Papers by Keyword: Polymerization Stress

Abstract: Local polymerization stress occurs due to polymerization shrinkage of resin based composites adhesively bonded to tooth tissues. Shrinkage causes local displacements of cavity walls, with possible occurrence of micro-cracks in the enamel, dentin and/or material itself. In order to design a cavity for experimental testing of polymerization shrinkage of dental composites using 3D optical analysis, in this paper finite element method (FEM) was used to analyze numerical models with different cavity radiuses. 3D optical strain and displacement analysis of composite materials and cavity walls is limited by equipment sensitivity i.e. 0.01% for strain and 1 micron for displacement. This paper presents the development of 3D computer premolar models with varying cavity radiuses, and local stress, strain and displacement analysis using FEM. Model verification was performed by comparing obtained results with data from the scientific literature. Using the FEM analysis of local strains, displacements and stresses exerted on cavity walls, it was concluded that the model with 1 mm radius was optimal for experimental optical 3D displacement analysis.

Abstract: This study explores degree of vinyl conversion (DVC), polymerization shrinkage (PS) and shrinkage stress (PSS) of the experimental amorphous calcium phosphate (ACP) composites intended for use as an endodontic sealer. Light-cure (LC), chemical cure (CC) or dual-cure (DC; combined light and chemical cure) resins comprised urethane dimethacrylate (UDMA), 2-hydroxyethyl methacrylate (HEMA), methacryloyloxyethyl phthalate (MEP) and a high molecular mass oligomeric co-monomer, poly(ethyleneglycol)-extended UDMA (PEG-U) (designated UPHM resin). To fabricate composites, a mass fraction of 60 % UPHM resin was blended with a mass fraction of 40 % as-made (am-ACP) or ground ACP (g-ACP). DVC values of copolymer (unfilled UPHM resin) and composite specimens were determined by infrared spectroscopy. Glass-filled composites were used as controls. PS and PSS of composites were determined by dilatometry and tensometry, respectively. LC copolymers attained extraordinary high DVC values at 24 h post-cure (95.7 %), compared to CC (52 %) and DC (79.3 %) copolymer specimens. While the DVC values of LC and DC am-ACP composites were reduced between 5 and 10 %, DVC values of DC g-ACP composites increased almost 8 % compared to the corresponding copolymers. High DVC attained in LC composites was, expectedly, accompanied with high PS values (on average 7 vol%). However, PSS developed in LC and especially DC composites did not exceed PSS values seen in other UDMA-based composites. Based on this initial evaluation, it is concluded that, DC, g-ACP filled UPHM composite shows promise as an endodontic sealer. However, further physicochemical evaluations, including water sorption, mechanical stability and ion release as well as a leachability studies need to be performed before this experimental material is tested for cellular responses and, eventually recommended for clinical utility.