Papers by Keyword: Mössbauer Spectrometry

Abstract: Mössbauer studies of bioreduction products stabilized by acetone and ethanol were carried out at wide temperature range from 80 K to room temperature and in external magnetic field applied perpendicular to γ-beam at room temperature. The initial products (mixture of non-stoichiometric magnetite and maghemite) were formed during the iron reduction of synthesized ferrihydrite by bacterium G. ferrihydriticus. The addition of acetone and ethanol led to slight particle size decrease. The average size and magnetic moments were 11.2 nm and 524 µ_B, respectively.

Abstract: The local environment issued from the phase decomposition in Fe-25Cr-12Co-1Si alloy during step ageing has been studied by 57Fe Mössbauer spectrometry. The phase decomposition is influenced by both ageing time and temperature. It processes rapidly when ageing temperature is high. The formation of different kinds of (Fe, Co)-rich, Fe-rich and Cr-rich domains with independent hyperfine parameters during phase decomposition was characterized by hyperfine field distribution. The magnetic hardening of the alloy was discussed basing on single domain particle model.