Papers by Keyword: Nanocrystalline Material

Abstract: The ability to control the mechanical properties of metal alloys is an urgent task in materials science. For formation of certain operational properties, in most cases, it is enough to treat the working surface of the product by laser radiation. Classical processing methods are ineffective in relation to multicomponent amorphous-nanocrystalline metallic alloys. This is due to their limited use. Usually, this treatment leads to the loss of unique properties the amorphous-nanocrystalline material. Increasing crack resistance and microhardness is not an easy problem. The structure of an amorphous nanocrystalline material can be destroyed under the action of laser processing. Laser nanosecond treatment, as result of a complex effect on the surface, slightly affects the structure of material. The treated material is characterized by increased microhardness and crack resistance, while at the same time such changes may be controlled.

Abstract: Nanomachining technology has broad application prospects and molecular dynamics method is an important research tools for studying nanoscale material removal mechanism. This paper is focused on the analysis of basic principle of molecular dynamics method and the progress of nanomachining model. The nanomachining mechanism of single crystalline brittle materials and plastic materials are investigated completely, micro-nanomachining mechanism of polycrystalline material is also summarized, The challenges and future development of the nanometric machining mechanism study are also discussed.

Abstract: This study reports on the fabrication of a Schottky solar cell with a cross-sectional schematic: ITO/PbS/Al with a commercial transparent conductive ITO and a p-type PbS absorber layer deposited by using a thermal evaporator. The structural and optical properties of constituent films are presented. X-ray diffraction showed that the thin films are polycrystalline. By using scanning electron microscopy, this study showed that the films possessed a uniform surface morphology over the substrate, and the films exhibit a nanocoral structure. Open circuit voltage,short-circuit current density and characteristics were studied under 30 mW/cm² solar radiation.

Abstract: Recent Experiments on Nano-Crystalline Materials Show an Increase of Strain-Rate Sensitivity in Contrast to the Conventional Coarse-Grained Materials. these Materials Also Show a Different Grain Size Dependency as Compared to Coarse-Grained Materials. to Explain these Issues, a Constitutive Equation Is Proposed which Considers Dominant Deformation Mechanisms Including Grain Interior Plasticity, Grain Boundary Diffusion and Grain Boundary Sliding. the Stresses Obtained from these Constitutive Equations Match Well with the Experimental Data for Nanocrystalline Copper at Different Strains and Strain Rates. the Model Also Well Predicts Variation of Strain Rate Sensitivity Parameter. this Variation Can Be Explained with Regard to the above Mentioned Effective Deformation Mechanisms. Deviation from the Hall-Petch Law and Inverse Hall-Petch Effect Are Also Well Illustrated by the Model.

Abstract: The texture evolution of the pure iron sample after the surface mechanical attrition treatment (SMAT) was investigated by means of electron backscattering and X-ray diffraction (XRD) analysis. Experimental observations indicated that four sections along depth were formed in the pure iron sample during the SMAT, i.e., nanostructured regime in the surface layer, submicro-sized, micro-sized and plastic deformed regime. Compared to the microstructure of sample, texture analysis was performed. It can be found that the <110>//ND fiber texture is the prominent texture. A strong orientation of (110)[11] along the <110>//ND fiber was formed in the plastic deformed regime, and as the depth from the top surface decreases, <110> //ND fiber texture intensity increases. The maximum intensity was reached in the micro-sized regime, and then it start to reduce. In the nanostructured regime, <110> //ND fiber texture nearly disappear.

Abstract: The microstructure of a Ni–18 wt.% Fe electrodeposits having a banded structure is described in detail. The aim is to investigate the influence of the banded structure on grain growth behaviour and texture and to elucidate if there are other mechanisms operative in the stabilization of nanocrystalline electrodeposits. Spectroscopy techniques have been used to characterize the variations in alloy/impurity concentration perpendicular to the growth direction. The influence of these chemical variations on the microstructural evolution has been monitored by in-situ annealing treatments in the TEM. Local texture of the annealed material has been determined by use of the electron backscatter diffraction (EBSD) technique. SEM and TEM investigations have shown that the banded structure is not related to phase changes and that grain growth is not affected by the banded structure, i.e. there is no preferred growth along bands. The first grown grains have <100>, <112> and <111> orientations with the growth direction and upon further grain growth a <111> fibre texture with respect to the growth direction of the electrodeposits is formed. The banded structure seems not to affect the general behaviour of nanocrystalline electrodeposits.

Abstract: The nanocrystalline MgAl₂O₄ powder was prepared by thermal explosion mode of low-temperature combustion synthesis (LCS) using urea as fuel and nitrates as oxidizers. The molar ratio of nitrates to urea and the adiabatic flame temperature was calculated according to the propellant chemistry and combustion thermodynamics theory respectively, and the effect of thermal explosion temperature on the properties of powder was investigated. The phase and morphology of the synthesized powder were investigated by X-ray diffraction and scanning electron microscopy. The results showed that the combustion process completed in very shortly time, and the cauliflower-like powder with porous structure was obtained. The crystalline size of MgAl₂O₄ increased with the increasing of thermal explosion temperature, and the powder had good crystalline shape and purity. The average crystalline size of MgAl₂O₄ prepared at 400 was approximately 40nm.

Abstract: Single spinel phase nanocrystalline ferrite (Ni_0.5Zn_0.5)_1-XCo_xFe₂O₄was prepared using the spraying co-precipitation method. The coercivity of prepared (Ni_0.5Zn_0.5)_1-XCo_xFe₂O₄ increases with an increasing content of cobalt. The enhancement of the saturation magnetization was observed up to the maximum value of 102.1emu/g as x was 0.5. This can be attributed to the substitution of the Ni₂₊ and Zn₂₊ ions with Co₂₊ ions. This changed the net magnetic moment between the sublattices of structure.

Abstract: The texture evolution in the plastic deformation layer of the pure iron sample after the surface mechanical attrition treatment (SMAT) was discussed through electron backscattering and X-ray diffraction (XRD) analysis. The results showed that: the surface layer of the iron sample can be subdivided into four sub-layers along the depth from the top surface: nano-sized regime, submicro-sized regime, micro-sized regime and deformed coarse-grained regime. Nano-sized regime possesses random crystallographic orientations. But in submicro-sized regime and micro-sized regime, the //ND fiber texture is the prominent texture with a strong orientation of (110)[1-11]. Increasing treatment time during SMAT process does not change the components of texture in plastic deformation layer, only strengthen their orientation density.

Abstract: Optical microscopy on the etched cross-section of a nanocrystalline Ni-18 wt.% Fe electrodeposit revealed the existence of a banded structure perpendicular to the growth direction. To evaluate if the banded structure is affecting grain growth and texture development, EBSD orientation maps were obtained after annealing for 30 min at 300, 350, and 400°C. Grown grains were found to be random in shape and no preferential sites for grain growth were observed. The texture of the grown grains is changing upon annealing and the final fibre texture parallel to growth direction of the electrodeposit can be obtained from texture components found at lower annealing temperatures when performing one or two consecutive twinning operations.