Papers by Keyword: Pyrotechnic Mixtures

Abstract: Pyrotechnic mixtures commonly present fast combustible and even detonable reaction. The process of the reaction produces huge heat and gases, featuring the origin of explosion. Therefore, in the practical situations, some catastrophic disasters usually occur in the storage houses and production factories related to those materials. For the safety consideration, the assessment on the explosive performance of pyrotechnic mixtures becomes necessary. In the paper, the pressure, temperature, and amount of gases from reaction of pyrotechnic compositions are obtained by establishing an analytic procedure based on the minimum Gibbs free energy principle. The results provide an initial condition for the hydrodynamic computation on the blast effects coming from explosion of some specific accidents.

Abstract: Experiments on combustion synthesis for the Ti-2B and Ti-C systems diluted with an inert metal are presented. The paper shows the influence of geometry, composition, density and particle size of diluent on the combustion front velocity. A Ti-2B reactant mixture diluted with Al and Cu and a Ti-C reactant mixture diluted with Al are studied. The metallic diluent and its concentration are varied. Besides, each experiment is based on a stack of cylinders with decreasing diameter in order to vary the heat losses. In some experiments the eventual quenching of the combustion reaction has been observed. Furthermore these experimental results are compared with theoretical calculations based on analytical expressions derived for such systems.