Papers by Keyword: Microstructural Change

Abstract: To investigate creep rupture properties and microstructural changes due to creep of the Mod.9Cr-1Mo steel with high initial hardness, creep rupture tests were carried out at 600°C and 650°C. The hardness of the gauge and grip portions of the ruptured specimens were also measured. This steel exhibited higher creep rupture strength than the conventional material at the two temperatures, but its creep rupture strength showed a larger decreasing tendency at 650°C. For the specimens ruptured at 600°C, an increasing tendency in lath width and a decreasing one in hardness were confirmed in gauge portions, but they were not observed in grip portions. However, for the specimens ruptured at 650°C, the hardness of both gauge and grip portions tended to decrease with the time to rupture, and the recovery of the lath structure and the coarsening of M₂₃C₆ carbides were particularly noticeable in the gauge portions.

Abstract: Change in the Microstructure of the L1₀-Type Ordered β' Phase Precipitated in Ag-20Pd-12Au-14.5Cu Alloy (mass%) Subjected to Solution Treatment with Varying Solution Treatment Time Was Investigated. The Size of the β' Phase Is Found to Decrease with Increasing Solution Treatment Time and the Vickers Hardness of the Alloy after Solution Treatment Decreases. Experimental Observations Show that the Microstructural Change of the β' Phase Strongly Contributes to the Change in Vickers Hardness. In Addition, the Formation and Growth of the β' Phase Are Concluded to Be Affected by the Distribution of Elements through Solution Treatment.

Abstract: In the rolling bearing, the flaking caused by rolling contact fatigue is classified into two types: surface originated flaking and subsurface originated flaking. It has been recognized that marked microstructural change can occur in subsurface originated flaking due to rolling contact fatigue. But there are few reports in surface originated flaking about microstructural change. In this study, surface originated flaking caused by rolling contact fatigue was investigated based on microstructural change. Thrust ball bearing and radial ball bearing was used for fatigue test. Simulation of dent originated flaking was carried out using the bearing with artificial dent. Another fatigue test subjected to surface originated flaking was done under shortage of oil film thickness lubrication condition. Microstructural change was measured by X-ray Diffractmetry (XRD) and Transmission Electron Microscopy (TEM) during fatigue testing. Microstructure of bearing steel used for fatigue test is consisted of martensite with small amount of retained austenite. XRD measurement reveals that the half peak width of martensite and volume fraction of retained austenite decreasing with increasing testing time, and the amount of decrease in these parameter were small in the surface originated flaking compared with subsurface originated flaking when the specimens were flaking. This suggests that surface originated flaking occurs in spite of mild microstructural change. TEM observation about the surface originated flaking shows plastic flow in the surface layer. Especially, it was confirmed that partial recrystallization occurs in the fatigue test under shortage of oil film thickness lubrication condition. But it was also confirmed that degree of recrystallization is lower in the surface originated flaking than subsurface one, and this reasonably explains XRD result. From these results, it was cleared that recrystallizaiton of martensite is differ in degree but not in kind between surface originated flaking and subsurface originated flaking.

Abstract: The applications of laser scanning confocal microscopy (LSCM) system were introduced to the track the phase transformation of steel. For the low and high carbon steel, the microstructural change along various thermal cycles was directly observed with LSCM system. The nature of non-themoelastic martensite was directly observed. Furthermore, direct checking of the nucleation site of ferrite phase was carried out for aluminum killed weld metal and titanium killed-steel. It was carried out concerning to acicular ferrite formation in high strength and low alloy steel. The assessment of the pinning effect of alumiunu nitride on the austenite phase at high temperature was also carried out by using LSCM system.

Abstract: Microstructural changes occurring in biomedical Co-Cr-Mo alloys with three carbon levels due to solution treatment and aging were investigated. Ingots of Co-Cr-Mo alloys with three different carbon levels were prepared by vacuum furnace melting; their chemical composition was Co-28Cr-6Mo-xC (x = 0.12, 0.25 and 0.35 mass%). Precipitates were electrolytically extracted from as-cast and heat-treated alloys. An M23C6 type carbide and a phase were detected as precipitates in as-cast Co-28Cr-6Mo-0.12C alloy, and an M23C6 type carbide and an  phase (M6C-M12C type carbide) were detected in as-cast Co-28Cr-6Mo-0.25C and Co-28Cr-6Mo-0.35C alloys. Only the M23C6 type carbide was detected during solution treatment. Complete precipitate dissolution occurred in all the three alloys after solution treatment. The holding time required for complete precipitate dissolution increased with increasing carbon content and decreasing solution treatment temperature. Complete precipitate dissolution occurred in the Co-Cr-Mo-C alloys solution treated at 1523 K for 43.2 ks; they were then subjected to aging from 873 to 1473 K for a heating time up to 44.1 ks after complete precipitate dissolution in solution treatment at 1523 K for 43.2 ks. The M23C6 type carbide with a grain size of 0.1–3 m was observed after aging. A time-temperature-precipitation diagram of the M23C6 type carbide formed in the Co-28Cr-6Mo-0.25C alloy was plotted.

