Papers by Keyword: Oxygen Isotope

Abstract: Based on a large number of carbon and oxygen stable isotope data, researched environment characteristics of Ordovician carbonate rocks in Yubei area, Tarim Basin. According to carbon, oxygen stable isotopes (&¹³C, &¹⁸O) data, combining the diagenetic environment characteristics studied all kinds of geochemical characteristics of rocks in Yubei area. The research results show that: Paleosalinity feature of Ordovician carbonate rocks in this area reflected the carbonate rocks is formed in the stability of the marine environment and basically kept the composition of carbon and oxygen isotopic of the original environment. the paleo temperature characteristics indicate that the diagenetic burial depth was increased first and then decreased, the sea level characteristics indicate that the sedimentary strata by Yingshan period to Lianglitage period corresponds with a rise in sea level.

Abstract: Poyanghu Lake located in the northern Jiangxi Province is the largest freshwater lake and also the second largest lake in China. In the present contribution, several water samples have been collected and carried out for hydrogen and oxygen isotope analyses. The results suggest that they have relatively higher hydrogen and oxygen isotopic ratios than those of meteoric water. Combined with previous data, we propose that the Poyanghu Lake water display higher stable isotopic compositions due to the strong evaporation and water-rock interaction.

Abstract: The stable isotope composition of river water contains some information of water cycle and climatic factors, such as precipitation, evaporation and temperature. Oxygen isotopes in river water were monitored at one site in Jinxiuchuang basin of Jinan southern mountain.δ¹⁸O values of river water show a variation from-7.82 on July 6 to-9.98 on June 6. The result reveals that the river water was mainly supplied by the precipitation. The isotopic variations at Jinxiuchuan river have strong precipitation patterns owning to different rainfall in summer.

Abstract: High temperature reactivity of materials under oxidizing atmospheres is based on the formation of protective oxide scales. The protectiveness is obtained when the thermally grown oxide scales are dense, continuous and adherent to the metallic substrates (even during thermal shocks); as a matter of fact, the growth of the scale has to be governed by diffusion of species across the growing scale. The diffusing species are coming from the substrate (metallic ions) and/or from the oxidizing atmosphere (oxygen ions). The understanding of growth mechanisms can be reached by making two stage oxidation experiments, using oxygen isotopes. The experiment consists in oxidizing first the metallic substrate in 16O2, evacuating the oxygen after the desired time, and replacing it by 18O2. The distribution of oxygen isotopes given by secondary ion mass spectrometry (SIMS) across the oxide scale informs about the growth mechanisms: anionic transport, cations diffusion or mixed diffusion processes. The use of marker experiment is able to determine the oxygen diffusion coefficients within the growing scales. In this case, a thick scale is grown under 16O2, followed by a shorter diffusion experiment in 18O2. The distribution of 18O isotope across the scale by plotting ln (18O intensity) versus x (depth in oxide) allows determining the oxygen effective diffusion coefficient in the scale, according to the classical Fick’s law solution. A more accurate analysis of these profiles can provide information about bulk and grain boundary diffusion of oxygen. The results can be related to kinetics according to Wagner’s theory. The proposed work consists firstly in making a state of the art review about oxygen diffusion in thermally grown oxide scales, and secondly in connecting the so-obtained outcome (effective, bulk and grain boundary diffusion) to kinetics results. The proposed oxides are chromia, alumina and zirconia.