Papers by Keyword: Metal Sulfide

Abstract: The efficient cleaning conversion of coal is more and more attracted due to resource exhaustion and environmental pollution. To improve the yield and quality of products of coal pyrolysis, the catalytic hydrogenated microwave pyrolysis was introduced, and the effects of metal sulfide on hydrogenated microwave pyrolysis were focused on discuss via the detection methods of proximate and ultimate analyses, SEM-EDS, FT-IR and GC-MS in this work. The results shown that because of the “hot-spot” effect and the characteristics of electromagnetic loss of metal sulfide, the temperature-rising rates with catalysts were obviously higher, but the final pyrolysis temperatures with or without catalyst were almost close. Higher temperature-rising rate with catalysts made the yield of liquid product more, which the yields of liquid product with MoS₂ and FeS₂ catalyst were 28.4 wt.% and 27.1 wt.%. The carbon distributions indicated that carbon in solid and gaseous products transferred into liquid product, when the catalysts added into pyrolysis reactions. The quality of tar with catalyst was improved, and the component content of light oil, intermedium oil and heavy oil were 67.55 wt.%, 27.98 wt.% and 4.47 wt.% for MoS₂ catalyst, in which the content of light oil increased by 10.30 times than that without catalyst. The thermal effect and catalysis of metal metal sulfide made complex aromatic compounds more thorough cracking, improved the amount and active of free hydrogen. Actived free hydrogen further enhanced cracking of heavy oil, resulting in the content of hydrogen in gaseous with catalysts decrease, and the content of light oil increased.

Abstract: The deactivation behavior of industrial hydrodemetallization catalysts was investigated in the presented work. The main objective of the study is to contribute to a better understanding of the nature of the coke and metal deposition on the used catalysts by applying chemical analysis and various advanced analytical techniques, such as X-ray diffraction analysis (XRD), thermal gravimetric analysis (TGA), transmission electron microscopy (TEM), and solid-state carbon-13 nuclear magnetic resonance spectroscopy (¹³C NMR). The results are discussed scientifically based on the physico–chemical properties of origin and used catalysts.

Abstract: A low-temperature precursor sulfuration route has been established to prepare metal sulfides with different nanostructures during the synthesis of nickel sulfide. The advantages of the low-temperature precursor sulfuration route were testified by the synthesis of different metal sulfides ( lead sulfide, zinc sulfide and cobalt sulfide). It offers a novel path to the preparation of other metal sulfides.

Abstract: The Multi-Morphologic nanostructures of nickel sulfides were synthesized successfully by a solution chemical route. The growth models of these materials and the most possible mutation process between these different morphologies were discussed.

Abstract: As the electrodes of secondary battery are made with sulfide composite powders, excellent electrode system of environmental non-toxicity and with high specific energy density and low material cost can be obtained. In this study, the (Fe, M)S2 composite powders was synthesized by mechanochemical processes (MCP) in order to improve of the cycle life in bettery. The formation of pyrite phase appreared at the case which adds nickel, but it was not observed in the case where the transition metal was does not add but the transition metal such as cobalt, molybdenum was added in stead. From charge-discharge test results, the initial discharge capasity of (Fe, Ni)S2 electrode was 845 mAh/g. The initial discharge capasity of (Fe, Co)S2 electrode was 500mAh/g, but it showed a better cycle perfoemance than the case where the diffrent transition metal was added.

Abstract: FeSx nanoparticles were synthesized by the chemical vapor condensation (CVC) process using the pyrolysis of iron pentacarbonyl (Fe(CO)5) and sulfur (S). The influence of CVC parameter on the formation of nanoparticle and size distribution was studied. The synthesized nanoparticles consisting of FeS, FeS2 and Fe2O3 were nearly spherical shape and 5~40 nm in mean diameter. Obtained particles were studied by applying the field emission scanning electron microscopy (FESEM) and high resolution transmission electron microscopy (HRTEM) and X-ray diffraction (XRD) methods. Electrochemical properties of the electrode fabricated with synthesized nanoparticles were evaluated.