Papers by Keyword: Oxide Coating

Abstract: The use of aluminum metal in daily life has widely used coloring techniques to enhance the aesthetic value of the metal. Aluminum anodizing process can produce porous on the metal surface. The formed porous can be used to store and hold the coloring agent to make them more durable. The research intends to observe the coloring characteristics on the aluminum surface influenced by several parameters of the anodizing process, including electrolyte concentration and electric current. In this study the current H2SO4 concentration was used as a variable to improve the quality of staining on anodized aluminum surfaces. The anodization process was carried out on H2SO4 electrolyte solution with variations in concentrations of 10% to 20% and the current density used was 3 A to 5 A. The tests were carried out using micro Vickers to observe the hardness value. The hardness was higher at lower concentration of electrolyte solution due to thinner layer of oxide film, scanning electron microscope to observe the structure and visual observations for anodized color quality. From the results given, the tendency of the lower current density the size and density of porous lower. With the same condition, the color was darker than higher current density.

Abstract: Anodic oxidation of Mg-Li-Al alloys using phosphoric acid-based bath were processed to obtain the corrosion-proof surface coating. The specimen oxidized at low voltage anodically dissolved without the formation of oxidized film. Anodic oxidation film could be formed at higher voltage due to thin layer preferentially formed on tthe active surface, this layer develops to stable thick film. There were no significant differences in film thickness between LA141 and LA143 alloys.

Abstract: AZ91 Mg alloy was micro arc oxidized under constant electrical parameters in silicate based and phosphate based electrolytes with and without addition of organic chemicals, namely Hexamethylenetetramine (HMTA), TRIS (hydroxymethyl) aminomethane (THAM) and Glycerol in two different concentrations. Following oxidation, samples were characterized by X-ray diffraction analysis (XRD), scanning electron microscopy (SEM), coating thickness measurements, hardness measurements and electrochemical corrosion tests. Results showed that coating layers mainly consisted of MgO, Mg₂SiO₄ and MgF₂ for silicate based electrolytes, and MgO for phosphate based electrolytes. Incorporation of organic chemicals into electrolyte composition did not change the type of the phases in the coating. However, when they are added in silicate based electrolytes, pore density and coating thickness are reduced and pore size is increased. On the other hand, there is no significant change in surface morphology when organic chemicals are added in phosphate based electrolyte. In the view point of corrosion resistance, organic chemicals did not enhance corrosion resistance of the samples oxidized in silicate based electrolytes, but exhibited some increment in corrosion resistance of the samples oxidized in phosphate based electrolytes.

Abstract: In this study, commercially pure titanium (Cp-Ti) was micro arc oxidized in an alkaline solution by using a bipolar power supply capable of applying square voltage pulses. In the oxidation process, voltage level and numbers of positive and negative pulses were varied, and the effect of such parameters on surface and cross sectional morphology of the coatings were evaluated. In characterization works, X-ray diffraction analysis (XRD), scanning electron microscopy (SEM), coating thickness measurements and surface roughness measurements were employed. Results generally showed that coating thickness and surface roughness greatly depend on the voltage level in that higher voltage levels give thicker coatings and rougher surfaces. When the number of successive positive voltage pulses is increased, more uniform surface appearance with well distributed and equal sized micro pores are obtained up to 400 V of positive voltage. When the oxidation is performed for positive and negative pulse numbers of 10-1 at higher voltage levels, the average pore size of the coating thickness increased and the number of pores decreased.

Abstract: The present paper is a review on the oxidation kinetics, electrical properties, chromium vaporization rate and microstructure investigations of oxide products formed on an uncoated Crofer 22 APU alloy and 1.4762 steel and coated by means of pulsed laser deposition and screen-printing methods with films of (La,Sr)CoO₃, (La,Ca)CrO₃, (La,Sr)CrO₃, (La,Sr)(Co,Fe)O₃ and MnCo₂O₄ in air and Ar-H₂-H₂O and Ar-CH₄-H₂O gas mixtures at 1023-1173 K for up to 1200 hrs. Microstructure investigations using SEM-EDS showed the influence of the reaction products formed in different atmospheres at the steel/coating interface on the electrical properties and Cr vaporization rate of these composite materials, which are used for construction of SOFC interconnects.

Abstract: Magnetic properties of iron-containing coatings obtained on aluminum by plasma electrolytic oxidation were analyzed in this paper. Theoretical curves of demagnetization of these objects are obtained. It is shown that the magnetic states of the analyzed samples can be caused by the presence of several phases with very different magnetic properties.

Abstract: The pure titanium long-cups were formed by preventing the seizing in cold multi-stage deep drawing processes. For the prevention, pure titanium sheets were treated by heating oxide coating. The coating is very effective in preventing the occurrence of seizure and galling. The fresh and clean titanium is not in direct contact with the die during the forming due to the existence of the oxide layer. In multi-stage deep drawing, pure titanium sheets of the JIS grade 2 was employed. Various cups were drawn by exchanging the punch and ringed die. The die was flat in the first stage, and was taped without a blankholder in the subsequent stages. The effects of the coating conditions on the occurrence of seizure in multi-stage deep drawing were examined. It was found that the coating titanium sheet has sufficient ability in preventing the seizure in multi-stage deep drawing processes. The pure titanium long-cups were successfully formed by a multi-stage deep drawing operation in cold.

Abstract: Oxide coatings offer great potential for their use in forming operations in the semi-solid state. Advantages of these types of coatings are high resistance against abrasive wear, high hot hardness and low thermal conductivity. Nevertheless deposition by pulsed Magnetron Sputter Ion Plating-PVD for oxide coatings is quite challenging: deposition rates are low and insulating layers on the target surface can cause arcing. On laboratory scale it was possible to deposit γ-Alumina using PVD in a temperature range, where hot working steel can be utilized. The next important step in the development towards an industrial application for larger forming tools is the upscaling process to larger coating units. In this work the process development of oxide coatings on an industrial coating unit for large tools was described. To increase adhesion of oxide top-layer additional bond coats were applied. Different process parameters like oxygen content, total pressure and substrate bias were varied, to improve the performance. The relationship between coating properties and process parameters of the deposited films were characterized by X-Ray-diffraction, Nanoindentation and Scanning Electron Microscopy (SEM). By using reactive pulsed PVD-process it was possible to deposit γ-Al2O3 on large steel tools for semi-solid melt protection. The developed coatings showed for thixoforging processes of X210CrW12 an extraordinary stability in field tests. The lifetime of the permanent moulds was increased by using PVD thin film coatings as a tool protection.

Abstract: In the multi-stage deep drawing processes of a beta titanium alloy sheet, the formability has been investigated. The beta titanium alloy sheets have sufficient ductility at room temperature, whereas a seizure tends to occur during deep drawing due to high reactivity with other materials. To prevent the seizure, the beta titanium alloy sheet was treated by oxide coating heating, because the coated sheet was not in direct contact with the die during deep drawing due to the existence of the oxide layer. The blank used was the commercial beta titanium alloy Ti-15V-3Cr-3Sn-3Al. The effect of the coating condition on the formability in the multi-stage deep drawing process was examined. It was found that long drawn cups with a height sixfold that of the diameter were successfully formed by oxide coating heating.