Papers by Keyword: Oxide Film

Abstract: The effect of grain size on the initiation behavior of exfoliation corrosion in cold-rolled Mg-14mass%Li-3mass%Al alloy was examined. Exfoliation corrosion initiated after 30 minutes in the coarse-grained structure (279μm), whereas it was delayed to 60 minutes in the fine-grained structure (75μm) and further to 75 minutes in the ultrafine-grained structure (39μm). This delay is attributed to the suppression of shear band formation and localization during cold rolling with decreasing grain size, which enhances the uniformity of surface reactions in the corrosive environment and promotes faster and denser formation of the protective film at the early stage. Accordingly, the improved condition of the initial corrosion film is considered the primary factor responsible for the delayed onset of exfoliation corrosion.

Abstract: In order to generate a nanoporous oxide film, stainless steel 304L is anodized using an alternating current (AC) and direct current (DC) source in an ethylene glycol solution containing ammonium fluoride, NH₄F, and water, H₂O. This study focuses on the differences between AC and DC anodizing in terms of current density versus time response, thickness, and depth of the oxide film formed on the anodized specimens, surface roughness, and element composition of the specimens because there is limited study on AC anodizing of stainless steel. In 0.5% 0.3M NH₄F and 3% H₂O in a glycol solution, the AC and DC anodizing is conducted for 30 minutes at voltages ranging from 30 V to 50 V and 21.2 V to 35.4 V, respectively. The current density versus time response revealed that AC anodizing produced more current density than DC anodizing. As for the thickness and depth of the generated oxide films, only the specimens that had been anodized in AC indicated an increase in these films, whereas specimens that had been anodized in DC showed the metal dissolving as the specimens degraded. The surface roughness of AC anodized specimens reduced with increasing anodizing voltage, whereas DC anodized specimens increased with increasing anodizing voltage. The element composition of the anodized specimens revealed that the mass percentage of oxygen, O element is higher for AC anodized specimens compared to DC specimens. This suggests that AC anodizing on stainless steel might offer important advantages and should be further researched.

Abstract: The research data on the specific features of the formation of oxide films on the Ti6Al4V alloy in the ethylene glycol-water electrolytes have been given. The kinetic dependences obtained for the alloy allowed us to establish that the specific features of the formation of oxide films during the electrochemical oxidation of the alloy surface depend on the solution composition and the current density. For the water-to-alcohol ratio of 50:50 the kinetic dependences show the sections that correspond to the formation of the barrier oxide layer and also to the formation of the pores due to the desorption of fluoride ions and the growth of the porous portion of oxide. As the water-to- alcohol ratio is decreased the indicated peculiarities of kinetic dependences are met not so often and do not obey any regularity. The obtained data are explained by the fact that an increase in the portion of the organic component of the solution results in a decreased etching capacity of the electrolyte due to the controlled activity of fluoride ions. The anode current density value has a similar effect on the variation of kinetic dependences. Its effect is explained by that an increase in the alloy oxidation rate results in the fast formation of the surface oxide and the specific features of kinetic curves are concealed. The linear relationship between the formation time of oxide of a minimum thickness for given conditions and the current density is unavailable and it is conditioned by the chemical interaction of the oxide film with electrolyte components. The obtained research data can be used for the formation of the individual bioinert and bioactive coatings for the implants of a medical purpose or for the formation of the matrix used for the production of composite coatings.

Abstract: This work investigated the influence of oxidation durations on the formation of oxide on the surface of wrought Co-28Cr-6Mo-1Si alloy. The iso-thermal oxidation was individually performed in air at 550°C for 4, 12 and 24 h. For comparison, the surface of the non-oxidized Co-28Cr-6Mo-1Si alloy was concurrently examined. The chemical compositions of the non-oxidized and oxidized alloys were principally analyzed via X-ray photoelectron spectroscopy (XPS). The XPS results revealed that the surface of the non-oxidized alloy enriched in Cr-oxide. After oxidation treatment, the Co-oxide, existing as Co²⁺ state was observed coexisting with two Cr-oxide states, Cr³⁺ and Cr⁴⁺. The low concentrations of Mo⁶⁺ were also observed on the oxidized alloy surface. With the increase in oxidation durations, the Co-oxide was suppressed by Cr-oxide. The XPS depth profile analysis indicated that the thickness of the oxide film increased with increasing the oxidation duration.

Abstract: This paper proposed a new method for processing titanium alloys based on preliminary plastic impact. The reasons for the deterioration of the surface roughness of titanium alloys during machining are considered. This problem lies in the formation of outgrowths on tool cutting wedge, which leads to the cutting process taking place as in the titanium-titanium pair. The adsorption phenomenon leads to the fact that the outgrowth is saturated with gases from the environment, and a thick oxide film is formed. As a result, high temperatures arise during machining from 1100 to 1200°C, increasing the cutting forces P and friction Q, which introduce the technological system into an unstable self-oscillating process. The problem posed eliminated by the method of preliminary plastic deformation, which forms a local inhomogeneous structure. At the stage of processing the titanium billet, the cutting edge enters the region with a heterogeneous structure, destroying the chips and growth with an oxide film. Since most of the temperature, about 80% takes away with the chips, the amplitude of the self-oscillating process decreases, which reduces the surface roughness of the processed titanium alloys.

