Papers by Keyword: Phase Transformation

Abstract: It has been established that external uniaxial tensile stresses influence the character and kinetics of the g®a-transformation in cold-rolled martensite steel at sub-zero temperatures (down to -60 °C).

Abstract: Ti-Ni based shape memory alloys (SMAs) are of excellent shape memory effect, superelasticity and damping property. These properties of the alloys can be fully displayed only after proper heat treatment. In this paper, the research progresses of the effect of the heat treatment on the microstructure, phase composition, phase transformation behaviors and shape memory properties in Ti-Ni based SMAs are reviewed, the correlation influence mechanism is summarized, and the future research directions in this field are pointed out. It is expected to provide reference for the development of Ti-Ni based SMAs and their heat treatment technologies.

Abstract: The phase compositions of surface and interior in Ti-32Nb-4Sn metastable b alloy were investigated. It was found that this alloy exhibits surface effect significantly different from the effects reported in Ti-10V-2Fe-3Al, Ti-22Nb-9Zr and the other titanium alloys. The surface of Ti-32Nb-4Sn specimen quenched from single b phase region was characterized by dominant b phase and a few of α″ and ω phase. While in the interior of the alloy, a large amount of α² martensite phase was observed in addition to b phase The orientation relationship between the α″ martensite and β phase is (110)_β∥(002)_α″, (020)_β∥(022)_α″ and [001]_β∥[100]_α″.

Abstract: Through the Gleeble3500 thermal simulation test machine, the phase transformation law of Nb microalloyed steel was studied and tested. After the compression deformation, it was cooled to room temperature at different speeds. Obtain the dynamic continuous cooling transformation diagram and the scanning structure diagram of the test steel, and then analyze the phase composition under different cooling speeds through JMatPro material performance simulation. The results show that: at a lower cooling speed (0.1°C/s), austenite decomposition is a diffusion-type phase change that takes place in a high-temperature region, and carbon atoms can diffuse sufficiently. At a moderate cooling rate (1°C/s), the bainite phase transition is a semi-diffusion phase transition in which carbon atoms are displaced in a non-cooperative thermally activated transition mode. When the cooling rate is high (15°C/s), the martensitic transformation is a non-diffusion-type transformation carried out in the low temperature region, and the atoms are directly transferred from the austenite lattice to the martensite lattice. With the increase of the cooling rate and the decrease of the transition temperature, from low-speed cooling→medium-speed cooling→high-speed cooling, respectively, the diffusion type phase transition→semi-diffusion type phase transition→the non-diffusion type phase transition. At different cooling rates, the continuous cooling transition diagram simulated by JMatPro is basically the same as the phase transition in the dynamic continuous cooling transition diagram of the test steel, which proves that the simulation prediction of the dynamic continuous cooling transition of the test steel by the JMatPro software has high accuracy and applicability.

Abstract: First, the metallic oxides of PbO, TiO2 and ZrO2 were mixed following (2, 1, 1) molar mass respectively. Then 4 samples were separated (S1, S2, S3 and S4). the first one S1 was subjected to calcination treatments at 600, 700 and 800 °C however, the S2 was treated at 700 °C only, the S3 at 800 °C and S4 at 850 °C. The X ray diffraction of the samples reveals important difference in the phases obtained, at 600 °C the quadratic riche phase of PbTiO3 was mainly observed on sample S1, after the treatment at 700 °C and 800°C, the same XRD patterns were obtained with the same peaks positions and the relative intensity. However the S2 revels different pattern from S1 at 700 °C relative to the formation of the Pb(Zr0.75, Ti0.25)O3 Rhombohedral riche phase. The S3 XRD results reveal also different pattern from S1 at 800 °C relative to the formation of Pb (Zr0.58, Ti0.42) O3 near the Morphotropic phase boundary (MPB) and the S4 confirm these finding. Thin films grown from the S1 and S4 used as target in the RF sputtering system, show important difference in the PZT stoichiometry obtained which is relative to Pb (Zr0.44, Ti0.56) located in the quadratic riche phase and Pb (Zr0.52, Ti0.48) O3 near the MPB respectively.

