Papers by Keyword: Microsegregation

Abstract: The Cu-8.5wt % Sn alloy presents an extensive microsegregation during its solidification. That microsegregation results in the formation of a eutectoid mixture, which is detrimental to subsequent forming processes. This study deals with the influence of solidification time and cooling rate on the microstructure of that alloy. The unidirectional solidification technique allowed the acquisition of thermal data. The optical microscopy enabled the microstructural characterization of the material, the measurement of dendrite arm spacings and the quantification of the volume fraction of the eutectoid mixture. A semi-analytical mathematical model was proposed to estimate the volume fraction of the eutectoid mixture. The model expresses the volume fraction as an implicit function of the Fourier number. The results showed that the microstructure is dendritic and that the characteristic spacings increase with the solidification time between the liquidus and the peritectic temperatures. The data also showed that for higher cooling rates the dendrite arm spacings are smaller and that there is a tendency for the volume fraction of eutectoid mixture in the columnar zone to increase with the Fourier number and to decrease with the cooling rate. The proposed model allowed obtaining values of volume fraction with the same order of magnitude of the experimental data, but with behavior tendency opposite to that observed.

Abstract: Microsegregation is intimately coupled with solidification, the development of microstructure, and involved in the formation of various casting defects. This paper demonstrates how the local composition of the metal matrix of graphitic cast irons, measured using quantitative electron microprobe analysis, can be used to determine its solidification chronology. The method is applied in combination with Fourier thermal analysis to investigate the formation of micropores in cast irons with varying proportions of compacted and spheroidal graphite produced by remelting. The results indicate that micropores formed at mass fractions of solid between 0.77 and 0.91, which corresponded to a stage of solidification when the temperature decline of the castings was large and increasing. In 4 out of the 5 castings, pores appear to have formed soon after the rate of solidification and heat dissipation had reached their maximum and were decreasing. While the freezing point depression due to build-up of microsegregation and the transition from compacted to spheroidal type growth of the eutectic both influencing solidification kinetics and the temperature evolution of the casting, the results did not indicate a clear relation to the observed late deceleration of solidification.

Abstract: The solidification experiments about macrosegregation formation of the Al-10%Bi hyper monotectic alloys under gravity conditions have been carried out. The results showed that the average diameter of the Bi-rich droplets linearly increases and the number density of the Bi-rich droplets exponentially decreases with solidification time under the gravity condition. Because of gravity settling and collisions coagulation between the droplets, area fraction of Bi-rich increased rapidly in the bottom of samples during early solidification. It’s easy to form Bi-rich layer at the bottom of the sample. The analysis demonstrates that nucleation and diffusion growth of drops are the dominant factors influencing the solidification microstructure during the early solidification and the same distribution of Bi-rich in different locations of sample. As the solidification process, gravity migration and collision coagulation beginning to play the leading role, lead to the difference in the distribution of Bi-rich droplets in different locations of sample 90%e5%a2%9e%e5%a4%a7&tjType=sentence&style=&t=increases+gradually" increases gradually in the same time. It caused macrosegregation of the final solidification microstructure under the gravity condition.

Abstract: The investigation was focused on the microstructure characterization as well as changes in chemical composition and hardness of water wall tubing weld overlaid with Inconel 625. The analysis comprised studies in a light and electron microscopy scale that included the evaluation of weld overlays microstructure and microsegregation of alloying elements across the overlay and base metal interface. The particular attention was turned to the distribution of the main element content (Fe, Ni, Mo, Nb, Cr) in the base metal fusion zone as well as in the weld overlay itself. It was shown that the solidification process resulted in significant segregation in alloying elements giving rise to the substantial differences in chemical composition between dendrite cores and interdendritic spaces. It is believed that the microsegregation together with precipitation of secondary phases may contribute to the deterioration of corrosion resistance and overall mechanical properties of weld overlay including ductility and fracture toughness.

Abstract: Graphite growth morphology was studied by using InLense detector on FEG-SEM after performing ion etching on the samples. Star like and circumferential growth mechanism of graphite was observed in the graphite nodules. Pure ternary alloy of hypo eutectic and hyper eutectic composition was treated with pure Mg, Ca and Sr, to study the effect of O and S concentration in the melt, on the transition of graphite morphology from nodular to vermicular/compacted and flake graphite. The change in the melt composition between the austenite dendrites due to micro-segregation of S, O and inoculants and their possible effects on the transition of graphite morphologies as well as the nucleation of new oxides/sulfides particles is discussed with the help of thermodynamics.