Abstract: The structure and chemical composition of the surface layers of aluminum 6000-series alloys after crystallization and homogenization annealing at 580 °C were investigated. It is shown that the state of the surface significantly depends on the presence of impurities in the coolant of the crystallizer, which deteriorate the continuity of the oxide film, which leads to the formation of light color of individual parts of the ingot surface.

Abstract: Plasma electrolytic oxidation (PEO) is a technique employed to significantly enhance the corrosion and tribological properties of the materials by forming an oxide ceramic film on the surface of the material. In this investigation, ZM21 Mg alloy was subjected to PEO treatment in silicate and phosphate-based aqueous solutions of 5grams and 10 grams per liter concentrations. The oxide film was characterized using SEM, profilometer, thickness meter, and polarization test. Results showed that the oxide film obtained with 10g/L phosphate-based solution offers higher corrosion resistance than the oxide films formed with other solutions.

Abstract: The corrosion resistance of SZA-6 zirconium alloy(Zr-0.5Sn-0.5Nb-0.3Fe-0.015Si) cladding tubes finally annealed at 480°C, 510°C and 560°C were studied by static autoclave in 360°C/18.6 MPa pure water and 360°C/18.6 MPa/0.01 mol/L LiOH aqueous solution. The microstructure of the samples before and after corrosion were analyzed by EBSD, TEM and SEM. The results showed that the corrosion weight gains of the three SZA-6 alloy samples were lower than that of Zr-4 alloy after 500 days corrosion in both hydrochemical mediums. After long-term corrosion, the corrosion weight gains of SZA-6 alloy in pure water and LiOH aqueous solution increased obviously with the final annealing temperature, while the corrosion weight gain of unstressed Zr-4 alloy was higher than that of recrystallized under the same condition. With the increase of the final annealing temperature, the high-angle grain boundaries in the alloy larger than 15° became more and recrystallization degree also increased. The Second Phase Precipitates (SPPs) were fine, uniform, and dispersively distributed with an average diameter of about 120 nm. Although the size and distribution of the SPPs were similar, the Nb/Fe ratio in the SPPs increased. The long-term corrosion weight gain of zirconium alloy was related to the number of parallel cracks in the oxide film and the uneven growth degree of the oxide film on the interface of the oxide film/matrix. The corrosion resistance of the alloy in two hydrochemical mediums was related to the degree of recrystallization and the content of Nb in the SPPs. Increasing the final annealing temperature would promote the formation of fine and uniform recrystallized grains, which was benefit to the corrosion resistance, but at the same time it would reduce the content of solid solution Nb in the αZr matrix, which in turn would be detrimental to the corrosion resistance.

Abstract: Microstructure and mechanical property of the Mg-TM (TM=Ni or Cu) -Y alloys were investigated. Results revealed that Mg phase, Long period stacking ordered (LPSO) phase, and Mg₂TM phase were formed in the Mg-TM-Y alloy around the composition ratios of TM and Y are 1:1 or 1:2. Tensile test clearly showed relationship between the mechanical property and microstructure in Mg-Ni-Y cast alloy. The 0.2% proof stress (σ_0.2) of the Mg-Ni-Y cast alloy increase with the increasing solute elements contents, while the elongation decreases. This result indicated that the Mg-TM-Y alloy with the composition ratios of TM and Y are 1:1 or 1:2 have both high proof stress and appropriate elongation. It was suggested that the LPSO phase was appropriate strengthening phase in the Mg-rich region in the Mg-TM-Y alloy system. Basal texture of the LPSO and Mg phases was formed by hot-rolling in the sheet plane and the Mg₂TM phase was dispersed in the Mg phase. The Mg₉₇Cu₁Y₂ rolled sheet showed highσ_0.2 about 350 MPa at room temperature. Furthermore, formation of an oxide film on the Mg-Cu-Y alloy was investigated at 973 K in air. As a result, it was suggested that the Y₂O₃ film was formed on the re-melted Mg-Cu-Y alloy surface as an incombustible oxide film.

Abstract: The corrosion resistance of Stellite 6 alloy in morpholine solution with pH 9.5 is investigated using the electrochemical test method, simulating the amine environment of the boiler feed water service condition in coal power plants. Polarization test is performed on Stellite 6 alloy under the low potential varying from-0.4 V_SCE to 1.2 V_SCE and is also conducted under a constant high potential (4 V_SCE) in order to fail the sample surface. 17-4PH stainless steel, which is also a common material for the application of the boiler feed water in coal power plants, is tested simultaneously under the same conditions for comparison. It is shown that the polarization curve 17-4PH steel from the low potential test has an apparent passivation region indicating a protective oxide film formed on the sample surface, but Stellite 6 only exhibits a tendency to passivate. Both samples after the failure tests under the high potential (4 V_SC) are analyzed using SEM/EDX. The surface morphologies indicate that the former is severely corroded in the solution while the latter is less corroded. The corrosion mechanisms of Stellite 6 alloy and 174PH stainless steel in morpholine solution are discussed with assistance of the Pourbaix diagrams.