Papers by Keyword: Polycarbonate (PC)

Abstract: Due it increasing use in electronics, polymers, mainly acrylonitrile-butadiene-styrene (ABS) and its blend with polycarbonate (PC), are making considerable part of electronic waste. It has been proven that halogenated flame retardants used in polymers for electronics are toxic to environment and human health. Aim of the research is to evaluate the effects of nanostructured montmorillonite clay (D43B) addition on the mechanical and thermal characteristics of PC, ABS and its binary blends. The effect of substitution of virgin polymers in the blend with recycled ones has been also investigated. It has been determined that as far as the recycled polymer content in the composites does not exceed 10wt.%, tensile and thermal properties of the systems are not considerably affected. Addition of D43B up to 1,0-1,5wt.% contributes to the increment of mechanical stiffness, strength and thermal stability of the composites.

Abstract: The surface disordering produced in polycarbonate specimens by 130 keV Ar+ ions has been investigated. The effect of argon ions on the surface structure of polycarbonate specimens has also been studied. The polycarbonate specimens were implanted with 130 keV Ar+ ions in the dose range of 1×1014-1×1016 ions cm-2. The change in the Urbach energy (disorder parameter) after implantation has been estimated using Urbach edge method by applying UV-Visible spectroscopic technique. Optical energy gaps of virgin as well as implanted specimens have also been calculated using UV-Visible spectroscopic technique. A clear enhancement in Urbach energy (disorder parameter) from 0.61 eV (virgin sample) to 1.38 eV (at a fluence of 1×1016 Ar+ cm-2) and a drastic decline in optical energy gap (4.1 eV to 0.63 eV) with increasing implantation dose has been observed. This decrease in optical energy gap has been found to have linear dependence on the increase in the Urbach energy which point towards the formation of disordered structures in the implanted layers of polycarbonate. The structural changes produced due to implantation have been studied using Attenuated Total Reflectance-Fourier Transform Infrared spectroscopic technique. Furthermore, Knoop microhardness has been found to be enhanced 14 times (at a load of 9.8 mN) after implantation. The possible correlation of the increase in Knoop surface hardness with the structural changes observed as a result of implantation has been established and discussed.

Abstract: In the present work the effect of plasma treatment has been used to improve the surface properties of polymeric membranes. The polymeric membranes of polycarbonate (PC) were synthesized using solution cast method. The plasma treatment was done in high vacuum chamber using nitrogen gas and the pressure for the plasma treatment was » 10-2 mbar. The effect of plasma treatment on surface properties like morphology, roughness, wettability and optical properties has been characterized using optical microscopy and UV-Vis spectroscopy for different time of plasma treatment.

Abstract: Stress-strain relationships of polycarbonate (PC) were determined over a very wide range of strain rates including shock wave regime. High-velocity plate impact tests, drop-weight tests, and quasi-static tests using universal and Instron testing machines were used for the high strain rate (107 s-1), medium strain rate (102 s-1) and low strain rate (10-4 s-1) tests, respectively. The revised unsteady wave sensing system (UWSS) for plate impact tests was newly developed to determine the stress-strain relationships and Hugoniot linear relation of PC. The system consists of a powder gun for plate impact tests and three polyvenylidene fluoride (PVDF) gauges embedded in the PC utilizing a newly developed nanosecond UWSS. As originally proposed, UWSS is aimed in obtaining experimental inputs for the Lagrangian analysis used to determine the dynamic behavior of materials. The new method to determine also the shock Hugoniot stress-strain curves is proposed for PC at medium particle velocities up to about 1 km/s. The revised, unsteady wave sensing system (M-UWSS, which we proposed before) using plate impact experiment with three PVDF gauges embedded is applied to construct stress-strain curves under shock loading up to Hugoniot stress σH and Hugoniot strain εH. Linear relationship between shock velocity Us and particle velocity Up: Us = C0 + S x Up, where C0 and S are material constants, is used to determine the constant S, since the constant C0 is determined as bulk sound velocity at ambient pressure. By using the momentum conservation and the mass conservation relations, S = (1 - C0 / CH) /εH, is derived from the linear relationship described above, where , ρ is density and CH ≈ Us.

Abstract: The purpose of this work was to investigate the effects of pre-load static load and dynamic load on the visco-elastic in polycarbonate. In the paper, static-dynamic sweep experiment of polycarbonate was performed on EPLEXOR 500N, which was manufactured by GABO of Germany. The variation laws of storage modulus, loss modulus and loss tangent as changing dynamic load in a large range were systematically analyzed and the spectral characteristics of dynamic-viscoelastic under static-dynamic loads were obtained. The experiment results on dynamic visco-elastic under the high load shows that the load effects on dynamic visco-elasticity of polycarbonate performing on the changing of the dynamic visco-elastic parameters, storage modulus become lager with the increasing of static load and decreasing with the increasing of dynamic load, while loss tangent decreases with the increasing of dynamic load and varies in a more complicated pattern as the increasing of static load.

Abstract: Polymers are vital materials in better performance of specific strength. However their application can be restricted by the lower glass transition temperature, Tg. Some polymers have been developed as engineering plastics for the high temperature applications. We examined the high temperature strength of polymers at constant applied stress. The creep rupture and viscoelastic behavior were scrutinized for PC (polycarbonate) and PMMA (polymethyl methacrylate), which were quite different in the molecular structures. The former contains benzene rings and the latter is a single polymer. Tg is 423 K for PC and 378 K for PMMA. The large difference in the creep behavior was observed near Tg. The creep life strongly depends upon the applied stress just below Tg. The creep life is a function of the applied stress as follows. n life t − µ s . The stress exponent, n depends upon the temperature. Mechanical models were applied to evaluate the viscoelastic properties of the polymers at high temperatures. The viscosity rapidly decreased near Tg , regardless of the smaller decrease in the elastic constant. The results would be due to the difference in the molecular structures. The benzene ring could contribute to the higher resistance against the creep deformation through the higher viscosity.

Abstract: In this paper, the TiNi fiber reinforced / PC composite material was developed, and then control of the fatigue crack growth due to the shape memory effect was studied. Enhancement of mechanical properties and resistance of deformation of the TiNi fiber reinforced / PC composite were investigated by fatigue experiments. The fatigue behavior and crack propagation were in-situ observed with a SEM servo-pulser (fatigue testing instrument with scanning electron microscope) while increasing temperature. As the results, the fatigue life was improved, and the effectiveness of fatigue resistance was confirmed. The shape memory effect and expansion behavior of the matrix caused by temperature increasing examined the effect of the fatigue crack propagation control. It was verified that the control of fatigue crack growth is attributed to the compressive stress field in the matrix due to shrinkage of the TiNi fibers above austenitic finishing temperature (Af).