Papers by Keyword: Microsegregation

Abstract: In order to obtain the directional microstructure of different supersaturation and growing velocity, three simulations is calculated with different initial temperature. When the initial temperature is 1576K, and the supersaturation and growing velocity are smaller. The average space length of columnar crystals is bigger, and microsegregation is smaller. when the initial temperature is 1574K, the supersaturation and growing velocity increase. The average space length of columnar crystals decreases, and microsegregation increase; when the initial temperature falls to 1566K, the supersaturation and growing velocity reach 1.176 and 3.238 cm per second. The microsegregation decreases rapidly. The average space length of columnar crystals is the smallest. The solute curve of columnar crystal is like a “U” figure. When the growing velocity is bigger than V_A, the phenomenon of solute trapping takes place.

Abstract: The microstructures and the solidification processes simulation of multi-principal high-entropy alloy FeCoNiCrMn were studied by using both experimental and computational approaches. The microstructures were identified by methods of XRD, SEM and EDS. The solidification process was simulated by Scheil-Gulliver solidification model. The alloy mainly forms a single FCC solid solution, but Mn atoms, as well as Ni atoms tend to be enriched in residual liquid phase during the solidification process. These atoms show interdendritic segregation. Present experimental results and computational results are supported each other well.

Abstract: This paper deals with the causes of a transversal crack in a steel slab with an l300×l45 mm cross-section by means of results from two models. Samples were taken from and around the crack in order to analyze the concentration (chemical heterogeneity) of the selected elements. Simultaneously, the concentration of elements at the surface of the crack was measured after the crack was opened. The chemical heterogeneity of elements was analyzed by means of the JEOL JXA 8600/KEVEX analytical equipment. The measurement results were processed using mathematical statistics procedures. The results proved that there was an internal crack initiating immediately below the curve of the solid-state temperature and consecutively propagating.

Abstract: Directional solidification (DS) of FeCoNiCrAl high entropy alloy is carried out to investigate the microstructures and microsegregation under controlled solidification conditions. With an increasing solidification rate, the interface morphology grows in a planar, cellular and dendritic manner. The microstructures of the dendritic and interdendritic segregation areas are found to be spherical precipitates and basket-weave structures, respectively. With the help of an electron microprobe, microsegregation is determined in directionally solidified FeCoNiCrAl high entropy alloys. In contrast to the as-cast condition, directional solidification can refine microstructures of FeCoNiCrAl high entropy alloy dramatically and reduce microsegregation effectively.

Abstract: Al-4.5%Cu ingots were prepared by a process of low frequency electromagnetic casting (LFEC) and conventional direct chill (DC) casting, respectively. The effects of low frequency electromagnetic field on the microsegregation were investigated from eutectic analysis and electro probe microanalysis (EPMA). It was found that the amount of the nonequilibrium eutectic and the dimension of the nonequilibrium eutectic were decreasing markedly. In contrast, the solute content in the α-Al phase increased to a certain extent in the presence of the low frequency electromagnetic field, and it increased with the incerasing electromagnetic.

Abstract: Microsegregation induced inhomogeneity of the coarsening of cuboidal γ’(Ni3(Al,Ti)) precipitates was studied in a single crystal nickel-based superalloy CMSX-4 at temperatures ranging from 850 to 1000 °C and for an ageing time up to 5000 h. Experimental results showed a significant statistical difference in the size of the γ’ precipitates between the dendrites and interdendritic region. The achieved results are analyzed and discussed from the point of chemical heterogeneity, activation energy for coarsening, time exponent, effective diffusion coefficient and γ/γ’ interfacial energy which control coarsening kinetics of the cuboidal γ’ precipitates within the dendrites and interdendritic region.

Abstract: The present paper focuses on the influence of combined additions of Zr and Mn on the recrystallisation resistance of aluminium alloy 2198 sheet. Dual additions of these dispersoid forming elements have previously been reported to be beneficial for reducing recrystallisation during solution treatment, as they exhibit opposing microsegregation partitioning on solidification. Contrary to expectation, it was found that the addition of Mn, to a standard Zr-containing 2198 sheet material, reduced recrystallisation resistance. The reasons for this behaviour are explored by analysis of the morphology, size, chemistry, and distribution of the dispersoid families formed, as a function of the Mn and Zr level, traced back to the homogenisation stage.

Abstract: Recently identified re-solidification behaviour of heavily alloyed single crystal super¬alloys has been incorporated into the Bridgman method. The process variables of resolidifcation temperature and mould withdrawal rate have been optimized. The microstructure, microporosity and eutectic phase fraction of re-solidified specimens were analyzed and compared with conventionally cast single crystal specimens. The potential advantage of this modified method has been illustrated by performing solution heat treatments on both re-solidified and normally cast specimens followed by eutectic phase fraction analysis.

Abstract: The paper deals with the effect of cooling rate on solidification behavior of IN 738LC nickel based superalloy and on resulting structural and chemical microheterogeneity of this alloy. Samples taken from as-received state were heated with controlled ramp rates (1, 5, 10 and 20 °C min-1). Immediately after melting they were cooled with the same controlled ramp rate with the help of the laboratory experimental system SETARAM SETSYS 18TM TG/DTA/TMA. Then the microanalysis of minority phases was conducted with use of X-ray spectroscopy and microstructure of the individual samples was documented by scanning electron microscopy. Chemical microheterogeneity was determined on the basis of measured concentration data of selected elements (Al, Ti, Cr, Co, Ni, Nb, Mo, Ta and W) in representative areas of the individual samples structure.

Abstract: Aluminum-Lithium alloys were developed as major replacements for existing aluminum alloys to reduce the weight of aircraft and aerospace structures. Mechanical properties of Al-Li alloys greatly depend on solidification conditions. Other than reducing the microsegregation, homogenization treatment has other effects on the microstructure of Al-Li ingots. In this research, effects of homogenization treatment at constant temperature (500°C) on the precipitation in the microstructure of Al-1Li-3Cu-0.1Zr (wt %) and Al-2Li-3Cu- 0.1Zr (wt %) specimens have been investigated. Results show that homogenization at 500°C for 24 hours not only increases the hardness and phases precipitating in grain but also reduces microsegregation of Fe in grain boundaries.