Papers by Keyword: Multiphase Diffusion

Abstract: Periodic layered morphology may occur during displacement solid-state reactions in ternary (and higher-order) silicide and other material systems. This periodic layered structure consists of regularly spaced layers (bands) of particles of one reaction product embedded in a matrix phase of another reaction product. The number of systems that is known to produce the periodic layered structure is rather small but increasing and includes metal/metal and metal/ceramic semi-infinite diffusion couples. The experimental results on different systems, where the periodic pattern formation has been observed are systematized and earlier explanations for this peculiar diffusion phenomenon are discussed. Formation of the reaction zone morphologies periodic in time and space can be considered as a manifestation of the Kirkendall effect accompanying interdiffusion in the solid state. The patterning during multiphase diffusion is attributed to diverging vacancy fluxes within the interaction zone. This can generate multiple Kirkendall planes, which by attracting in situ-formed inclusions of “secondary-formed phase” can result in a highly patterned microstructure.

Abstract: The work is devoted to the study of contact melting in the Al-Si system, which is an aluminum film deposited on a silicon single-crystal substrate. The impulse action of high-density currents (j> 8.1010 A / m2) passing through an aluminum film is analyzed. It was found that under the considered electric heat loads in the system, the degradation processes associated with the appearance of a molten aluminum zone and subsequent contact melting in the metal-semiconductor system develop. From the analysis of contact melting processes, a technique for estimating the coefficients of multiphase diffusion in the system under consideration is a thin aluminum film-single-crystal silicon substrate.