Abstract: Effects of peening direction on the reverse transformation induced by the shot-peening for the Fe-33 mass%Ni alloy with large amount of martensite (α’) are investigated. When the angle between the peened surface and the peening direction (Hereafter, peening angle) is 90 ^o, the reverse transformation occurs and subsequently martensitic transformation is induced by the shot-peening. On the other hand, in case of the peening angle of 30 ^o, only reverse transformation occurs. Furthermore, the volume fraction of austenite (γ) in the specimen after the shot-peening increases as the peening angle decreases. This means that the reverse transformation induced by the shot-peening is enhanced by decreasing the peening angle. Moreover, residual compressive stress around the peened surface increases as the peening angle decreases. Since the hydrostatic compressive stress decreases phase transformation temperature, the phase transformation temperature around the peened surface would be decreased by the shot-peening. Therefore, the reverse transformation behavior depending on the peening angle can be explained by the residual compressive stress due to the shot-peening.

Abstract: An in-house 2D finite volume model, specific for components of simple shape, was developed and applied to predict the thermal and microstructural evolution during heat treatment of steel forgings. The results of the thermal metallurgical modelling, including hardness profiles through the thickness, were compared with the experimental ones. Moreover, the 3D FEM software Deform-HT, able to calculate the thermal and microstructural evolution and the stress field during quenching, was specialized for the cases of interest. Examples of optimal heat treatment to develop the target microstructure and strength and reduce the risk of quenching cracks are discussed.

Abstract: The effect of strain rate on the β texture evolution during two-step hot forging of Ti-6246 alloy was investigated. The two-step forging consisted of 15% or 50% prior-β forging at 980°C and subsequent 60% or 25% forging at 870°C in the (α + β) dual-phase region. The total compression ratio was 75%, and the investigated strain rates were 0.01 and 1.0 s⁻¹. The β forging texture showed typical {001} and {111} body-centered cubic textures. With increasing compression ratio in the (α + β) region and at a strain rate of 0.01 s⁻¹, the amount of precipitated α phase increased. Dynamic recrystallization was rarely observed after forging in the (α + β) region at a strain rate of 0.01 s⁻¹. Large amounts of α precipitates lowered the {001} β texture intensity through slip transmission between the α and β phases under the Burgers orientation relationship. However, in specimens forged at a strain rate of 1.0 s⁻¹, as the compression ratio in the β single-phase region increased, the growth of dynamic-recrystallized β grains was promoted at the prior-β grain boundaries, where α-phase precipitation was not substantial. These effects resulted in a higher {001} texture intensity of the β phase in specimens forged at 1.0 s⁻¹ compared with that of the β phase in specimens forged at 0.01 s⁻¹.

Abstract: The effect of tempering time on the microstructure and mechanical properties of SA738 Gr.B nuclear power steel was studied using SEM, TEM and thermodynamic software, and its precipitation and microstructure evolution during tempering were clarified. The results showed that SA738 Gr.B nuclear power steel has better comprehensive mechanical properties after tempering at 650 °C for 1h. With the extension of the tempering time, M₃C transformed into M₂₃C₆ with increasing size, which affected the yield strength and impact energy. When the tempering time is 8h ~ 10h, due to the transformation of M₃C to M₂₃C₆, the composition of matrix around the carbide changed, causing the temperature of A_c1 dropped, forming twin-martensite which deteriorated the impact toughness of the steel.

Abstract: Characterization of advanced materials by neutron powder diffraction provides information not accessible by other techniques. Thanks to the low absorption of neutrons, the bulk of the material and large-grain samples can be investigated, moreover in situ at elevated temperatures. The neutron diffraction use is demonstrated on two types of technologically important materials: Ti-Zr alloy and Co-Re high temperature alloy. In Ti-Zr alloy, the residual stress relief and microstrain evolution after ECAP was established. Boron influence on TaC strengthening precipitates in Co-Re high temperature alloys was shown not to be significant at the foreseen alloy operation temperatures, although boron content has a strong influence on the matrix phase.