes
an acoustic-assist technique that has been shown to decrease the required threshold field and
increase the stress and strain output of FSMA actuation. The application of an acoustic assistance
from a 33-mode piezoelectric stack is shown to improve MFIS of Ni–Mn–Ga single crystals by
reducing the required threshold field and twinning-yield stress. Threshold field reductions of up to
80 kA/m are observed, and the twinning-yield stress can be reduced by up to 0.5 MPa. The effect of
acoustic assistance on FSMA actuation can be understood as a form of time varying stress waves
that facilitate twin-boundary motion. A stress wave analysis is shown to give a quantitative
understanding of the measured reduction in the twinning-yield stress. For FSMA cyclic actuation,
both operating stress and strain outputs of the FSMA actuation are significantly enhanced by
acoustic assistance. Without the acoustic assistance, the maximum reversible strain of the sample
used here is 3% and appears only in the limited external stress range between 0.7 and 1 MPa. With
the acoustic assistance, the maximum reversible strain increases to 4.5% and appears in a broader
range of stress output between 0.4 and 1.2 MPa. The reduction in the twinning-yield stress due to
the acoustic assistance significantly improves the FSMA cyclic actuation performance; magnetic
energy not used to drive twin-boundary motion can be utilized to work against a larger external
load.
147
Authors: Tatsuaki Sakamoto, Takashi Fukuda, Tomoyuki Kakeshita
Abstract: We have measured temperature dependence of the uniaxial magnetocrystalline
anisotropy constant Ku and the shear stress τr eq required for the twinning plane movement of an Fe-31.2Pd alloy in order to explain the field orientation dependence of rearrangement of martensite variants (RMV) of this alloy in the field-cooling process. Under the [001]P field (P represents parent phase), the RMV occurs perfectly at the temperatures where the measurement was performed; in
this case, the magnetic shear stress acting across the twinning plane τmag, which is evaluated from Ku, becomes nearly twice as large as τr eq. On the other hand, under the [011]P field, the RMV occurs partially at all the measuring temperatures; in this case the maximum of τmag is nearly the same as τr eq. It is successful to evaluate the following relation quantitatively; τmag> τr eq is satisfied when RMV occurs under magnetic field.
201
Authors: Tomoyuki Kakeshita, Takashi Fukuda, Tatsuaki Sakamoto
Abstract: We have investigated the magnetic field-induced strain (MFIS) of the martensite and the parent phases in an Fe-31.2Pd(at.%) single crystal, which exhibits a martensitic transformation at TM = 230K. Below TM, a large MFIS of several percent appears due to rearrangement of martensite variants and this strain remains when a magnetic field is removed. Such rearrangement depends on magnetic field direction; Variants are perfectly rearranged into the variant, which lowers the magnetocrystalline anisotropy energy most, when a magnetic field is applied along [001]P, and partially when [011]P and hardly when [111]P (“P” represents “parent” phase). The dependence on the field direction can be explained by comparing the magnetic shear stress tmag with the shear stress t
req required for rearrangement of variants. Above the temperature, TM, a relatively large MFIS appears and it increases up to about 10-3 with decreasing temperature from 280 K toward TM. This MFIS is probably caused by anomalies of some physical properties, such as elastic constant and dipole-dipole interaction coefficient in the parent phase.
1999
Authors: Feng Chen, Zhiyong Gao, Wei Cai, Lian Cheng Zhao
Abstract: The stability of magnetic field induced strain (MFIS) in Ni52Mn24Ga24 single crystal under temperature and magnetic field cycling is investigated and the corresponding micro-mechanism is also discussed. It shows that the saturated MFIS is very sensitive to temperature. Below martensitic transformation temperature(Tm), with increasing temperature, the saturated MFIS increases almost linearly. Besides, the saturated MFIS initially decreases with increasing the field cycling number less than four times, then does not change with further increasing the number of field cycles. The decrease of saturated MFIS can be attributed to the
decrease of twin boundary mobility, which is related to the crystal defect introduced by immigration of twin boundary under field cycling.
2025
Authors: Jing Min Wang, Cheng Bao Jiang, Hui Bin Xu
Abstract: The behavior of twin variants reorientation in Ni50Mn27.5Ga22.5 single crystal under the applied mechanical stress and magnetic field was investigated. Through three times of compression, the twinning stress was reduced from 4.4MPa to 0.4MPa, and 2.5% stress induced strain was obtained. During the succedent MFIS measurement, with the increase of measurement number of times, the critical field (μ0H)c at which the MFIS jumps became lower, and the corresponding jumping magnetostrain ε j, and the maximal magnetostrain εmax ascended. At last, a quasi
single-variant state was realized, and the sample showed repeatable 6.21% MFIS, which is close to the theoretical value (1-c/a)*100%. The results are discussed from the point of martensitic microstructure evolution.
2013