Authors: Ragunathan Santiagoo, Sam Sung Ting, Ismail Hanafi, Mastura Jaafar
Abstract: The compatibilizer effect of ENR-50 on the tensile properties and morphology of linear low density polyethylene (LLDPE)/ recycled acrylonitrile butadiene rubber (NBRr)/ rice husk powder (RHP) composites has been studied. The RHP size utilize in this work is 150 – 300 μm. LLDPE/NBRr/RHP composites were prepared by melt mixing technique at 180 °C for 9 minutes at 50 rpm rotor speed using heated two roll mill. The series of composites investigated were 100/0/5, 80/20/5, 70/30/5, 60/40/5, 50/50/5, and 40/60/5. The composites were analysed by using tensile test and morphology examination. The result showed that the tensile strength of composite was decreased with the increasing of recycled acrylonitrile butadiene rubber (NBRr) content while elongation at break (Eb) were increased. However, the tensile strength and elongation at break result for composites with ENR-50 as compatibilizer showed higher values. The morphological finding supports the tensile properties which indicate better interaction between the RHP filler and LLDPE/NBRr matrix in the presence of ENR-50 compatibilizer.
210
Authors: Nurliayana Ariffin, Santiagoo Ragunathan, Sam Sung Ting, Hanafi Ismail
Abstract: The thermal degradation of linear low density polyethylene (LLDPE)/ recycled acrylonitrile butadiene rubber (NBRr)/ rice husk powder (RHP) composites with and without epoxidized nature rubber (ENR-50) were studied. The thermal degradation of this composite was evaluated for 30 days using oven ageing. The NBRr content was manipulated in this work and the particle size for the rice husk powder was 150-300 μm. The composites were prepared by using two-roll mills at 180 °C and then were compressed at 180 °C to produce a 1 mm thin sheets. The dumbbell samples then were analysed by using universal testing machine and field emission screening electron microscopy for tensile and morphological properties. The results obtained showed that tensile strength was decreased with the increasing of NBRr content for both oven ageing and control composites. However the oven ageing composites recorded much lower tensile properties. This may possibly due to the chain session of LDPPE matrix at longer heat exposure duration. This finding is supported by the morphological micrograph with less ductile features of the respective specimens.
205
Authors: Santiagoo Ragunathan, Ismail Hanafi, Hussin Kamarudin
Abstract: The effect of silane treatment on processing characteristic and swelling behavior of recycled acrylonitrile butadiene rubber (NBRr)/polypropylene (PP)/rice husk powder (RHP) composites has been studied. Polypropylene/recycled acrylonitrile butadiene rubber/rice husk powder (PP/NBRr/RHP) composite were prepared by melt mixing technique at 180º C for 9 minutes and 50rpm rotor speed using an internal mixer. Five different composites compositions (70/30/0, 7030/5, 70/30/10, 70/30/15 and 70/30/30), with silane treated RHP (treated) and without silane treatment RHP (untreated) was studied. The specimens were analyzed for swelling behavior with ASTM oil No.3 and processing torque of composites was obtained during composite preparation. The results showed that swelling percentage for both composites increased with NBRr content. However the treated composites exhibited lower swelling characteristics. Processing torque of both composites also showed higher torque reading with increasing NBRr content. However the treated composite with silane exhibited much higher torque value for similar composition composites. Better interaction between RHP filler and PP/NBRr matrixs was obtained with treated composites.
478
Authors: Santiagoo Ragunathan, Ismail Hanafi, Hussin Kamarudin
Abstract: The effect of silane treatment on tensile properties and morphology of recycled acrylonitrile butadiene rubber(NBRr)/polypropylene(PP)/rice husk powder(RHP) composites has been studied. Polypropylene/recycled acrylonitrile butadiene rubber/rice husk powder (PP/NBRr/RHP) composite were prepared by melt mixing technique at 180º C for 9 minutes and 50rpm rotor speed using an internal mixer. Five different composites compositions (70/30/0, 7030/5, 70/30/10, 70/30/15 and 70/30/30), with silane treated RHP(treated) and without silane treatment(untreated) was studied. The specimens were analyzed by different techniques i.e. tensile test and scanning electron microscopy (SEM). The result obtained showed lower tensile properties with increasing amount of NBRr content. Lower tensile strength and tensile modulus was exhibited with increasing NBRr content. However higher tensile strength, greater tensile modulus and lower elongation at break in PP/NBRr/RHP was exhibited for silane treated RHP composites compare with untreated RHP. PP/NBRr/RHP composite was found to become more brittle with strong attachment between PP/NBR matrix and RHP filler with silane treatment. Good adhesion between silane treated RHP filler and PP/NBRr matrix was confirmed by the morphological studies.
472