Papers by Keyword: Microwave Hydrothermal Process

Abstract: Nanostructured cobalt sulfide(CoS) can be widely used as high energy density batteries, supercapacitors, solar photovoltaic materials and catalysts due to its excellent electronical, optical, magnetic and catalytic performance. In order to synthesize CoS crystallites in a efficient route, a facile microwave hydrothermal process was developed by using cobalt nitrate hexahydrate and thioacetamide(TAA) as source materials. The phase compositions and morphologies of the crystallites were characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). The influences of microwave hydrothermal temperature and time on the phase, grain size and morphology of the CoS nanocrystallites were particularly investigated. Results show that CoS crystallites can be obtained at the hydrothermal temperature of 180 °C. The as-synthesized CoS nanocrystallites are hexagonal phase that with the grain size of 10~30 nm. With the increase of hydrothermal time, the increase in particle size and the (102)-oriented growth are obviously.

Abstract: Nanocrystalline TiO₂ films were deposited on polymethylmethacrylate (PMMA) substrates by dip–coating process from colloidal anatase aqueous solutions. Microwave–hydrothermal process treating TiO₂ colloidal solutions was applied to enhance crystallization under a mild condition and avoid post–treatment. The as–prepared TiO₂ films were characterized and analysed by X–ray diffraction (XRD), UV–visible spectroscopy and atomic force microscopy (AFM). The photocatalytic degradation of Rhodamine B (RhB) under ultraviolet radiation was explored. Results show that pure anatase TiO₂ is achieved rapidly using microwave hydrothermal process. The TiO₂ suspension becomes uniformly disperse, stable and deposit-free after ultrasonic dispersion. The thin films deposited on unmodified PMMA substrates from the dispersive TiO₂ colloidal solution are dense, homogeneous, crack–free, without visible agglomerates and show high photocatalytic activity without post-treatment. Rhodamine B has been degraded over 99 % after 180 minutes under UV irradiation.

Abstract: One-dimensional (1D) nanostructure such as nanowires (NWs), nanobelts and nanorods have attracted tremendous attention in recent years due to their exceptional micro-structural properties and novel potential applications. In the present investigation, titania (TiO2) nanowires are synthesized by microwave hydrothermal process (MHP) treating TiO2 nano powder with NaOH inside a microwave oven for 5h at 210°C and 350W. The mechanical properties of as synthesized TiO2 nanowires are determined by bending it with a nanomanipulator inside a scanning electron microscope (SEM). Young’s moduli of the nanowires are measured to be approximately 11.870.923GPa.