Abstract: After development of the well-known T/P91 steel grade in the early 80’s and its long industrial experience since early 90’s, it has been necessary to develop new martensitic creep resistant steels to answer the demand of the power generation industry. New USC (ultra-super critical) boilers require materials with advanced creep properties to reach severe steam parameters. Addition of W to the steel has been found by many researches to be effective to increase creep rupture strength at high temperatures and already used in some developed steel grades such as T/P92, T/P122 and AISI 422 for the USC boilers. Recently, long-term creep strength of the advanced high Cr ferritic steels has been argued regarding the instability of their microstructures at high temperatures over 600 °C. This microstructural instability seems to be enhanced with increasing Cr content or with substitution of Mo by W in the steels. The aim of this paper is concentrated on the investigation of the microstructural development of the studied steel using the Jominy end-face quench test. Different hardness profiles from this test were introduced.

Abstract: The effect of the betatizing conditions on microstructure, transformation characteristics and pseudoelastic behavior has been studied in an unidirectionally solidified Cu-Al-Ni based alloy. The coarse γ2 phase is precipitated in the cast-rod betatized at 650
 and the volume fraction of it is decreased by increasing the betatizing temperature above 700 . However, a small amount of γ2 phase is left behind despite betatizing at 800 . No martensitic transformation takes place in the cast-rod betatized at 650, because the precipitation of γ2 phase leads to stabilization of β1 parent phase. However, β1→β1′ martensitic transformation occurs in the cast-rod betatized at 700  and both β1→β1′ and β1→γ1′ martensitic transformations concurrently undergoes in the cast-rod betatized above 750  because of the slope of Al concentration nearby γ2 phase. The loaddisplacement loop of the as-cast rod betatized at 750  is linear, but those of the as-cast rods betatized at 800  and 850  are non-linear showing the typical pseudoelastic loop and the deformation is completely recovered upon unloading.

Abstract: The effects of flash-heating and aging on the microstructure and transformation characteristics has been studied in Cu-Al-Ni based melt-spun ribbons. When the as-spun ribbon, stabilized due to higher Al content and fast cooling, is flash-heated at 750 °C, the β1 parent phase is partially retained. Even though flash-heating temperature is increased upto 850 °C, a little β1 parent phase with lager grains above 10 μm is still retained. The Ms temperature is increased with increasing flash-heating temperature due to the decrease of grain constraint within grown grains. However, the greater part of β1 parent phase with smaller grains of 2 ~ 3 μm is transformed to martensite in the initial stage of aging at 200 °C. The Ms temperature of the ribbon with smaller grains is higher than that of the ribbon with larger grains. It is considered that the increase of Ms temperature is caused to the disappearance of lattice defects introduced during melt spinning by aging at 200 °C rather than grain growth.

Abstract: In this paper we will discuss the impact of residual stresses on the reliability of microelectronic components and the materials used therein. The following issues will be particularly emphasized: First, the tendency toward delamination and subsequent cracking along interfaces, such as between silicon dies, organic substrates, glues, and underfill material; second, the fatigue of electrolytically deposited copper vias within the substrate and FR4 board material; third, the accumulation of irreversibly accumulated plastic (creep) strain in lead containing as well as leadfree solders; the microstructural change observed during thermo-mechanical use within the bulk as well as at the interface of solder interconnects. We will present state-of-the-art numerical techniques that allow to quantify the development of stresses and strains within the aforementioned materials, mostly by finite element analysis, as well as the coupling between local stresses and diffusion processes, which is theoretically based on phase field models. Further emphasis is put on proper knowledge and determination of the inherent material parameters and how theoretical predictions can be linked to and validated by experimental observations and facts.