Papers by Keyword: Mo-Ta Alloy

Abstract: The thermodynamic properties of high temperature metals and alloys are studied using the statistical moment method, going beyond the quasi-harmonic approximations. Including the power moments of the atomic displacements up to the fourth order, the Helmholtz free energies and the related thermodynamic quantities are derived explicitly in closed analytic forms. The configurational entropy term is taken into account by using the tetrahedron cluster approximation of the cluster variation method (CVM). The energetics of the binary (Ta-W and Mo-Ta) alloys are treated within the framework of the first-principles TB-LMTO (tight-binding linear muffin tin orbital) method coupled to CPA (coherent potential approximation) and GPM (generalized perturbation method). The equilibrium phase diagrams are calculated for the refractory Ta-W and Mo-Ta bcc alloys.

Abstract: Fractography was used in order to investigate the effects of Ta addition on the diffusion behavior of carbon in molybdenum. Mo-1.5mass%Ta alloy was carburized by the solid-state carburization process at a temperature between 1073 and 1473 K. Fracture surface of the specimen was observed before and after the carburization process and carbon diffusion distance was estimated from the change in fracture mode as a function of distance from the specimen surface. Results are as follows. (1) Ta addition slightly decreased the carbon diffusion distance. (2) Ta addition had almost no effect on the activation energy for diffusion. (3) These results suggest preferential combination between carbon atoms and Ta atoms is only minor.