Papers by Keyword: NMR Relaxation

Abstract: The superconducting iron-pnictides SmFeAsO1-xFx (x = 0.15 and x = 0.2) are studied by means of 19F-NMR spectroscopy and SQUID magnetometry. Fluctuating diamagnetism above Tc is briefly examined, stressing the analogy with the phenomenology in underdoped cuprates. The 19F relaxation rate allows us to infer an indirect magnetic coupling between Sm3+ moments, possibly involving conduction electrons in FeAs bands, with no appreciable effects on crossing the superconducting transition temperature. A comparison between the superconducting samples and the insulating SmOF, often present as spurious phase in SmFeAsO1-xFx pnictides, is also carried out. Relevant differences in the spin dynamics features are found.

Abstract: Materials with an average particle size of less than about 50 nm often show new or at least enhanced physical properties. In many cases nanocrystalline ionic conductors exhibit a high increase of cation, e. g. Li+, or anion, e. g. F−, diffusivity. In the present contribution we review recent studies on ion dynamics in nanocrystalline ion conductors, both single-phase systems and composites, being prepared by high-energy ball milling. These include, e.g., LiTaO3, Li2O:Al2O3, LiF:Al2O3, BaF2, CaF2, BaF2:CaF2 and (BaF2:CaF2):Al2O3. Dynamic properties were probed by 7Li and/or 19F NMR line shape and relaxation as well as ion conductivity measurements.

Abstract: Multiple-time spin-alignment echo (SAE) NMR spectroscopy of spin- 3 2 nuclei is used to study ultraslow diffusion in the hexagonal layered Li ion conductor LixTiS2 (x  1). Two-time correlation functions were monitored by recording (Jeener-Broekaert) echo amplitudes for constant evolution and variable mixing times. Echo decay rates t