Abstract: This article is to assess the modeling treatment of the growth kinetics (finite or infinite diffusion in liquid and solid phases) during solidification and its influence on the calculation of macrosegregation. A model of diffusion-governed growth kinetic for ternary alloy is developed and used for this assessment. Solidification of a 2D casting (50 x 50 mm²) of a ternary alloy (Fe-0.45 wt.% C-1.06 wt.%Mn) is considered. The result shows that finite diffusion in liquid, important for the initial stage of solidification, plays very important role in the formation of macrosegregation. Moreover, the role of the finite diffusion kinetics in the formation of macrosegregation shows differently in the two extreme cases of solidification structures (columnar or equiaxed).

Abstract: Solidification experiment a graphite mold was carried out on ternary alloy Al-4.61Cu-0.92Si and typical dendrite microstructure was obtained. The influence of heat treatment on microsegregation between the dendrite, and the amount and morphology of the non-equilibrium eutectic phases were studied. Line scans results shows that the dendrite microsegregation disappeared after heat treatment under temperature near the ternary eutectic point. And the amount of eutectic phases is decreased obviously and the morphology of most θ-phase is changed from normal pattern to sphere or nearly spherical.

Abstract: Steels with manganese contents of more than 20% offer a new and favourable combination of material properties like high strength and high ductility. These extraordinary mechanical properties are based on the TWIP effect, which depends on the Stacking Fault Energy (SFE). But there are still problems in the conventional production of high-manganese steels, which prevents their widespread use. Both in casting and subsequent hot rolling difficulties occur, with the consequence that the production is very expensive. One alternative production process of high-manganese steels is strip casting, which basic feasibility was shown in earlier work. Strip casting allows the casting and rolling of hot strip in one combined process. In this way hot strip with a thickness of less than 3 mm could be produced. Characteristic for the strip cast material is the as-cast structure with a fine dendritic structure, which shows pronounced microsegregations with a short wavelength. The pronounced microsegregations can have an impact on the local chemical composition and thus on the dominating forming mechanisms that occur. In this work therefore the microsegregations of strip cast material are investigated by means of electron probe microanalysis (EPMA) measurement. Besides the local element distribution, also the presence and composition of non-metallic inclusions are analysed. Especially oxides from the casting process and sulfides from the raw material are expected. Furthermore, different annealing processes for the elimination of the dendritic as-cast structure are examined. In these experiments the temperatures were varied in the range from 900 to 1150°C at annealing times from several minutes to a few hours.

Abstract: In this paper, the directional solidification microstructure of Bridgman system was simulated using phase-field method, and different calculated results were obtained with four pulling velocities. When the pulling velocity is 0.06 cm/s, the columnar crystals competitively grow in the initial stage, and have a necking phenomenon in the last stage. When the pulling velocity is 0.04 cm/s, the columnar crystals become thinner and competitively grow all the time, and the microsegregation is bigger. When the pulling velocity is 1.00 cm/s, planar interface comes back, and solute trapping takes place. The columnar crystals become much thinner, and microsegregation decreases. When the pulling velocity is 3.00 cm/s, the grain boundary of columnar crystals becomes unconspicuous, and the degree of microsegregation approaches 1.

Abstract: This paper investigates the influence of electrical pulses inoculation and Al-5Ti-B on the as-cast structure of 7075 aluminum alloy. The experimental results indicate that the number of the secondary branch crystal of the solidification structure is effectively controlled, and the feature of as-cast structure achieve the equiaxial and spherical grains after the liquid 7075 Al-alloy was treated by electrical impulse inoculation and Al-5Ti-B. Compared with these samples treating without electrical impulse inoculation, the segregation of Cu and Fe is restrained to a certain extent too. Some primary refinement mechanisms analyze those effects on the solidification structure by treating with electric pulse and Al-5Ti-B; this experiment may provide a theoretical reference for the application of electric impulse in 7075 aluminum alloy.