Papers by Keyword: R-Phase Transformation

Abstract: The influence of Nb addition on phase transformation, especially the intermediate R phase transformation and microstructure of TiNiFe shape memory alloys were investigated by means of electrical resistivity, optical microscope, energy dispersive spectroscopy and X-ray diffraction. The results showed that the R phase transformation was inhibited with the increase of Nb content. The martensite start transformation temperature decreased from 227K to 158K when the Nb content increased from 0.5 at.% to 2 at.%. The microstructure of the alloys were mainly characterized by TiNi matrix phase in which Fe and Nb resolved.

Abstract: A Ni-rich Ti-50.7.at%Ni alloy was processed by Equal Channel Angular Extrusion (ECAE) at 500°C. After 8 passes ECAE, microstructure was refined to sub-micron scale, approximately 0.2 μm～0.3 μm. TEM observation reveals that Ti3Ni4 phase precipitated in Ni-rich Ti-50.7.at%Ni alloy during the preheating treatment before each ECAE pass, but re-dissolved during sequent ECAE processes. After ECAE treatment, the B2R transformation occurred within a larger temperature range. Comparing with the solution-treated TiNi specimen, the martensitic transformations start (Ms) and peak temperatures (Mp) of TiNi specimens ECAEed were dramatically lowered. Super-elasticity characteristics of TiNi alloy were tested by tensile loading and unloading cycles. The results reveal that at a tensile strain of 4% or smaller, ultrafine-grained (UFG) TiNi alloy processed by 4 passes ECAE shows better super-elasticity than solution-treated sample. Microstructure evolution and its effect on phase transformations and super-elasticity characteristics have been discussed.

Abstract: The use of smart material such as Ti-Ni in actuators application requires an intense mechanical and metallurgical investigation to understand its behavior. This paper studies martensitic transformation using DSC and X-ray diffraction techniques to compare shape memory parameters in Ti-50.2%Ni (A1) and equiatomic Ti-50.0%Ni (A2) Alloys. The as as-received samples were submitted to annealing at 400°C and 500°C for 24 hours then quenched in at 25°C. The influence of heat treatment on martensitic transformations temperatures and the appearance of R-phase were analyzed using DSC and X-ray diffraction.

Abstract: Dynamic actuation properties of two types of high-speed microactuators utilizing Ti-Ni-based thin films were investigated. One type is a microactuator utilizing a Ti-Ni-Pd thin film which has high transformation temperatures. Cooling rate of a microactuator increases with increasing temperature difference between transformation and atmosphere temperatures, thus the increase in transformation temperature is effective to increase the actuation response. The other type is a microactuator using R-phase transformation of a Ti-Ni thin film which has a narrow transformation temperature hysteresis. The narrow transformation temperature hysteresis of the R-phase transformation is effective to increase the actuation response. Both types of actuators are promising for high response applications. The working frequency of the microactuators reached 100Hz in the two types of microactuators utilizing the martensitic transformation of the Ti-Ni-Pd thin film and the R-phase transformation of the Ti-Ni thin film.